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30 条记录 (耗时 0.02 秒)

    Asymmetric imine hydrogenation processes
    26.
    发明授权
    Asymmetric imine hydrogenation processes 有权
    不对称亚胺加氢工艺

    公开(公告)号：US07816533B2

    公开(公告)日：2010-10-19

    申请号：US10596489

    申请日：2004-12-15

    申请人： Kamaluddin Abdur-Rashid

    发明人： Kamaluddin Abdur-Rashid

    IPC分类号： C07D211/08

    CPC分类号： C07C209/52 ,  C07C211/27 ,  C07C211/35

    摘要： A process for the catalytic hydrogenation or asymmetric hydrogenation of imines of Formula (I) to the corresponding amines of Formula (II) is provided in which R1 is aryl; R2 is aryl, cyclic, alkyl, alkenyl or alkynyl; and R3 is alkyl. The catalytic system includes a ruthenium complex containing (1) a diamine and (2) a diphosphine or two monodentate phosphines ligands. Such process also relates to the asymmetric hydrogenation of prochiral imines to the chiral amines using chiral ruthenium complexes bearing chiral diphosphines or chiral monodentate phosphines and chiral diamines.

    摘要翻译： 提供了将式（I）的亚胺催化氢化或不对称加氢到相应的式（II）的胺的方法，其中R 1是芳基; R2是芳基，环状，烷基，烯基或炔基; 并且R 3是烷基。 催化体系包括含有（1）二胺和（2）二膦或两个单齿膦配体的钌络合物。 这种方法还涉及使用携带手性二膦或手性单齿膦和手性二胺的手性钌络合物将前手性亚胺与手性胺的不对称氢化反应。

    Asymmetric Imine Hydrogenation Processes
    27.
    发明申请
    Asymmetric Imine Hydrogenation Processes 有权
    不对称亚胺氢化过程

    公开(公告)号：US20070293681A1

    公开(公告)日：2007-12-20

    申请号：US10596489

    申请日：2004-12-15

    申请人： Kamaluddin Abdur-Rashid

    发明人： Kamaluddin Abdur-Rashid

    IPC分类号： C07C209/26 ,  C07D207/06 ,  C07D221/00

    CPC分类号： C07C209/52 ,  C07C211/27 ,  C07C211/35

    摘要： A process for the catalytic hydrogenation or asymmetric hydrogenation of imines of Formula (I) to the corresponding amines of Formula (II) is provided in which R1 is aryl; R2 is aryl, cyclic, alkyl, alkenyl or alkynyl; and R3 is alkyl. The catalytic system includes a ruthenium complex containing (1) a diamine and (2) a diphosphine or two monodentate phosphines ligands. Such process also relates to the asymmetric hydrogenation of prochiral imines to the chiral amines using chiral ruthenium complexes bearing chiral diphosphines or chiral monodentate phosphines and chiral diamines.

    摘要翻译： 提供了式（I）的亚胺与式（II）的相应胺的催化氢化或不对称氢化的方法，其中R 1是芳基; R 2是芳基，环状，烷基，链烯基或炔基; R 3是烷基。 催化体系包括含有（1）二胺和（2）二膦或两个单齿膦配体的钌络合物。 这种方法还涉及使用携带手性二膦或手性单齿膦和手性二胺的手性钌络合物将前手性亚胺与手性胺的不对称氢化反应。

    Process for hydrogenating unactivated imines using ruthenium complexes as catalysts
    28.
    发明授权
    Process for hydrogenating unactivated imines using ruthenium complexes as catalysts 失效
    使用钌配合物作为催化剂氢化未活化的亚胺的方法

    公开(公告)号：US07256311B2

    公开(公告)日：2007-08-14

    申请号：US10513321

    申请日：2003-05-15

    申请人： Kamaluddin Abdur-Rashid ,  Robert H. Morris

    发明人： Kamaluddin Abdur-Rashid ,  Robert H. Morris

    IPC分类号： C07C209/52

    CPC分类号： C07D453/02 ,  C07B2200/07 ,  C07C209/52 ,  C07C2601/02 ,  C07C2601/04 ,  C07C211/48 ,  C07C211/42

    摘要： A process is provided for the hydrogenation or asymmetric hydrogenation of dialkyl, alkylalkenyl and dialkenyl imines of formula (II) to provide amines of formula (III), wherein, (i) R1 and R2 are optionally substituted cyclic, linear or branched alkyl or alkenyl; R3 is a hydrogen atom, a hydroxy radical, optionally substituted C1 to C8 cyclic, linear or branched alkyl or alkenyl, optionally substituted aryl; or (ii) R1 is alkyl or alkenyl, R2 is alkyl or alkenyl and the two are linked together or with R3 to form one or more rings; using a catalytic system comprising a base and a ruthenium complex containing (1) a diamine and (2) a diphosphine ligand or monodentate phosphine ligands in hydrogenation and asymmetric hydrogenation processes

    摘要翻译： 提供了用于氢化或不对称氢化式（II）的二烷基，烷基烯基和二烯丙基亚胺以提供式（III）的胺的方法，其中，（i）R 1和R 2 2是任选取代的环状，直链或支链烷基或烯基; R 3是氢原子，羟基，任选取代的C 1至C 8环，直链或支链烷基或链烯基，任选取代的 芳基; 或（ii）R 1是烷基或链烯基，R 2是烷基或链烯基，并且两者连接在一起或与R 3连接形成 一个或多个戒指; 使用包含碱和钌络合物的催化体系，所述催化体系包含（1）二胺和（2）氢化和不对称氢化方法中的二膦配体或单齿膦配体

    Process for hydrogenating unactivated imines using ruthenium complexes as catalysts
    29.
    发明申请
    Process for hydrogenating unactivated imines using ruthenium complexes as catalysts 失效
    使用钌配合物作为催化剂氢化未活化的亚胺的方法

    公开(公告)号：US20050209487A1

    公开(公告)日：2005-09-22

    申请号：US10513321

    申请日：2003-05-15

    申请人： Kamaluddin Abdur-Rashid ,  Robert Morris

    发明人： Kamaluddin Abdur-Rashid ,  Robert Morris

    IPC分类号： C07D487/08 ,  B01J31/24 ,  C07B53/00 ,  C07B61/00 ,  C07C209/52 ,  C07C211/48 ,  C07C29/30

    CPC分类号： C07D453/02 ,  C07B2200/07 ,  C07C209/52 ,  C07C2601/02 ,  C07C2601/04 ,  C07C211/48 ,  C07C211/42

    摘要： A process is provided for the hydrogenation or asymmetric hydrogenation of dialkyl, alkylalkenyl and dialkenyl imines of formula (II) to provide amines of formula (III), wherein, (i) R1 and R2 are optionally substituted cyclic, linear or branched alkyl or alkenyl; R3 is a hydrogen atom, a hydroxy radical, optionally substituted C1 to C8 cyclic, linear or branched alkyl or alkenyl, optionally substituted aryl; or (ii) R1 is alkyl or alkenyl, R2 is alkyl or alkenyl and the two are linked together or with R3 to form one or more rings; using a catalytic system comprising a base and a ruthenium complex containing (1) a diamine and (2) a diphosphine ligand or monodentate phosphine ligands in hydrogenation and asymmetric hydrogenation processes.

    摘要翻译： 提供了用于氢化或不对称氢化式（II）的二烷基，烷基烯基和二烯丙基亚胺以提供式（III）的胺的方法，其中，（i）R 1和R 2 2是任选取代的环状，直链或支链烷基或烯基; R 3是氢原子，羟基，任选取代的C 1至C 8环，直链或支链烷基或链烯基，任选取代的 芳基; 或（ii）R 1是烷基或链烯基，R 2是烷基或链烯基，并且两者连接在一起或与R 3连接形成 一个或多个戒指; 使用包含碱和钌络合物的催化体系，其在氢化和不对称氢化过程中含有（1）二胺和（2）二膦配体或单齿膦配体。