摘要:
An electrophotographic imaging member including a substrate, a charge generating layer, a charge transport layer, and an overcoat layer formed from a solution including a first cross linkable polyamide film forming binder free of methyl methoxy groups, an optional second cross linkable polyamide film forming binder containing methyl methoxy groups, a cross linking catalyst and a hole transport material. A process for forming an overcoated imaging member is also disclosed.
摘要:
A crosslinkable coating composition including an alcohol soluble acrylated polyamide containing alkoxymethyl or alkoxyalkylmethyl groups attached to amide nitrogen atoms, a crosslinking catalyst and a mixture of a hydroxy functionalized aromatic diamine with a hydroxy functionalized triarylamine. A coating is formed from this composition.
摘要:
A process for fabricating an electrophotographic imaging member includingforming a charge generating layer,forming an undried charge transport layer coating by applying to the charge generating layer a solution selected from either or both the group consisting ofa solution including a charge transport molecule, a first film forming binder and at least a first solvent anda solution including a charge transporting polymer and at least a first solvent,forming an undried overcoat layer coating by applying to the undried charge transport layer coating an overcoat layer coating solution including a second film forming polymer and at least a second solvent, the charge transport molecule and first film forming polymer or either or both a charge transporting polymer being substantially insoluble in the second solvent and the second polymer being substantially insoluble in the first solvent,applying heat to both the undried charge transport layer coating and the undried overcoat layer coating to migrate the first solvent from the charge transport layer coating through the undried overcoat layer coating while maintaining the overcoat layer coating porous to migration of the first solvent through the overcoat layer coating until the charge transport layer is substantially dry,increasing the heat applied to the overcoat layer coating to form a substantially dry overcoat layer.
摘要:
An electrophotographic imaging member includinga substrate,a charge generating layer,a charge transport layer, andan overcoat layer includinga hole transporting hydroxy arylamine compound having at least two hydroxy functional groups,bis-(2-methyl-4-diethylaminophenyl)-phenylmethane anda cross linked polyamide film forming binder.A process for forming an overcoated imaging member is also disclosed.
摘要:
A flexible electrophotographic imaging member including a supporting substrate coated with at least one imaging layer comprising charge transport material free of long chain alkyl carboxylate groups and a small amount of a different second hole transporting material containing at least two long chain alkyl carboxylate groups dissolved or molecularly dispersed in a film forming binder and coated from a mixture of solvents containing low boiling component and a small concentration of high boiling solvent. Preferably, the flexible electrophotographic imaging member is free of an anticurl backing layer, the imaging member comprising a supporting substrate uncoated on one side and coated on the opposite side with at least a charge generating layer and a charge transport layer containing comprising a first charge transport material and a small amount of a different second hole transporting material containing at least two long chain alkyl carboxylate groups dissolved or molecularly dispersed in a film forming binder and coated from a mixture of solvents containing low boiling component and a small concentration of high boiling solvent.
摘要:
An electrophotographic imaging member containing a charge generating layer and a charge transport layer, the charge transport layer comprising a film forming binder, a first aromatic diamine represented by the general formula: ##STR1## wherein X is selected from the group consisting of an alkyl group containing from 1 to 4 carbon atoms and chlorine and a second aromatic diamine represented by the general formula: ##STR2## wherein R.sub.1 represents an alkyl group or an alkoxy group, R.sub.2 represents a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, an alkoxycarbonyl group or a substituted amino group and R.sub.3 represents an alkyl group, an alkoxy group, a halogen atom, an alkoxycarbonyl group or a substituted amino group.
摘要:
A photoconductive imaging member is disclosed comprising a charge generation layer and a charge transport layer comprising an oxidative inhibitor. An electrophotographic imaging process using the imaging member of the invention is also described.
摘要:
A conductive composition including a mixture of a reaction product ofa hole transporting hydroxy functionalized aryl amine,a hydroxy functionalized arylamine that is different from the hole transporting hydroxy functionalized aryl amine,a cross linkable polyamide, andand an acid capable of simultaneously cross linking the polyamide and oxidizing a portion of the hydroxy functionalized arylamine,the mixture of a reaction product includinga hole transporting hydroxy functionalized aryl amine andan oxidized hydroxy functionalized aryl amine in aa crosslinked polyamide matrix.Other embodiments including processes for applying the aforementioned composition and processes for using devices containing the compositions in high speed laser printing and related printing systems are also disclosed.
摘要:
An allyloxymethylatedpolyamide composition is disclosed, the allyloxymethylatedpolyamide being represented by Formulae I and II: ##STR1## wherein: n is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R is an alkylene unit containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.2 sites are --H, andbetween 1 and 99 percent of the R.sub.2 sites are --H, and the remainder of the R.sub.2 sites is between 25 percent and 99 percent --CH.sub.2 --O--(CH.sub.2).sub.w --CH.dbd.CH.sub.2, whereinw is 1, 2 or 3,between 1 and 75 percent of the R.sub.2 sites are --CH.sub.2 --O--R.sub.5, andR.sub.5 is an alkyl unit containing 1 to 4 carbon atoms, and ##STR2## wherein: m is a positive integer sufficient to achieve a weight average molecular weight between about 5000 and about 100,000,R.sub.1 and R are independently selected from the group consisting of alkylene units containing from 1 to 10 carbon atoms,between 1 and 99 percent of the R.sub.3 and R.sub.4 sites are --H, and between 25 percent and 99 percent of the remainder of the R.sub.3 and R.sub.4 sites are --CH.sub.2 --O--(CH.sub.2).sub.w --CH.dbd.CH.sub.2,whereinw is 1, 2 or 3, andbetween 1 percent and 75 percent of the R.sub.2 sites are --CH.sub.2 --O--R.sub.5wherein R.sub.5 is an alkyl unit containing 1 to 4 carbon atoms.The allyloxymethylatedpolyamide may be synthesized by reacting an alcohol soluble polyamide with formaldehyde and an allylalcohol.The allyloxymethylatedpolyamide may be cross linked by a process selected from the group consisting of(a) heating an allyloxymethylatedpolyamide in the presence of a free radical catalyst, and(b) hydrosilation of the double bond of the allyloxy group of the allyloxymethylatedpolyamide with a silicon hydride reactant having at least 2 reactive sites.A preferred article includesa substrate,at least one photoconductive layer, andan overcoat layer comprisinga hole transporting hydroxy arylamine compound having at least two hydroxy functional groups, anda cross linked allyloxymethylatedpolyamide film forming binder.A stabilizer may be added to the overcoat.
摘要:
A flexible electrophotographic imaging member including a supporting substrate coated with at least one imaging layer comprising hole transporting material containing at least two long chain alkyl carboxylate groups dissolved or molecularly dispersed in a film forming binder.