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公开(公告)号：US20050197447A1
公开(公告)日：2005-09-08
申请号：US11072817
申请日：2005-03-04
申请人： Jiren Gu , Krishna Venkataswamy
发明人： Jiren Gu , Krishna Venkataswamy
IPC分类号： C08F8/00 , C08K3/00 , C08L23/04 , C08L51/00 , C08L53/02 , C09D123/04 , C09D151/00 , C09D153/02
CPC分类号： C08F8/00 , C08K3/00 , C08L23/04 , C08L51/00 , C08L53/02 , C09D123/04 , C09D151/00 , C09D153/02
摘要： A thermoplastic elastomer (TPE) for overmolding (OM) a nylon substrate with an overmolded layer consists essentially of an inert filler, a plasticizer, preferably a mineral oil, and chosen combinations of ingredients from the following: (i) a functionalized “high rubber” SHDS (styrene-hydrogenated diene-styrene) having a functionality of 1%, the “small end blocks” together present in an amount in the range from about 8-25% by weight; (ii) hydrogenated SDS or SHDS block copolymer having polystyrene endblocks and a polymerized vinyl aromatic monomer in the poly(conjugated diene) midblock, the polystyrene endblocks together present in an amount in the range from 20-30% by weight of the block copolymer, excluding weight of the polystyrene in the polydiene midblock; (iii) a functionalized “high rubber” SHDS having a functionality of >1% but
摘要翻译： 用于包覆成型（OM）的具有包覆成型层的尼龙基底的热塑性弹性体（TPE）主要由惰性填料，增塑剂，优选矿物油组成，以及选自下列成分的组合：（i）官能化的“高橡胶 功能性为1％的SHDS（苯乙烯 - 氢化二烯 - 苯乙烯），“小端嵌段”的量一般为约8-25重量％ （ii）在聚（共轭二烯）中间嵌段中具有聚苯乙烯端嵌段和聚合的乙烯基芳族单体的氢化SDS或SHDS嵌段共聚物，聚苯乙烯端嵌段一起以嵌段共聚物的20-30重量％ 不包括聚二烯中间嵌段中聚苯乙烯的重量; （iii）具有> 1％但<2％的官能度的官能化“高橡胶”SHDS，“小端嵌段”一起存在于约8-25重量％的范围内; （iv）0-30重量％的组合物，官能化聚烯烃（F3），具有2至4个碳原子的烯烃; （v）0-15重量％的组合物，氢化非官能化氢化聚苯乙烯 - 聚（共轭二烯） - 聚苯乙烯（SHDS）嵌段共聚物; 和（vi）增加组合物使用寿命的添加剂。
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公开(公告)号：US06368700B1
公开(公告)日：2002-04-09
申请号：US09393731
申请日：1999-09-10
IPC分类号： B32B702
CPC分类号： B32B7/02 , B32B27/08 , B32B27/32 , B32B2307/536 , B32B2307/712 , B32B2323/10 , B32B2605/08 , B60J10/17 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L51/06 , C08L75/00 , C08L75/04 , C08L2205/03 , C08L2205/04 , C08L2205/22 , C09D123/10 , Y10T428/24777 , Y10T428/24802 , Y10T428/24983 , C08L2666/24 , C08L2666/20 , C08L2666/02
摘要： A weatherseal or belt-line seal for a vehicle is formed by extrusion of an olefin-based thermoplastic elastomer or vulcanizate (first TPV) as an elongate body of arbitrary length and cross-section. The cross-section is adapted for use in a particular location in the opening of a structure to be protected against wind and rain, for example around the glass of a window in a vehicle's door, or around the opening (at the periphery) in which the door is closed, so as to present at least one sealing surface against which the glass or door may be abutted to provide a seal against the elements. A slip-coating is co-extruded onto one or more longitudinal sealing surfaces of the body; the slip-coating contains a novel compatibilizer which allows thermoplastic polyurethane (TPU) to be chemically bonded to a graft copolymer of polypropylene (PP) and a compound having two anhydride groups. The reaction product of the grafted PP and the TPU effects a thermal bond with the sealing surface of the body. The slip-coating has a combination of softness and abrasion resistance which are uniquely suited for the purpose of the weatherseal.
摘要翻译： 用于车辆的耐候密封带或带状线密封件是通过挤出作为任意长度和横截面的细长体的烯烃类热塑性弹性体或硫化橡胶（第一TPV）形成的。 横截面适用于要防止风雨的结构的开口中的特定位置，例如在车辆门的窗户玻璃周围或围绕开口（在周边）处，其中 门关闭，以便呈现至少一个密封表面，玻璃或门可抵靠该密封表面以抵靠元件提供密封。 滑动涂层共挤出到主体的一个或多个纵向密封表面上; 滑移涂层含有一种新颖的相容剂，其允许热塑性聚氨酯（TPU）与聚丙烯（PP）和具有两个酸酐基团的化合物的接枝共聚物化学键合。 接枝PP和TPU的反应产物与本体的密封面发生热粘合。 滑爽涂层具有柔软性和耐磨性的组合，其特别适用于耐候密封胶的目的。
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23.发明授权Thermoplastic elastomer triblend from an engineering thermoplastic, functionalized ethylene and or diene polymer, and brominated isobutylene p-methylstyrene copolymer 失效来自工程热塑性塑料，功能化乙烯和/或二烯聚合物和溴化异丁烯对甲基苯乙烯共聚物的热塑性弹性体
公开(公告)号：US6069202A
公开(公告)日：2000-05-30
申请号：US987989
申请日：1997-12-10
IPC分类号： C08L7/00 , C08L9/00 , C08L23/26 , C08L23/28 , C08L63/00 , C08L77/00 , C08L77/06 , C08L67/00 , C08L77/12 , C08L81/00
摘要： Desirable thermoplastic vulcanizates can be prepared from a polar engineering thermoplastic; a halogenated copolymer of p-alkylstyrene and an isomonoolefin having from 4 to 7 carbon atoms; and either an ethylene rubbery polymer or a diene based rubbery polymer or combinations thereof. The ethylene rubbery polymer desirably has at least one pendant carboxylic acid group, amine group, epoxy group, hydroxyl group or an anhydride of two carboxylic acid groups or combinations thereof. Desirable diene based rubbery polymers include epoxidized natural rubber and epoxidized homopolymers and copolymers of dienes.
摘要翻译： 希望的热塑性硫化橡胶可以由极性工程热塑性塑料制成; 对烷基苯乙烯和具有4至7个碳原子的异单烯烃的卤代共聚物; 和乙烯橡胶状聚合物或二烯基橡胶状聚合物或其组合。 乙烯橡胶状聚合物理想地具有至少一个羧酸侧基，胺基，环氧基，羟基或两个羧酸基的酸酐或其组合。 理想的二烯基橡胶状聚合物包括环氧化天然橡胶和二烯的环氧化均聚物和共聚物。
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24.发明授权
公开(公告)号：US5942577A
公开(公告)日：1999-08-24
申请号：US926672
申请日：1997-09-09
申请人： Krishna Venkataswamy
发明人： Krishna Venkataswamy
IPC分类号： C08K5/47 , C08L33/06 , C08L33/08 , C08L67/02 , C08L69/00 , C08L77/00 , C08L77/06 , C08L33/14
摘要： A thermoplastic elastomer is formed from a thermoplastic polymer such as a polyester, polycarbonate, or combinations thereof or a polyamide, which polymer is melt blended with an acrylic rubber. The acrylic rubber desirably has from about 0.5 to about 5 mole percent repeat units from halogen (desirably chlorine) containing monomer. Subsequently the acrylic rubber is crosslinked with 2,5-mercapto-1,3,4-thiadiazole or a derivative thereof. Such a thermoplastic elastomer may have a compression set less than 50% making it useful in applications involving continuous use under compression.
摘要翻译： 热塑性弹性体由热塑性聚合物如聚酯，聚碳酸酯或其组合或聚酰胺形成，该聚合物与丙烯酸橡胶熔融共混。 丙烯酸橡胶理想地具有约0.5至约5摩尔％的含卤素（所需氯）单体的重复单元。 随后丙烯酸橡胶与2,5-巯基-1,3,4-噻二唑或其衍生物交联。 这种热塑性弹性体可以具有小于50％的压缩永久变形，使其在涉及在压缩下连续使用的应用中是有用的。
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25.发明授权Processes for producing thermoplastic elastomers having improved engineering performance 失效制造具有改进的工程性能的热塑性弹性体的方法
公开(公告)号：US5936039A
公开(公告)日：1999-08-10
申请号：US967057
申请日：1997-11-10
IPC分类号： B01F5/00 , C08L23/00 , C08L23/02 , C08L23/10 , C08L23/16 , C08L67/00 , C08L77/00 , C08L101/00 , C08L9/00
摘要： Processes for the preparation of a thermoplastic elastomer comprising a triblend of engineering resin, dynamically vulcanized alloy of thermoplastic olefin polymer and elastomeric copolymer, and a compatibilizer for the engineering resin and alloy. The compatibilizer can be formed in a separate step or in-situ in a one step process. The processes produce compositions which retain structural integrity at high temperature, and have good tensile properties, elongation and fluid resistance.
摘要翻译： 制备热塑性弹性体的方法，该热塑性弹性体包含工程树脂的三元组，热塑性烯烃聚合物的动态硫化合金和弹性共聚物，以及用于工程树脂和合金的增容剂。 增容剂可以在单独的步骤中形成或在一步法中原地形成。 该方法产生在高温下保持结构完整性并具有良好的拉伸性能，伸长率和耐流体性的组合物。
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公开(公告)号：US5574105A
公开(公告)日：1996-11-12
申请号：US439738
申请日：1995-05-12
申请人： Krishna Venkataswamy
发明人： Krishna Venkataswamy
IPC分类号： C08L23/04 , C08L23/10 , C08L23/16 , C08L23/18 , C08L23/20 , C08L23/22 , C08L23/28 , C08L51/06 , C08L67/00 , C08L67/02 , C08L77/00 , C08F8/00 , C08F8/42 , C08L77/04
CPC分类号： C08L77/00 , C08L23/10 , C08L23/283 , C08L51/06 , C08L2205/08 , C08L2205/22 , C08L23/16
摘要： A thermoplastic elastomer comprising a triblend of engineering resin, dynamically vulcanized alloy of thermoplastic olefin polymer and elastomeric copolymer, and a compatibilizer for the engineering resin and alloy. The compositions retain structural integrity at high temperature, and have good tensile properties, elongation and fluid resistance.
摘要翻译： 一种热塑性弹性体，其包括工程树脂的三元组，热塑性烯烃聚合物的动态硫化合金和弹性体共聚物，以及用于工程树脂和合金的增容剂。 组合物在高温下保持结构完整性，并且具有良好的拉伸性能，伸长率和耐流体性。
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公开(公告)号：US5523350A
公开(公告)日：1996-06-04
申请号：US408771
申请日：1995-03-23
IPC分类号： C08F8/00
CPC分类号： C08L23/0869 , C08L2312/00
摘要： The thermoplastic elastomer compositions contain a continuous phase or matrix of an engineering thermoplastic such as ester polymer and a discontinuous phase of an acrylic rubber which is cured substantially by using epoxidized oils. The cured composition which can be dynamically vulcanized has good physical properties such as tensile strength, elongation, and high temperature resistance.
摘要翻译： 热塑性弹性体组合物包含工程热塑性塑料的连续相或基质，例如酯聚合物和基本上通过使用环氧化油固化的丙烯酸橡胶的不连续相。 可以动态硫化的固化组合物具有良好的物理性能，例如拉伸强度，伸长率和耐高温性。
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