Abstract:
Provided is a method for manufacturing a sulfide-based solid electrolyte including preparing a precursor comprising lithium sulfide, germanium sulfide, aluminum sulfide, phosphorus sulfide, and sulfur, conducting a mixing process of the precursor to prepare a mixture, and crystallizing the mixture to form a compound represented by Li9.7Al0.3Ge0.7P2S12. The sulfide-based solid electrolyte may have high ionic conductivity.
Abstract:
Provided is a lithium secondary battery including a first electrode, a second electrode spaced apart from the first electrode, a solid electrolyte disposed between the first electrode and the second electrode, wherein the solid electrolyte includes a fibril and a plurality of sulfide particles, the fibril includes polytetrafluoroethylene, the fibril surrounds at least some of the sulfide particles or is in contact with at least some of the sulfide particles.
Abstract:
Provided is a cellulose derivative composition for an all-solid-state secondary battery binder including a compound represented by Formula 1 below according to the inventive concept. In Formula 1, R1, R1′, R2, R2′, R3, and R3′ are each independently any one among a carboxymethyl group, a sulfur substituent, or a phosphorus substituent, in which a monovalent metal is substituted or hydrogen, wherein R1, R2, and R3 is —CH2COOX, , SO3X, —PO3X or —PO3X2 where X may be any one among sodium (Na), potassium (K), rubidium (Rb), or cesium (Cs). R1′, R2′, and R3′ is —CH2COOY, —SO3Y, —PO3Y or —PO3Y2 where Y may be lithium (Li).
Abstract:
Provided is a cellulose derivative composition for a secondary battery binder, a method of preparing a composition for a secondary battery electrode, including the same, and a secondary battery including the same. According to the inventive concept, the cellulose derivative composition for a secondary battery binder may include a compound represented by Formula 1 below.
Abstract:
Provided is a method for manufacturing a solid secondary battery, wherein the method includes forming a composite electrolyte film, and forming a positive electrode and a negative electrode respectively on both surfaces of the composite electrolyte film. The forming of a composite electrolyte film includes preparing inorganic ion conductor powder coated with an ion resistance layer, removing the ion resistance layer to expose the surface of the inorganic ion conductor powder, mixing the inorganic ion conductor powder with an organic ion conductor and a solvent to prepare a composite electrolyte solution, and removing the solvent from the composite electrolyte solution.
Abstract:
Provided is a cellulose derivative composition for a secondary battery binder, a method of preparing a composition for a secondary battery electrode, including the same, and a secondary battery including the same. According to the inventive concept, the cellulose derivative composition for a secondary battery binder may include a compound represented by Formula 1 below.
Abstract:
A method of preparing a lithium phosphate-based solid electrolyte according to an embodiment of the present invention may include preparing a precursor solution which includes a lithium compound, a phosphate compound, and an aluminum compound, forming a first intermediate by performing a hydrothermal reaction process on the precursor solution, forming a second intermediate by calcinating the first intermediate, and crystallizing the second intermediate. The precursor solution may further include a metal compound or a metalloid compound. The lithium phosphate-based solid electrolyte of the present invention may have high ionic conductivity and high purity.
Abstract:
An oxide-based solid electrolyte according to the present invention may be LixLa3M2O12 and may have a cubic phase. The oxide-based solid electrolyte may further include first and second dopants. A method of preparing an oxide-based solid electrolyte according to the concept of the present invention may include mixing a lithium compound, a lanthanum compound, a metal compound, a first dopant precursor, and a second dopant precursor to prepare an intermediate, and crystallizing the intermediate to prepare LixLa3M2O12 crystals having a cubic phase.
Abstract:
A solid polymeric electrolyte and a lithium battery with the same. The electrolyte includes a polymer matrix, which may have a mesh structure with the polymer matrix being formed of a cured photo-crosslinking agent. The electrolyte also includes inorganic particles distributed in the polymer matrix, and a lithium salt and an organic solvent impregnated between the polymer matrix and the inorganic particles. The electrolyte has a first portion, a second portion, and a third portion connecting the first and second portions, wherein one of the first, second, and third portions is located apart from a flat plane connecting the others. The lithium battery includes an anode electrode provided with an anode active material and an anode current collector, and a cathode electrode provided with a cathode active material and a cathode current collector and disposed to face the anode electrode, with the electrolyte interposed between the two electrodes.
Abstract:
Provided is a method for manufacturing a solid electrolyte including preparing a preparation solution by dissolving first polymers and second polymers in a cosolvent which includes a first cosolvent and a second cosolvent, preparing a mixture solution by adding a lithium solution to the preparation solution, preparing an electrolyte paste by removing the second cosolvent in the mixture solution, and forming an electrolyte film by coating the electrolyte paste on a substrate.