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公开(公告)号:US20070203258A1
公开(公告)日:2007-08-30
申请号:US10571758
申请日:2004-09-17
申请人: Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Steeman
发明人: Masanobu Sugimoto , Satoshi Kamo , Takeo Shigemoto , Zen Komiya , Paulus Steeman
CPC分类号: C08G18/672 , C03C25/1061 , C03C25/1065 , C08G18/4854 , C08L75/16 , C09D175/16 , Y10T428/2933 , C08G18/48 , C08L2666/14
摘要: The invention relates to a curable liquid resin composition comprising: (A) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 800 g/mol or more, but less than 6,000 g/mol, and (B) a urethane(meth)acrylate having a structure originating from a polyol and a number average molecular weight of 6,000 g/mol or more, but less than 20,000 g/mol, wherein the total amount of the component (A) and component (B) is 20-95 wt % of the curable liquid resin composition and the content of the component (B) is 0.1-30 wt % of the total of the component (A) and component (B).
摘要翻译: 本发明涉及一种可固化液体树脂组合物,其包含:(A)具有起始于多元醇的结构和数均分子量为800g / mol以上但小于6,000g / mol的氨基甲酸酯(甲基)丙烯酸酯,以及 (B)具有来自多元醇的结构和数均分子量为6000g / mol以上但小于20,000g / mol的氨基甲酸酯(甲基)丙烯酸酯,其中组分(A)和组分 (B)为可固化液体树脂组合物的20-95重量%,组分(B)的含量为组分(A)和组分(B)的总量的0.1-30重量%。
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公开(公告)号:US5053471A
公开(公告)日:1991-10-01
申请号:US613939
申请日:1990-11-13
申请人: Kohei Goto , Zen Komiya , Noboru Yamahara , Akira Iio
发明人: Kohei Goto , Zen Komiya , Noboru Yamahara , Akira Iio
CPC分类号: C08L65/00 , C08G61/08 , G11B7/2538
摘要: A transparent resin material consisting of a (co)polymer obtained by subjecting at least one compound represented by the general formula (I) or a combination of said compound and other copolymerizable monomer to metathesis polymerization, or a hydrogenation product of the (co)polymer: ##STR1## wherein A and B are independently hydrogen atoms or C.sub.1-10 hydrocarbon groups; X and Y are independently hydrogen atoms, C.sub.1-10 hydrocarbon groups, halogen atoms, halogen-substituted C.sub.1-10 hydrocarbon groups, --(CH.sub.2).sub.n COOR.sup.1, --(CH.sub.2).sub.n OCOR.sup.1, --(CH.sub.2).sub.n OR.sup.1, --(CH.sub.2).sub.n CN, --(CH.sub.2).sub.n CONR.sup.2 R.sup.3, --(CH.sub.2).sub.n COOZ, --(CH.sub.2).sub.n OCOZ, --(CH.sub.2).sub.n OZ or --(CH.sub.2).sub.n W [R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently C.sub.1-20 hydrocarbon groups, Z is a halogen-substituted hydrocarbon group, W is SiR.sub.p.sup.5 D.sub.3-p (R.sup.5 is a C.sub.1-10 hydrocarbon group, D is a halogen atom, --OCOR.sup.5 or --OR.sup.5, p is 0 or an integer of 1-3), n is 0 or an integer of 1-10] with the proviso that at least one of X and Y is selected from the above groups other than the hydrogen atom and the hydrocarbon groups, or X and Y may form together ##STR2## and m is 0 or 1. Said transparent resin material is moldable and has sufficient optical properties, low hygroscopicity, good heat resistance and excellent adhesion to recording layer.
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公开(公告)号:US07532795B2
公开(公告)日:2009-05-12
申请号:US10568453
申请日:2004-08-20
申请人: Atsuya Takahashi , Takeo Shigemoto , Zen Komiya , Hiroki Ohara
发明人: Atsuya Takahashi , Takeo Shigemoto , Zen Komiya , Hiroki Ohara
IPC分类号: B32B17/02 , G02B6/02 , G02B6/04 , G02B6/036 , G02B6/44 , C08L75/16 , C09D175/16 , C08F290/06 , C08F2/46
CPC分类号: C09D175/16 , C03C25/106 , C08G18/672 , C08G18/8175 , Y10T428/2938 , C08G18/48
摘要: The invention relates to a radiation-curable liquid resin composition comprising: (A) 20-90 wt % of a urethane(meth)acrylate oligomer, and (B) 1-35 wt % of a monomer shown by the following formula (1), wherein R1 represents a hydrogen atom or a methyl group, R2 and R3 individually represent a hydrogen atom or an alkyl group having 1-4 carbon atoms, R4 represents a hydrogen atom or a methyl group, and n represents an integer of 1-6, or a monomer including a hydroxyl group.
摘要翻译: 本发明涉及一种可辐射固化液体树脂组合物,其包含:(A)20-90重量%的氨基甲酸酯(甲基)丙烯酸酯低聚物和(B)1-35重量%的由下式(1)表示的单体, 其中R1表示氢原子或甲基,R2和R3分别表示氢原子或具有1-4个碳原子的烷基,R4表示氢原子或甲基,n表示1-6的整数 ,或包含羟基的单体。
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公开(公告)号:US20050244752A1
公开(公告)日:2005-11-03
申请号:US10508993
申请日:2003-03-23
申请人: Junji Yoshizawa , Atsuya Takahashi , Masahito Mase , Zen Komiya
发明人: Junji Yoshizawa , Atsuya Takahashi , Masahito Mase , Zen Komiya
IPC分类号: C09J4/02 , C08F289/00 , C08F290/06 , C09J4/06 , C09J11/00 , G11B7/24
CPC分类号: C08F290/061 , C08F289/00 , C08F290/06 , C09J4/06
摘要: A radiation-curable resin composition for adhesives comprising (A) a bisphenol-type epoxy (meth)acrylate having a hydroxyl group, (B) a polyfunctional (meth)acrylate having an aliphatic cyclic structure or an aromatic cyclic structure other than the component (A), and (C) a photoinitiator, wherein the content of the component (A) and the content of the component (B) in the composition are respectively 30 wt % or more. The radiation-curable resin composition for adhesives of the present invention exhibits excellent adhesion to silver, silicon compound, and aluminum, superior moisture-heat resistance, and fast curability, especially at the edge of the disk, and therefore is very useful in the manufacture of optical disks in comparison with conventional adhesives.
摘要翻译: 一种用于粘合剂的辐射固化树脂组合物,其包含(A)具有羟基的双酚型环氧(甲基)丙烯酸酯,(B)具有脂肪族环状结构的多官能(甲基)丙烯酸酯或除该成分 A)和(C)光引发剂,其中组分(A)的含量和组分(B)中组分的含量分别为30重量%或更多。 本发明的粘合剂用辐射固化型树脂组合物对银,硅化合物和铝具有优异的粘合性,优异的耐湿热性和快速固化性,特别是在盘的边缘,因此在制造中非常有用 与常规粘合剂相比。
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公开(公告)号:US5164469A
公开(公告)日:1992-11-17
申请号:US648237
申请日:1991-01-31
申请人: Kohei Goto , Zen Komiya , Noboru Yamahara , Akira Iio , Masao Hisatomi , Hiroshi Oka
发明人: Kohei Goto , Zen Komiya , Noboru Yamahara , Akira Iio , Masao Hisatomi , Hiroshi Oka
摘要: A transparent resin material consisting of a hydrogenation product of a (co)polymer obtained by subjecting at least one compound represented by general formula (I) or a combination of at least 5% by weight of said compound and 95% by weight or less of other copolymerizable cyclic olefin monomer to metathesis polymerization: ##STR1## wherein A and B are independently hydrogen atoms or C.sub.1-10 hydrocarbon groups; and X and Y are independently hydrogen atoms, C.sub.1-10 hydrocarbon groups, --C(CH.sub.2).sub.n COOR.sup.1 groups or --(CH.sub.2).sub.n OCOR.sup.1 groups [R.sup.1 is a C.sub.1-20 hydrocarbon group and n is 0 or an integer of 1-10] with the proviso that at least one of X and Y is selected from the above --(CH.sub.2).sub.n COOR.sup.1 and --(CH.sub.2).sub.n OCOR.sup.1 groups. Said transparent resin material is moldable and has sufficient optical properties, low hygroscopicity, good heat resistance and excellent adhesion to recording layer.
摘要翻译: 将由通式(I)表示的至少一种化合物或至少5重量%的所述化合物的组合和95重量%以下的化合物所得的(共)聚合物的氢化产物组成的透明树脂材料 其它可共聚的环烯烃单体进行复分解聚合反应:其中A和B独立地为氢原子或C 1-10烃基; 并且X和Y独立地是氢原子,C 1-10烃基,-C(CH 2)n COOR 1基团或 - (CH 2)nOCOR 1基团[R 1是C 1-20烃基,n是0或1-10的整数] 条件是X和Y中的至少一个选自上述 - (CH 2)n COOR 1和 - (CH 2)nOCOR 1基团。 所述透明树脂材料是可模塑的并且具有足够的光学性能,低吸湿性,良好的耐热性和对记录层的优异粘合性。
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公开(公告)号:US08242202B2
公开(公告)日:2012-08-14
申请号:US10592490
申请日:2005-03-15
申请人: Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
发明人: Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
IPC分类号: C09D11/00 , C08G18/00 , B32B15/00 , C08L75/00 , C08F283/04
CPC分类号: C03C25/106 , C08G18/12 , C08G18/672 , C08G18/8175 , C09D175/16 , Y10T428/2933 , C08G18/48
摘要: The invention relates to a curable liquid resin composition comprising the following components (A), (B), and (C): (A) a urethane (meth)acrylate oligomer, (B) a monomer shown by the following formula (1), CH2═CR1COOR2 (1) wherein R1 represents a hydrogen atom or a methyl group and R2 represents a monovalent organic group, 40 wt % or more of the total amount of the component (B) being a monomer in which the R2 group in the formula (1) is a nonpolar organic group, and the monomer in the component (B) in which the R2 group in the formula (1) is a nonpolar organic group being hereinafter referred to as “nonpolar (meth)acrylate-containing monomer”, and (C) a polymerization initiator.
摘要翻译: 本发明涉及一种包含以下组分(A),(B)和(C)的可固化液体树脂组合物:(A)氨基甲酸酯(甲基)丙烯酸酯低聚物,(B)由下式(1) ,CH2 = CR1COOR2(1)其中R1表示氢原子或甲基,R2表示一价有机基团,作为单体的组分(B)的总量的40重量%以上,其中, 式(1)为非极性有机基团,式(1)中的R 2基为非极性有机基团的成分(B)中的单体以下称为“含有非极性(甲基)丙烯酸酯的单体” ,(C)聚合引发剂。
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公开(公告)号:US20080254288A1
公开(公告)日:2008-10-16
申请号:US10592490
申请日:2005-03-15
申请人: Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
发明人: Hiroshi Yamaguchi , Satoshi Kamo , Takeo Shigemoto , Zen Komiya
CPC分类号: C03C25/106 , C08G18/12 , C08G18/672 , C08G18/8175 , C09D175/16 , Y10T428/2933 , C08G18/48
摘要: The invention relates to a curable liquid resin composition comprising the following components (A), (B), and (C): (A) a urethane (meth)acrylate oligomer, (B) a monomer shown by the following formula (1), CH2═CR1COOR2 (1) wherein R1 represents a hydrogen atom or a methyl group and R2 represents a monovalent organic group, 40 wt % or more of the total amount of the component (B) being a monomer in which the R2 group in the formula (1) is a nonpolar organic group, and the monomer in the component (B) in which the R2 group in the formula (1) is a nonpolar organic group being hereinafter referred to as “nonpolar (meth)acrylate-containing monomer”, and (C) a polymerization initiator.
摘要翻译: 本发明涉及一种包含以下组分(A),(B)和(C)的可固化液体树脂组合物:(A)氨基甲酸酯(甲基)丙烯酸酯低聚物,(B)由下式(1) ,其中R 1表示氢原子或甲基(CH 2)2,其中R 1表示氢原子或甲基 R 2表示一价有机基团,作为单体的成分(B)的总量的40重量%以上,式中R 2〜 (1)是非极性有机基团,式(1)中的R 2-2基团为非极性有机基团的成分(B)中的单体以下称为“非极性( (C)聚合引发剂。
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公开(公告)号:US20060128856A1
公开(公告)日:2006-06-15
申请号:US10529180
申请日:2003-09-29
申请人: Atsuya Takahashi , Junji Yoshizawa , Masakatsu Ukon , Zen Komiya
发明人: Atsuya Takahashi , Junji Yoshizawa , Masakatsu Ukon , Zen Komiya
IPC分类号: C08L93/00
CPC分类号: C09J175/16 , C08F290/067
摘要: Provided is a liquid curing resin composition exhibiting excellent adhesion to PET-PET, MS-PET and the like, having excellent processability, heat resistance and water resistance, and having a high-cure rate. A liquid curing resin composition containing the following components (A) and (B): (A) 30 to 70 wt. % of a urethane (meth)acrylate having a number-average molecular weight of from 10000 to 40000, and (B) 30 to 60 wt. % of an ethylenically unsaturated monomer having a glass transition point, in the form of a homopolymer, of 60° C. or greater.
摘要翻译: 本发明提供对PET-PET,MS-PET等具有优异的加工性,耐热性和耐水性优异且固化率高的液体固化性树脂组合物。 含有下列组分(A)和(B)的液体固化树脂组合物:(A)30至70重量% %的数均分子量为10000〜40000的氨基甲酸酯(甲基)丙烯酸酯,(B)30〜60重量% %的具有60℃或更高的均聚物形式的具有玻璃化转变点的烯属不饱和单体。
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公开(公告)号:US20050282938A1
公开(公告)日:2005-12-22
申请号:US11079480
申请日:2005-03-15
申请人: Hiroshi Yamaguchi , Masanobu Sugimoto , Satoshi Kamo , Zen Komiya
发明人: Hiroshi Yamaguchi , Masanobu Sugimoto , Satoshi Kamo , Zen Komiya
IPC分类号: B05D1/36 , C08F290/06 , C08G18/67 , C09D5/18 , C09D7/12 , C09D155/00 , C09D175/14 , C09D175/16 , G02B6/44
CPC分类号: C09D175/16 , C08G18/672 , G02B6/4402 , G02B6/4436 , G02B6/4438 , C08G18/48
摘要: The invention relates to a curable liquid resin composition which exhibits excellent curability, can be applied at high speed, and produces a cured product having a Young's modulus appropriate for the upjacket layer and excellent coating removal properties of the upjacket layer. The curable liquid resin composition according to the invention comprises: (A) a urethane (meth)acrylate, (B) a reactive diluent, (C) a polymerization initiator, and (D) particles with a number average particle size of 0.1-100 μm.
摘要翻译: 本发明涉及一种显示出优异的固化性的可固化液体树脂组合物,可以高速施加,并且可以生产具有适合于鞋面层的杨氏模量和优异的鞋面层的涂层去除性能的固化产物。 根据本发明的可固化液体树脂组合物包含:(A)氨基甲酸酯(甲基)丙烯酸酯,(B)反应性稀释剂,(C)聚合引发剂,和(D)数均粒径为0.1-100 妈妈
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30.
公开(公告)号:US20090191404A1
公开(公告)日:2009-07-30
申请号:US10592767
申请日:2005-03-15
申请人: Shingo Itai , Yoshikazu Yamaguchi , Zen Komiya
发明人: Shingo Itai , Yoshikazu Yamaguchi , Zen Komiya
CPC分类号: C08K3/22 , C08F222/1006 , C08K3/20 , C08K9/06 , C09D4/00 , C09D5/006 , C09D5/24 , C09D7/62 , Y10T428/265 , Y10T428/31931
摘要: The object of the invention is to provide a curate liquid composition excelling in storage stability and curability and capable of forming a coat (film) which excels in antistatic properties, hardness, scratch resistance, and transparency on the surface of various substrates, a cured film of the composition, and an anti static laminate. This object is achieved by providing a curate liquid composition comprising the following components (A), (B), (C), and (D): (A) particles comprising an oxide of at least one element selected from the group consisting of indium, antimony, zinc, and tin as a major component, (B) a compound having two or more polymerizable unsaturated groups in the molecule, (C) a silicon-containing surfactant, and (D) a solvent.
摘要翻译: 本发明的目的是提供一种在储存稳定性和固化性方面优异且能够形成在各种基材的表面上具有优异的抗静电性,硬度,耐刮擦性和透明性的涂膜(膜)的凝固液组合物,固化膜 的组合物,和抗静电层压板。 该目的通过提供一种包含以下组分(A),(B),(C)和(D))的凝固液组合物来实现:(A)包含选自铟的至少一种元素的氧化物的颗粒 ,锑,锌和锡作为主要成分,(B)分子中具有2个以上聚合性不饱和基团的化合物,(C)含硅表面活性剂和(D)溶剂。
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