ETHYLENE-BASED POLYMERS WITH NEW DISTRIBUTIONS OF TERMINAL AND INTERNAL UNSATURATIONS

    公开(公告)号:US20200231712A1

    公开(公告)日:2020-07-23

    申请号:US16634914

    申请日:2018-07-13

    IPC分类号: C08F2/01 C08F10/02

    摘要: A high pressure, free radical polymerization process to form an ethylene-based polymer, the process comprising at least the following step: polymerizing a reaction mixture comprising ethylene, using a polymerization system comprising the following: (A) a reactor configuration comprising at least one reactor that comprises at least two reaction zones, a first reaction zone (reaction zone 1) and an ith reaction zone (where i≥2); wherein the ith reaction zone is the last reaction zone, and wherein i is the total number of reaction zones; (B) at least two ethylene-based feed streams, a first ethylene-based feed stream and an nth ethylene-based feed stream, wherein the first ethylene-based feed stream is sent to the first reaction zone, and the nth ethylene-based feed stream is the last ethylene based feed stream sent to the reactor configuration; wherein n≤i; and RZn/RZ1 does not equal 1.0, where RZ1=mole fraction of make-up ethylene in the first ethylene-based feed stream to the first reaction zone; where RZn=mole fraction of make-up ethylene in the last ethylene-based feed stream sent to the reactor configuration; (C) a control system to control the percentage of the make-up ethylene in the first ethylene-based feed stream, and the percentage of the make-up ethylene in the nth ethylene-based feed stream; and wherein at least one reaction zone receives a CTA make-up feed stream comprising an alpha-olefin, and wherein the alpha-olefin has a chain transfer activity constant (Cs) value ≤0.10, and wherein the chain transfer activity constant (Cs) is measured at 1360 atm, 130° C.

    PEROXIDE CONTAINING POLYOLEFIN FORMULATION
    22.
    发明申请

    公开(公告)号:US20200181374A1

    公开(公告)日:2020-06-11

    申请号:US16623858

    申请日:2018-08-27

    摘要: A process of melt compounding a polyolefin formulation comprising a ethylenic-based (co)polymer, an antioxidant, and from 0.15 to 1.00 weight percent of an organic peroxide having a 1-hour half-life temperature of less than or equal to 155 degrees Celsius (° C.) and/or a 10-hour half-life temperature of less than or equal to 135° C. Also, intermediate compositions having a modified rheology and crosslinked polyolefin products made therefrom; methods of making and using same; and articles containing same.

    Moisture-and peroxide-crosslinkable polymeric compositions

    公开(公告)号:US10308829B2

    公开(公告)日:2019-06-04

    申请号:US15028967

    申请日:2014-11-10

    摘要: Crosslinkable polymeric compositions comprising a polyolefin having hydrolyzable silane groups, an organic peroxide, and optionally a silanol condensation catalyst. Such crosslinkable polymeric compositions are crosslinkable via a combination of peroxide crosslinking and moisture curing. Such crosslinkable polymeric compositions can be employed in the production of various articles of manufacture, such as coated conductors.

    OPTICAL FIBER CABLE COMPONENTS
    29.
    发明申请
    OPTICAL FIBER CABLE COMPONENTS 有权
    光纤电缆组件

    公开(公告)号:US20160289433A1

    公开(公告)日:2016-10-06

    申请号:US15035264

    申请日:2014-11-12

    IPC分类号: C08L23/06 G02B6/44

    摘要: Polymeric compositions comprising a high-density polyethylene, a crystalline polypropylene, and an olefin block composite. Optical cable components fabricated from an extrudable polymeric composition of high-density polyethylene, a crystalline polypropylene, and an olefin block composite. Optionally, the polymeric composition can further comprise a nucleating agent. The polymeric composition may also contain one or more additives. The optical fiber cable components can be selected from buffer tubes, core tubes, and slotted core tubes, among others.

    摘要翻译: 包含高密度聚乙烯,结晶聚丙烯和烯烃嵌段复合材料的聚合物组合物。 由高密度聚乙烯,结晶聚丙烯和烯烃嵌段复合材料的可挤出聚合物组合物制成的光缆部件。 任选地,聚合物组合物还可以包含成核剂。 聚合物组合物还可以含有一种或多种添加剂。 光纤电缆组件可以选自缓冲管,芯管和开槽芯管等。