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公开(公告)号：US08318013B2
公开(公告)日：2012-11-27
申请号：US13329401
申请日：2011-12-19
申请人： Lubo Zhou , Chunqing Liu , Carlos A. Cabrera , Peter K. Coughlin
发明人： Lubo Zhou , Chunqing Liu , Carlos A. Cabrera , Peter K. Coughlin
CPC分类号： B01D53/228 , B01D67/0006 , B01D71/62 , B01D2256/16 , B01D2256/24 , B01D2257/504 , B01D2258/06 , B01D2323/30 , B01D2323/345 , Y02C10/10
摘要： The present invention involves the use of a multi-stage membrane system for gas, vapor, and liquid separations. In this multi-stage membrane system, high selectivity and high permeance or at least high selectivity polybenzoxazole membranes or cross-linked polybenzoxazole membranes are applied for a pre-membrane or both the pre-membrane and the secondary membrane. A primary membrane can be from conventional glassy polymers. This multi-stage membrane system can reduce inter-stage compression cost, increase product recovery and product purity for gas, vapor, and liquid separations. It can also save the cost compared to the system using all the high cost polybenzoxazole membranes or cross-linked polybenzoxazole membranes.
摘要翻译： 本发明涉及使用多级膜系统进行气体，蒸汽和液体分离。 在该多级膜系统中，对膜前或膜前和膜进行二次膜的预选择，高选择性和高渗透性或至少高选择性的聚苯并恶唑膜或交联聚苯并恶唑膜。 初级膜可以来自常规玻璃状聚合物。 这种多级膜系统可以降低气体，蒸汽和液体分离的阶段间压缩成本，提高产品回收率和产品纯度。 与使用所有高成本聚苯并恶唑膜或交联聚苯并恶唑膜的系统相比，还可以节省成本。
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22.发明授权公开(公告)号：US07166149B2
公开(公告)日：2007-01-23
申请号：US10755453
申请日：2004-01-12
IPC分类号： B01D53/06
CPC分类号： B01D53/261 , B01D53/0462 , B01D53/06 , B01D2253/108 , B01D2253/25 , B01D2256/24 , B01D2256/245 , B01D2257/2045 , B01D2257/2066 , B01D2257/80 , B01D2259/40052 , B01D2259/40081 , B01D2259/4009 , B01D2259/402
摘要： Using a high pressure rotary adsorbent wheel, a high value compressed gas feed can be purified by concentrating the impurity such as water, condensing it out, before final purification. Instead of exhausting gas from the system, the effluent can be put back into the feed at a point prior to condensation of the high value gas feed, and therefore the entire feed is purified without any high value gas feed going into a waste stream.
摘要翻译： 使用高压旋转吸附轮，可以在最终净化之前将杂质如水浓缩，冷凝出来，从而净化高价值的压缩气体进料。 代替从系统中排出气体，流出物可以在高价值气体进料冷凝之前的某一点被放回到进料中，因此整个进料被纯化，没有任何高价值的气体进料进入废物流。
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公开(公告)号：US4904518A
公开(公告)日：1990-02-27
申请号：US213261
申请日：1988-06-29
IPC分类号： B32B18/00
CPC分类号： B32B18/00 , C04B2237/34 , C04B2237/341 , C04B2237/343 , C04B2237/346 , C04B2237/348 , C04B2237/38 , C04B2237/704 , Y10T428/24802 , Y10T428/24851 , Y10T428/249969 , Y10T428/24999 , Y10T428/26 , Y10T428/261 , Y10T428/263
摘要： This invention relates to multi-compositional, multiphase composite compositions comprising as phases thereof (i) an electronically conducting or semi-conducting substrate, (ii) an inorganic oxide composition layer in proximity to at least a portion of the surface of said electrically conducting or semi-conducting substrate and (iii) an inorganic crystalline molecular sieve composition layer upon at least a portion of the surface of said inorganic oxide composition layer. The inorganic crystalline molecular sieve composition layer is grown by crystal growth upon at least a portion of the inorganic oxide composition layer surface. The different phases of the composite compositions are substantially contiguous and exhibit a distinct compositional and/or structural heterogeneity of one phase to another. The multi-compositional, multiphase composite compositions have beneficial utility as a moisture sensing element in an electric hydrometer which measures the moisture content of moisture-containing systems by change in electrical impedance. This invention also relates to processes for preparing the multi-compositional, multiphase composite compositions.
摘要翻译： 本发明涉及多组合多相复合材料组合物，其包含其相（i）电子导电或半导电基材，（ii）无机氧化物组合物层，其接近所述导电或半导电基材表面的至少一部分， 半导体基材和（iii）在所述无机氧化物组合物层的至少一部分表面上的无机结晶分子筛组合物层。 无机结晶分子筛组合物层通过在无机氧化物组合物层表面的至少一部分上的晶体生长而生长。 复合组合物的不同相基本上是连续的，并且表现出一个相与另一相的不同组成和/或结构异质性。 多组分多相复合组合物作为电子比重计中的湿度感测元件具有有益的用途，其通过电阻抗的变化来测量含湿系统的含水量。 本发明还涉及制备多组分多相复合组合物的方法。
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24.发明授权Polymer membranes prepared from aromatic polyimide membranes by thermal treating and UV crosslinking 有权通过热处理和UV交联由芳族聚酰亚胺膜制备的聚合物膜公开(公告)号：US09138692B2
公开(公告)日：2015-09-22
申请号：US13547313
申请日：2012-07-12
申请人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Minkov , Lubo Zhou
发明人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Minkov , Lubo Zhou
CPC分类号： B01D71/62 , B01D53/228 , B01D67/0093 , B01D2323/08 , B01D2323/30 , B01D2323/345 , C08G73/1039 , C08G73/1042 , C08G73/1046 , C08G73/1064 , C08G73/16 , C08L79/08 , Y02C20/20
摘要： The present invention discloses a new type of high performance polymer membranes prepared from aromatic polyimide membranes by thermal treating and crosslinking and methods for making and using these membranes. The polymer membranes were prepared from aromatic polyimide membranes by thermal treating under inert atmosphere followed by crosslinking preferably by using a UV radiation source. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The membranes showed significantly improved selectivity and permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The membranes can be fabricated into any convenient geometry and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used for other applications such as for catalysis and fuel cell applications.
摘要翻译： 本发明公开了通过热处理和交联由芳族聚酰亚胺膜制备的新型高性能聚合物膜以及制造和使用这些膜的方法。 聚合物膜由芳族聚酰亚胺膜通过在惰性气氛下热处理制备，然后优选通过使用UV辐射源进行交联。 芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。 与没有任何处理的芳族聚酰亚胺膜相比，膜显示出气体分离的选择性和渗透性显着提高。 膜可以制造成任何方便的几何形状，并且不仅适用于各种液体，气体和蒸汽分离，而且还可以用于其它应用，例如用于催化和燃料电池应用。
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公开(公告)号：US08613362B2
公开(公告)日：2013-12-24
申请号：US12412653
申请日：2009-03-27
申请人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
发明人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
CPC分类号： B01D71/64 , B01D67/0088 , B01D2323/08 , B01D2323/30
摘要： The present invention discloses a new type of high performance polymer membranes derived from aromatic polyimide membranes and methods for making and using these membranes. The polymer membranes described in the present invention were derived from aromatic polyimide membranes by crosslinking followed by thermal treating. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The high performance polymer membranes showed significantly improved permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The high performance polymer membranes also showed significantly improved selectivity for gas separations compared to the thermal-treated but non-UV-crosslinked aromatic polyimide membranes. The high performance polymer membranes of the present invention are suitable for liquid, gas, and vapor separations, as well as for catalysis and fuel cell applications.
摘要翻译： 本发明公开了一种衍生自芳族聚酰亚胺膜的新型高性能聚合物膜以及制造和使用这些膜的方法。 本发明中描述的聚合物膜通过交联然后进行热处理从芳族聚酰亚胺膜得到。 芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。 与没有任何处理的芳族聚酰亚胺膜相比，高性能聚合物膜显示出显着改善气体分离的渗透性。 与热处理但非UV交联的芳族聚酰亚胺膜相比，高性能聚合物膜还显示出对气体分离的选择性显着提高。 本发明的高性能聚合物膜适用于液体，气体和蒸汽分离，以及催化和燃料电池应用。
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26.发明授权Polymer membranes prepared from aromatic polyimide membranes by thermal treating and UV crosslinking 有权通过热处理和UV交联由芳族聚酰亚胺膜制备的聚合物膜公开(公告)号：US08241501B2
公开(公告)日：2012-08-14
申请号：US13165939
申请日：2011-06-22
申请人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Minkov , Lubo Zhou
发明人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Minkov , Lubo Zhou
CPC分类号： B01D71/62 , B01D53/228 , B01D67/0093 , B01D2323/08 , B01D2323/30 , B01D2323/345 , C08G73/1039 , C08G73/1042 , C08G73/1046 , C08G73/1064 , C08G73/16 , C08L79/08 , Y02C20/20
摘要： The present invention discloses a new type of high performance polymer membranes prepared from aromatic polyimide membranes by thermal treating and crosslinking and methods for making and using these membranes. The polymer membranes were prepared from aromatic polyimide membranes by thermal treating under inert atmosphere followed by crosslinking preferably by using a UV radiation source. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The membranes showed significantly improved selectivity and permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The membranes can be fabricated into any convenient geometry and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used for other applications such as for catalysis and fuel cell applications.
摘要翻译： 本发明公开了通过热处理和交联由芳族聚酰亚胺膜制备的新型高性能聚合物膜以及制造和使用这些膜的方法。 聚合物膜由芳族聚酰亚胺膜通过在惰性气氛下热处理制备，然后优选通过使用UV辐射源进行交联。 芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。 与没有任何处理的芳族聚酰亚胺膜相比，膜显示出气体分离的选择性和渗透性显着提高。 膜可以制造成任何方便的几何形状，并且不仅适用于各种液体，气体和蒸汽分离，而且还可以用于其它应用，例如用于催化和燃料电池应用。
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公开(公告)号：US4860584A
公开(公告)日：1989-08-29
申请号：US213239
申请日：1988-06-29
CPC分类号： G01N27/225 , G01N27/121
摘要： A moisture sensing element is disclosed which comprises an electrically continuous article comprising a multi-compositional, multi-phase composite composition comprising as phases thereof (i) an electrically conducting or semiconducting substrate, (ii) an inorganic oxide composition layer in proximity to at least a portion of the surface of the electrically conducting or semiconducting substrate and (iii) an inorganic crystalline molecular sleeve composition layer upon at least a portion of the surface of the inorganic oxide composition layer, wherein the different phases of the composite composition are substantially contiguous and exhibit at least one of a distinct compositional heterogeneity and a distinct structural heterogeneity of one phase to the other; and at least one electrode affixed to the article in current carrying relationship so that the current carried by the electrode passes through at least a portion of the inorganic crystalline molecular sieve composition layer.
摘要翻译： 公开了一种湿度感测元件，其包括电连续制品，其包含多组分多相复合材料组合物，其包含其相位（i）导电或半导体衬底，（ii）至少接近于无机氧化物组合物层 所述导电或半导体衬底的表面的一部分和（iii）无机氧化物组合物层的表面的至少一部分上的无机结晶分子套管组合物层，其中所述复合组合物的不同相基本上是连续的， 表现出一个阶段与另一个阶段的不同组成异质性和不同结构异质性中的至少一个; 以及至少一个电极以电流携带关系固定在制品上，使得由电极承载的电流通过至少一部分无机结晶分子筛组合物层。
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公开(公告)号：US4740648A
公开(公告)日：1988-04-26
申请号：US906895
申请日：1986-09-15
申请人： Jule A. Rabo , Peter K. Coughlin
发明人： Jule A. Rabo , Peter K. Coughlin
CPC分类号： B01J29/084 , C07C2/00 , C07C2529/08
摘要： Linear and/or branched claim C.sub.2 to C.sub.12 olefins are converted to hydrocarbon mixtures suitable for use as liquid motor fuels by contact with a catalyst capable of ensuring the production of desirable products with only a relatively minor amount of heavy products boiling beyond the diesel oil range. The catalyst having desirable stability during continuous production operations, comprises a steam stabilized zeolite Y catalyst of hydrophobic character, desirably in aluminum-extracted form. The olefins such as propylene, may be diluted with inerts, such as paraffins or with water, the latter serving to moderate the acidity of the catalyst, or to further moderate the activity of the aluminum-extracted catalyst, so as to increase the effective life of the catalyst.
摘要翻译： 直链和/或支链的C 2 -C 12烯烃转化为适合用作液体发动机燃料的烃混合物，其通过与能够确保产生理想产物的催化剂接触，所述催化剂仅具有相对较少量的超过柴油范围的重质产物 。 在连续生产操作期间具有期望稳定性的催化剂包括具有疏水性的蒸汽稳定的沸石Y催化剂，希望是铝提取形式。 烯烃如丙烯可以用惰性物质例如链烷烃或水稀释，后者用于调节催化剂的酸度，或进一步降低铝提取催化剂的活性，从而提高有效寿命 的催化剂。
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29.发明授权
公开(公告)号：US4663355A
公开(公告)日：1987-05-05
申请号：US865468
申请日：1986-05-21
申请人： Peter K. Coughlin
发明人： Peter K. Coughlin
IPC分类号： B01J23/75 , B01J23/89 , B01J29/08 , B01J29/14 , B01J29/76 , B01J29/85 , B01J37/04 , C07C1/04
CPC分类号： B01J23/8913 , B01J23/75 , B01J23/8933 , B01J29/084 , B01J29/146 , B01J29/76 , B01J29/85 , B01J37/04 , C07C1/0435 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2523/04 , C07C2523/12 , C07C2523/50 , C07C2523/52 , C07C2523/72 , C07C2523/75 , C07C2523/89 , C07C2529/14 , C07C2529/85
摘要： The addition of an inert metal component, such as gold, silver or copper, to a Fischer-Tropsch catalyst comprising cobalt enables said catalyst to convert synthesis gas to liquid motor fuels at about 240.degree.-370.degree. C. with advantageously reduced selectivity of said cobalt for methane in said conversion. The catalyst composition can advantageously include a support component, such as a molecular sieve, co-catalyst/support component or a combination of such support components.
摘要翻译： 将惰性金属组分如金，银或铜添加到包含钴的费 - 托催化剂中使得所述催化剂能够在约240-370℃下将合成气转化为液体运动燃料，同时有利地降低所述 所述转化中的甲烷钴。 催化剂组合物可以有利地包括载体组分，例如分子筛，助催化剂/载体组分或这些载体组分的组合。
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公开(公告)号：US08454727B2
公开(公告)日：2013-06-04
申请号：US13099883
申请日：2011-05-03
申请人： Lubo Zhou , Peter K. Coughlin , Pamela J. Dunne
发明人： Stephen R. Dunne , Lubo Zhou , Peter K. Coughlin
IPC分类号： B01D53/22
CPC分类号： B01D53/22 , B01D53/1443 , B01D53/1456 , B01D53/229 , B01D53/62 , B01D53/75 , B01D2252/20447 , B01D2252/20484 , B01D2252/20489 , B01D2253/108 , B01D2256/22 , B01D2256/245 , B01D2257/302 , B01D2257/304 , B01D2257/404 , B01D2257/504 , B01D2259/4566 , B01D2317/022 , C10L3/104 , Y02C10/04 , Y02C10/06 , Y02C10/08 , Y02C10/10
摘要： The present invention provides a process for treating a natural gas stream comprising sending a natural gas stream to at least one membrane unit to produce a permeate stream containing a higher concentration of carbon dioxide and a retentate stream containing a lower concentration of carbon dioxide. Then the retentate stream is sent to an adsorbent bed to remove carbon dioxide and other impurities to produce a natural gas product stream. The regeneration gas stream is sent through the molecular sieve adsorbent bed to desorb the carbon dioxide. In one process flow scheme, the regeneration stream is combined with the permeate stream from the membrane unit. Then the combined stream is sent to an absorbent column to remove carbon dioxide from the permeate stream to produce a second natural gas product stream. In the alternative flow scheme, a second membrane unit is used to improve efficiency.
摘要翻译： 本发明提供一种处理天然气流的方法，包括将天然气流送至至少一个膜单元以产生含有较高浓度二氧化碳的渗透物流和含有较低浓度二氧化碳的滞留物流。 然后将滞留物流送入吸附床以除去二氧化碳和其它杂质以产生天然气产物流。 再生气流通过分子筛吸附剂床排出以解吸二氧化碳。 在一个工艺流程图中，再生流与来自膜单元的渗透物流组合。 然后将合并的流送到吸收塔以从渗透物流中除去二氧化碳，以产生第二天然气产物流。 在替代流程中，使用第二膜单元来提高效率。
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