公开(公告)号：US20070237968A1

公开(公告)日：2007-10-11

申请号：US11758360

申请日：2007-06-05

申请人： Yoshifumi Kijima ,  Toshiaki Anzaki ,  Daisuke Inaoka ,  Hiromasa Wada

发明人： Yoshifumi Kijima ,  Toshiaki Anzaki ,  Daisuke Inaoka ,  Hiromasa Wada

IPC分类号： B32B17/06

CPC分类号： C03C17/36 ,  B01J35/004 ,  C03C2217/71 ,  C03C2218/365

摘要： The present invention provides a glass member including a photocatalyst layer and a heat reflecting layer, the glass member having high photocatalytic activity and exhibiting a low reflectance and a colorless or pale blue reflection color tone or a bluish green or green reflection color tone. The glass member is produced by laminating an antistripping layer made of silicon oxide or the like, a crystalline undercoat layer made of zirconium oxide or the like and a photocatalyst layer made of titanium oxide or the like on the other surface of a glass substrate having a heat reflecting layer formed on one surface thereof. The heat reflecting layer is formed such that the other surface of the glass substrate has a reflection chromaticity (a*, b*) satisfying −4≦a*≦2 and −5≦b*≦0 and a visible light reflectance of 10% or less, the crystalline undercoat layer is allowed to have a thickness ranging from 2 to 28 nm, and the photocatalyst layer is allowed to have a thickness ranging from 2 to 20 nm, whereby the glass member having a colorless or pale blue reflection color tone can be produced. Likewise, the heat reflecting layer is formed such that the reflection chromaticity (a*, b*) satisfies −15≦a*≦−2 and −10≦b*≦10 and the visible light reflectance is 13% or less, the crystalline undercoat layer is allowed to have a thickness ranging from 2 to 28 nm, and the photocatalyst layer is allowed to have a thickness ranging from 2 to 14 nm, whereby the glass member having a bluish green or green reflection color tone can be produced.

摘要翻译： 本发明提供一种玻璃构件，其包含光催化剂层和热反射层，该玻璃构件具有高的光催化活性并且具有低反射率和无色或浅蓝色反射色调或蓝绿色或绿色反射色调。 玻璃构件通过层压由氧化硅等制成的防夹层，由氧化锆等制成的结晶底涂层和由氧化钛等制成的光催化剂层而制成，在玻璃基板的另一表面上具有 在其一个表面上形成热反射层。 热反射层形成为使得玻璃基板的另一个表面具有满足-4 <= a * <= 2和-5 <= b * <= 0的反射色度（a *，b *）和可见光 反射率为10％以下，使结晶性底涂层的厚度为2〜28nm，使光催化剂层的厚度范围为2〜20nm，由此玻璃构件具有无色或浅色 可以产生蓝色反射色调。 同样地，热反射层形成为使得反射色度（a *，b *）满足-15 <= a * <= - 2和-10 <= b * <= 10，可见光反射率为13％ 使得结晶底涂层的厚度为2〜28nm，使光催化剂层的厚度为2〜14nm，由此，具有蓝绿色或绿色反射色调的玻璃构件可以 生产。

公开(公告)号：US20060051597A1

公开(公告)日：2006-03-09

申请号：US10518601

申请日：2003-06-17

申请人： Toshiaki Anzaki ,  Daisuke Inaoka ,  Yoshifumi Kijima

发明人： Toshiaki Anzaki ,  Daisuke Inaoka ,  Yoshifumi Kijima

IPC分类号： C23C14/32 ,  B32B17/06 ,  B32B15/04 ,  C23C14/00

CPC分类号： C23C14/3414 ,  C03C17/2456 ,  C03C2217/212 ,  C03C2217/24 ,  C03C2218/155 ,  Y10T428/31678

摘要： The present invention provides a method for forming a titanium compound film on a substrate by a sputtering process by use of, in place of a conventional metallic titanium target, a titanium target containing a metal (such as tin or zinc) having two or more times higher sputtering yield in an argon atmosphere than titanium; an article coated with a titanium compound film; and a sputtering target for use in the film coating. The content of tin or zinc in the titanium target containing tin or zinc is preferably in the range of 1 to 45 at %, and further a third metal may be added. These can remove drawbacks in that the film has a low film formation rate and a high output power cannot be applied due to the occurrence of arcing in forming a titanium compound film on the surface of a substrate, such as plate-shaped glass, by a reactive sputtering process.

摘要翻译： 本发明提供一种通过溅射法在基板上形成钛化合物膜的方法，其中使用代替常规金属钛靶的含有两次或更多次金属（例如锡或锌）的钛靶 在氩气氛中钛的溅射产率更高; 涂有钛化合物膜的制品; 以及用于膜涂层的溅射靶。 含有锡或锌的钛靶中的锡或锌的含量优选为1〜45原子％，进一步添加第3金属。 这些可以消除薄膜形成速度低的缺陷，并且由于在诸如板状玻璃的基板的表面上形成钛化合物膜时由于发生电弧而不能施加高的输出功率 反应溅射工艺。

公开(公告)号：US07006291B2

公开(公告)日：2006-02-28

申请号：US10630925

申请日：2003-07-31

申请人： Masahiro Hori ,  Teruyuki Sasaki ,  Hiroaki Yamamoto ,  Kentaro Fukuda ,  Kenichi Yamada ,  Toshiaki Anzaki ,  Kenjiro Hamanaka ,  Koichiro Nakamura ,  Masaatsu Kido

发明人： Masahiro Hori ,  Teruyuki Sasaki ,  Hiroaki Yamamoto ,  Kentaro Fukuda ,  Kenichi Yamada ,  Toshiaki Anzaki ,  Kenjiro Hamanaka ,  Koichiro Nakamura ,  Masaatsu Kido

IPC分类号： G02B1/10

CPC分类号： G02B1/14 ,  G02B1/041 ,  G02B1/105 ,  G02B1/113 ,  G02B3/0006 ,  G02B3/0031 ,  G02B3/0056 ,  C08L63/00

摘要： The optical device having a predetermined surface profile of the invention is fabricated by forming a multi-layered dielectric film on the surface of a solid composition layer having a glass transition temperature of not lower than 100° C. The solid composition layer is formed by molding and curing a polymerizable organic group-having fluid composition. The curing may be effected through photopolymerization or thermal polymerization of the polymerizable organic group in the composition, and a predetermined surface profile is transferred onto the composition layer from the mold used. The cured composition is released from the mold, and this is coated with a multi-layered dielectric film.

摘要翻译： 通过在玻璃化转变温度不低于100℃的固体组合物层的表面上形成多层电介质膜来制造具有本发明的预定表面轮廓的光学装置。固体组合物层通过模制 并固化具有可聚合的含有机基团的流体组合物。 可以通过组合物中的可聚合有机基团的光聚合或热聚合来实现固化，并且将预定的表面轮廓从所使用的模具转移到组合物层上。 固化的组合物从模具中释放，并用多层电介质膜涂覆。

公开(公告)号：US06419800B2

公开(公告)日：2002-07-16

申请号：US09764520

申请日：2001-01-18

申请人： Toshiaki Anzaki ,  Kenji Mori

发明人： Toshiaki Anzaki ,  Kenji Mori

IPC分类号： C23C1435

CPC分类号： C23C14/352 ,  C23C14/505 ,  C23C14/544 ,  C23C14/545 ,  G02B1/10 ,  H01J37/3405

摘要： There may be used a film-forming apparatus having a substrate 4 that is rotatable around the center of one rotating axis 10 in the vertical direction situated in an inner cylinder 12, and a plurality (four in FIG. 2) of target units each comprising the pair of targets 2A, 2B (2B is under 2A serially arranged in the vertical direction inside an outer cylinder 13 opposite the surface 4a of the substrate 4, which are arranged in parallel in the circumferential direction of the inner wall of the outer cylinder 13. By employing a method whereby voltage is applied while alternatively reversing the polarity to each of the targets 2A, 2B, it is possible to form a coating on the surface of a substrate by glow discharge sputtering, to accomplish destaticizing while the sputtering can be carried out using a small in-line or bell jar apparatus with small space.

摘要翻译： 可以使用具有基板4的膜形成装置，该基板4可以在位于内筒12中的垂直方向上围绕一个旋转轴线10的中心旋转，并且多个（图2中的四个）各自包括 一对目标2A，2B（2B）在与外筒13的内壁的圆周方向平行布置的外筒13的与基板4的表面4a相对的外侧的垂直方向下排列为2A以下 通过采用施加电压的方法，同时交替地将极性反转到每个靶2A，2B，可以通过辉光放电溅射在衬底的表面上形成涂层，从而在可以承载溅射的情况下实现静电化 使用小空间的小型在线或钟形瓶装置。