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公开(公告)号：US5114563A
公开(公告)日：1992-05-19
申请号：US618761
申请日：1990-11-27
申请人： Brent M. Lok , Celeste A. Messina , Robert L. Patton , Richard T. Gajek , Thomas R. Cannan , Edith M. Flanigen
发明人： Brent M. Lok , Celeste A. Messina , Robert L. Patton , Richard T. Gajek , Thomas R. Cannan , Edith M. Flanigen
IPC分类号： B01J20/18 , B01J29/85 , C01B37/08 , C07C2/54 , C07C2/58 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J20/18 , B01J29/85 , C01B37/08 , C07C2/54 , C07C2/58 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2529/85
摘要： The catalytic conversion of hydrocarbon feedstocks is affected under effective conversion process conditions in the presence of silicoaluminophosphate-based catalyst compositions.
摘要翻译： 在基于硅铝磷酸盐的催化剂组合物存在下，烃原料的催化转化在有效的转化工艺条件下受到影响。
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公开(公告)号：US4952384A
公开(公告)日：1990-08-28
申请号：US197407
申请日：1988-05-20
申请人： Brent M. T. Lok , Bonita K. Marcus , Celeste A. Messina , Stephen T. Wilson , Edith M. Flanigen
发明人： Brent M. T. Lok , Bonita K. Marcus , Celeste A. Messina , Stephen T. Wilson , Edith M. Flanigen
IPC分类号： B01J29/84 , B01J29/85 , C01B25/45 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/84 , B01J29/85 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C01B39/00 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of MO.sub.2.sup.n, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR : (M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "M" represents iron and/or titanium, and at least one of cobalt, magnesium, manganese and zinc; "n" is O, -1 or -2; "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有MO2n，AlO2和PO2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基础上的经验化学组成，由下式表示：mR：（MxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “M”表示铁和/或钛，以及钴，镁，锰和锌中的至少一种; “n”为O，-1或-2; “m”表示每摩尔（M×AlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的“M”，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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3.发明授权Hydrocarbon conversion process using titanium-aluminum-phosphorus-silicon-oxide molecular sieves as catalyst 失效使用钛 - 铝 - 磷 - 氧化硅分子筛作为催化剂的烃转化过程
公开(公告)号：US4880520A
公开(公告)日：1989-11-14
申请号：US260689
申请日：1988-10-21
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of TiO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Ti.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Ti.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of titanium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有TiO 2，AlO 2，SiO 2和PO 2四面体单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（TiwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（TiwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的钛，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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4.发明授权
公开(公告)号：US4781814A
公开(公告)日：1988-11-01
申请号：US46396
申请日：1987-05-06
IPC分类号： B01J29/84 , C01B37/06 , C01B39/54 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G11/05 , C10G47/02 , C10G11/04 , C10G45/12 , C10G47/04
CPC分类号： C07C5/41 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structure of MO.sub.2, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis are expressed by the formula:mR: (M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; "M" represents at least two elements capable of forming framework tetrahedral oxides and selected from the group consisting of arsenic, beryllium, boron, chromium, gallium, germanium, lithium and vanadium; and "x", "y" and "z" represent the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is disclosed. The catalyst is useful in the cracking and hydrocracking of various hydrocarbonaceous feeds.
摘要翻译： 公开了具有MO2，AlO2和PO2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基的经验化学组成由下式表示：mR：（MxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（M×AlyPz）O 2存在的“R”摩尔量; “M”表示能够形成骨架四面体氧化物并选自砷，铍，硼，铬，镓，锗，锂和钒的至少两种元素; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的“M”，铝和磷的摩尔分数。 公开了它们作为吸附剂，催化剂等的用途。 该催化剂可用于各种烃类进料的裂化和加氢裂化。
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公开(公告)号：US4744885A
公开(公告)日：1988-05-17
申请号：US766961
申请日：1985-08-19
IPC分类号： B01J27/185 , B01J29/84 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G11/02 , C01G11/02 , C01G25/00 , C01G45/04
CPC分类号： C07C5/41 , B01J27/1853 , B01J29/84 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C01B39/00 , C07C2529/84
摘要： Novel class of crystalline microporous ferroaluminophosphate compositions containing as lattice constituents in addition to AlO.sub.2 and PO.sub.2 structural units, ferric and/or ferrous iron in tetrahedral coordination with oxygen atoms. These compositions are prepared hydrothermally using organic templating agents and are suitably employed as catalysts or adsorbents.
摘要翻译： 除AlO 2和PO 2结构单元之外还含有作为晶格组分的结晶微孔铁铝磷酸盐组合物的新型，与氧原子四面体配位的铁和/或亚铁。 这些组合物是使用有机模板剂水热制备的，并且适合用作催化剂或吸附剂。
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公开(公告)号：US20230227381A1
公开(公告)日：2023-07-20
申请号：US17769476
申请日：2020-09-30
CPC分类号： C07C2/18 , C07C5/2716 , B01J27/16 , B01J29/40 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01D3/14 , C07C2529/40 , C07C2527/173
摘要： Provided is a method for producing a propylene oligomer, which is advantageous in that a lowly branched propylene oligomer can be obtained at high selectivity. A method for producing a propylene oligomer, including an oligomerization step of oligomerizing propylene at lower than 160° C. in the presence of at least one member selected from a group consisting of a catalyst containing crystalline molecular sieve and a catalyst containing phosphoric acid, a fractional distillation step of obtaining a fraction containing a propylene trimer, a propylene tetramer, or a mixture thereof, and an isomerization step of isomerizing the propylene trimer, propylene tetramer, or mixture thereof contained in the fraction in the presence of a catalyst containing phosphoric acid.
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公开(公告)号：US5254791A
公开(公告)日：1993-10-19
申请号：US10372
申请日：1993-01-28
IPC分类号： B01J27/053 , B01J27/125 , B01J27/16 , C07C5/27 , C07C5/29
CPC分类号： C07C5/2716 , B01J27/053 , B01J27/125 , B01J27/16 , C07C5/29 , C07C2101/14
摘要： C.sub.5 -C.sub.10 cycloalkanes (preferably methylcyclopentane) are isomerized in the presence of a catalyst comprising aluminum chloride and at least one of the following materials: boron phosphate on silica, boron phosphate on activated carbon, boron sulfate on silica.
摘要翻译： C5-C10环烷烃（优选甲基环戊烷）在包含氯化铝和至少一种以下物质的催化剂存在下异构化：二氧化硅上的磷酸二氢钠，活性炭上的磷酸硼，二氧化硅上的硫酸氢钠。
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8.发明授权
公开(公告)号：US4973460A
公开(公告)日：1990-11-27
申请号：US218494
申请日：1988-07-06
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of LiO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of lithium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有LiO 2，AlO 2，PO 2和SiO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（LiwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（LiwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的锂，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4940570A
公开(公告)日：1990-07-10
申请号：US835293
申请日：1986-03-03
IPC分类号： B01J29/84 , C01B25/45 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of BeO.sub.2, AlO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Be.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Be.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of beryllium, aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有BeO 2，AlO 2和PO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有由下式表示的无水基础上的经验化学组成：mR：（BexAlyPz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（BexAlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的铍，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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公开(公告)号：US4846956A
公开(公告)日：1989-07-11
申请号：US250407
申请日：1988-09-28
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of MnO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Mn.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mn.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有MnO 2，AlO 2，SiO 2和PO 2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基础上的经验化学组成，其由下式表示：mR：（MnwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（MnwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的锰，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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