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21.发明授权
公开(公告)号：US5057295A
公开(公告)日：1991-10-15
申请号：US845255
申请日：1986-03-28
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of BO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(B.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline port system; "m" represents the molar amount of "R" present per mole of (B.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fraction of boron, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有BO2，AlO2，PO2和SiO2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（BwAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（BwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的硼，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US5032368A
公开(公告)日：1991-07-16
申请号：US830890
申请日：1986-02-19
IPC分类号： B01J29/84 , C01B25/45 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of GaO.sub.2, AlO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Ga.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Ga.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of gallium, aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有GaO2，AlO2和PO2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（GaxAlyPz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（GaxAlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的镓，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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23.发明授权
公开(公告)号：US4992250A
公开(公告)日：1991-02-12
申请号：US852175
申请日：1986-04-15
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of GeO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Ge.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" represent per mole of (Ge.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" present the mole fractions of germanium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as absorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有GeO 2，AlO 2，PO 2和SiO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（GewAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（GewAlxPySiz）O 2的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的锗，铝，磷和硅的摩尔分数。 还公开了它们作为吸收剂，催化剂等的用途。
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公开(公告)号：US4985151A
公开(公告)日：1991-01-15
申请号：US409531
申请日：1989-09-19
申请人： Brent M. T. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
发明人： Brent M. T. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S95/902
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of ELO.sub.2, SiO.sub.2 and PO.sub.2 framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; "EL" represents at least one element capable of forming a framework oxide unit; and "w", "x", "y" and "z" represent the mole fractions of elements(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有ELO2，SiO2和PO2骨架氧化物单元的三维微孔骨架结构的结晶分子筛。 分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（ELwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（ELwAlxPySiz）O 2存在的“R”摩尔量; “EL”表示能够形成骨架氧化物单元的至少一种元素; 和“w”，“x”，“y”和“z”分别表示作为骨架氧化物存在的元素“EL”，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4973785A
公开(公告)日：1990-11-27
申请号：US182738
申请日：1988-04-18
申请人： Brent M. T. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
发明人： Brent M. T. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of ELO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; "EL" represents at least one element capable of forming a framework oxide unit; and "w", "x", "y" and "z" represent the mole fractions of element(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有ELO2，AlO2，SiO2和PO2骨架氧化物单元的三维微孔骨架结构的结晶分子筛。 分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（ELwAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（ELwAlxPySiz）O 2存在的“R”摩尔量; “EL”表示能够形成骨架氧化物单元的至少一种元素; 和“w”，“x”，“y”和“z”分别表示作为骨架氧化物存在的元素“EL”，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4952383A
公开(公告)日：1990-08-28
申请号：US029540
申请日：1987-03-24
IPC分类号： B01J20/18 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Molecular sieves having three-dimensional microporous framework structures of BO.sub.2, AlO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (B.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (B.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of boron, aluminum and phosphorus, respectively, present as tetrahedral oxides. The use of these molecular sieves as adsorbents, catalysts etc. is also disclosed.
摘要翻译： 公开了具有BO2，AlO2和PO2四面体单元的三维微孔骨架结构的分子筛。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（BxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（BxAlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的硼，铝和磷的摩尔分数。 还公开了使用这些分子筛作为吸附剂，催化剂等。
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公开(公告)号：US4793984A
公开(公告)日：1988-12-27
申请号：US600312
申请日：1984-04-13
申请人： Brent M. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
发明人： Brent M. Lok , Bonita K. Marcus , Lawrence D. Vail , Edith M. Flanigen , Robert L. Patton , Stephen T. Wilson
IPC分类号： B01J20/18 , B01J29/04 , B01J29/85 , C01B37/06 , C01B37/08 , C01B39/04 , C01B39/10 , C01B39/12 , C07B61/00 , C07C2/12 , C07C2/54 , C07C2/70 , C07C2/86 , C07C4/06 , C07C4/08 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C01B25/26 , B01J27/182
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of ELO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system: "m" represents the molar amount of "R" present per mole of (El.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; "EL" represents at least one element capable of forming a framework oxide unit; and "w", "x", "y" and "z" represent the mole fractions of element(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有ELO2，AlO2，SiO2和PO2骨架氧化物单元的三维微孔骨架结构的结晶分子筛。 分子筛具有由下式表示的无水基础上的经验化学组成：mR：（ELwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂：“m”表示“ 每摩尔（ElwAlxPySiz）O2存在R“ “EL”表示能够形成骨架氧化物单元的至少一种元素; 和“w”，“x”，“y”和“z”分别表示作为骨架氧化物存在的元素“EL”，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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28.发明授权
公开(公告)号：US4735806A
公开(公告)日：1988-04-05
申请号：US845985
申请日：1986-03-31
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C01B25/26 , B01J27/182
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of GaO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Ga.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Ga.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of gallium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有GaO 2，AlO 2，PO 2和SiO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（GawAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（GawAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的镓，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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29.发明授权Molecular sieve compositions with aluminum, phosphorus and at least two other elements 失效具有铝，磷和至少两种其他元素的分子筛组合物
公开(公告)号：US4686093A
公开(公告)日：1987-08-11
申请号：US600171
申请日：1984-04-13
IPC分类号： B01D53/28 , B01J20/02 , B01J20/08 , B01J27/18 , B01J29/00 , B01J29/04 , B01J29/84 , C01B25/45 , C01B35/14 , C01B37/06 , C01B39/06 , C01B39/54 , C07B61/00 , C07C2/12 , C07C2/54 , C07C2/70 , C07C2/86 , C07C4/08 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/32 , C07C5/41 , C10G35/095 , C10G49/08 , C01B25/00 , B01J27/188 , B01J27/198
CPC分类号： C07C5/41 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structure of MO.sub.2, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis are expressed by the formula:mR:(M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; "M" represents at least two elements capable of forming framework tetrahedral oxides and selected from the group consisting of arsenic, beryllium, boron, chromium, gallium, germanium, lithium and vanadium; and "x", "y" and 37 z" represent the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is disclosed.
摘要翻译： 公开了具有MO2，AlO2和PO2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基的经验化学组成由下式表示：mR：（MxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（M×AlyPz）O 2存在的“R”摩尔量; “M”表示能够形成骨架四面体氧化物并选自砷，铍，硼，铬，镓，锗，锂和钒的至少两种元素; 和“x”，“y”和37z“分别表示作为四面体氧化物存在的”M“，铝和磷的摩尔分数，它们用作吸附剂，催化剂等。
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30.发明授权Process for the use of chromium-aluminum-phosphorus-oxide molecular sieve compositions 失效使用铬 - 铝 - 氧化磷分子筛组合物的方法
公开(公告)号：US4851106A
公开(公告)日：1989-07-25
申请号：US176345
申请日：1988-03-31
IPC分类号： B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G11/04 , C10G35/06 , C10G45/04 , C10G47/02
CPC分类号： C07C5/41 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of CrO.sub.2, AlO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Cr.sub.x Al.sub.Y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Cr.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represents the mole fractions of chromium, aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有CrO 2，AlO 2和PO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（CrxAlYPz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（CrxAlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的铬，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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