公开(公告)号：US20050180909A1

公开(公告)日：2005-08-18

申请号：US11084884

申请日：2005-03-21

申请人： Shiou-Jyh Hwu ,  Qun Huang ,  Mutlu Ulutagay

发明人： Shiou-Jyh Hwu ,  Qun Huang ,  Mutlu Ulutagay

IPC分类号： B01J29/84 ,  C01B37/00 ,  C01B39/06 ,  C01B39/08 ,  C01B39/10 ,  C01B39/50 ,  C01B39/54 ,  C01B25/45

CPC分类号： C01B39/06 ,  B01J29/84 ,  C01B37/00 ,  C01B37/002 ,  C01B39/08 ,  C01B39/10 ,  C01B39/50 ,  C01B39/54

摘要： The present invention is directed to open-framework and microporous solids particularly well suited for use in catalysis and ion exchange. The microporous solids are constructed by using a salt template which can be readily removed without destroying the framework of the micropore. Various microporous solids can be formed having different geometric structures depending upon the templating salt used and the concentration. Examples of two compounds include Na2Cs[Mn3(P2O7)2]Cl(1) and K2.02Cs2.90[Cu3(P2O7)2]C12.92(2). Compound 1 crystallizes in the space group C2/c with a=21.210(8), b=5.272(2), c=13.924(2)Å, beta=119.04(2), and Z=4. Compound 2 crystallizes in the space group 14/mcm with a=b=18.001(3), c=13.530(4)Å, and Z=8. Both compounds have 3-D (Mn, Cu)—P—O frameworks. For 1, two MnO4, two MnO5 polyhedra and four PO4 tetrahedra form small tunnels where Cs+ and Cl− ions reside. For 2, CuO4 and P2O7 groups form two different tunnels, one is similar to that in 1 (ca. 5.3 Å in diameter) while the other formed by eight CuO4 polyhedra and eight PO4 tetrahedra has an approximate diameter of 12 Å.

摘要翻译： 本发明涉及特别适用于催化和离子交换的开放框架和微孔固体。 通过使用可以容易地除去的盐模板来构建微孔固体，而不会破坏微孔的骨架。 根据所使用的模板盐和浓度，可以形成具有不同几何结构的各种微孔固体。 两种化合物的实例包括Na2C [Mn3（P2O7）2] Cl（1）和K2.02C2.90 [Cu3（P2O7）2] C12.92（2）。 化合物1在空间群C2 / c中结晶，a = 21.210（8），b = 5.272（2），c = 13.924（2），β= 119.04（2），Z = 4。 化合物2在空间群14 / mcm中结晶，a = b = 18.001（3），c = 13.530（4），Z = 8。 两种化合物都具有3-D（Mn，Cu）-P-O骨架。 对于1，两个MnO4，两个MnO5多面体和四个PO4四面体形成Cs +和Cl-离子存在的小隧道。 对于2，CuO 4和P 2 O 7组形成两个不同的隧道，一个类似于1（直径约5.3），而由八个CuO 4多面体和八个PO 4四面体形成的另一个具有大约12的直径。

公开(公告)号：US5227151A

公开(公告)日：1993-07-13

申请号：US792573

申请日：1991-11-15

申请人： David C. Calabro

发明人： David C. Calabro

IPC分类号： B01J29/85 ,  C01B39/10

CPC分类号： B01J29/85 ,  C01B39/10 ,  Y10S423/30

摘要： A method of preparing silicoaluminophosphate (SAPO) compositions from a forming mixture which comprises sources of oxides of silicon, aluminum and phosphorus and quaternary ammonium-functionalized organosiliconate directing agent wherein the oxides of silicon are provided at least in part by said directing agent, e.g., N-trimethoxysilylpropyl-N,N,N-trimethylammonium chloride.

摘要翻译： 一种从形成混合物制备硅铝磷酸盐（SAPO）组合物的方法，所述形成混合物包含硅，铝和磷的氧化物源和季铵官能化的有机硅酸盐定向剂，其中硅的氧化物至少部分地由所述导向剂提供， N-三甲氧基甲硅烷基丙基-N，N，N-三甲基氯化铵。

公开(公告)号：US4420467A

公开(公告)日：1983-12-13

申请号：US331832

申请日：1981-12-17

申请人： Thomas V. Whittam

发明人： Thomas V. Whittam

IPC分类号： C01B39/00 ,  B01J29/70 ,  B01J29/78 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  C01B39/06 ,  C01B39/10 ,  C01B39/12 ,  C01B39/40 ,  C01B39/46 ,  C01B33/20 ,  B01J29/04 ,  C01B33/28

CPC分类号： C01B39/10 ,  B01J29/70 ,  B01J29/78 ,  C01B39/06 ,  C01B39/12 ,  C01B39/40 ,  B01J2229/20

摘要： A synthetic zeolite material, designated zeolite Nu-5, having a molar composition expressed by the formula; 0.5 to 1.5 R.sub.2 O: Y.sub.2 O.sub.3 : at least 10 XO.sub.2 : 0 to 2000 H.sub.2 O wherein R is a monovalent cation or 1/n of a cation of valency n, X is silicon and or germanium, Y is one or more of aluminium, iron, chromium, vanadium, molybdenum, arsenic, manganese, gallium or boron, and H.sub.2 O is water of hydration additional to water notionally present when R is H, and having a defined X-ray diffraction pattern. Zeolite Nu-5 is a useful catalyst.

摘要翻译： 具有由式表示的摩尔组成的合成沸石材料，称为沸石Nu-5; 0.5至1.5 R2O:Y2O3：至少10XO2：0至2000H2O其中R是一价阳离子或1 / n的价数阳离子n，X是硅或锗，Y是铝，铁， 铬，钒，钼，砷，锰，镓或硼，当R为H时，H 2 O是除水以外的水合水，并且具有确定的X射线衍射图。 沸石Nu-5是一种有用的催化剂。

公开(公告)号：US4060568A

公开(公告)日：1977-11-29

申请号：US672194

申请日：1976-03-31

申请人： Paul G. Rodewald

发明人： Paul G. Rodewald

IPC分类号： B01J29/08 ,  B01J29/00 ,  B01J29/06 ,  B01J29/16 ,  B01J29/18 ,  B01J29/26 ,  B01J29/40 ,  B01J29/48 ,  B01J29/65 ,  B01J29/70 ,  C01B33/40 ,  C01B39/00 ,  C01B39/10 ,  C01B39/12 ,  C01B39/36 ,  C01B39/38 ,  C01B39/42 ,  C01B39/44 ,  C07B61/00 ,  C07C1/00 ,  C07C2/00 ,  C07C2/02 ,  C07C2/66 ,  C07C2/76 ,  C07C2/86 ,  C07C4/00 ,  C07C5/41 ,  C07C6/12 ,  C07C15/02 ,  C07C15/08 ,  C07C67/00 ,  C07C1/20 ,  C07C1/24

CPC分类号： B01J29/40 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/42 ,  B01J29/65 ,  B01J29/70 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  Y10S423/22 ,  Y10S423/23 ,  Y10S423/29 ,  Y10S423/33 ,  Y10S585/906

摘要： A catalyst is provided, which is especially applicable for the selective production of certain desired hydrocarbons, comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12, a constraint index, as hereinafter defined, within the approximate range of 1 to 12 and having contained within the interior crystalline structure thereof added amorphous silica in an amount of at least about 0.1 and preferably between about 2 and about 10 weight percent. The invention described herein also encompasses synthesis of the specified catalyst and use of the same in selectively producing low molecular weight olefins and/or para-xylene from appropriate charge stocks.

摘要翻译： 提供了一种催化剂，其特别适用于某些所需烃的选择性生产，其包含二氧化硅与氧化铝之比至少约为12的结晶铝硅酸盐沸石，约定指数如下所定义，在约1至 12并且其内部结晶结构中含有至少约0.1，优选约2至约10重量％的量的无定形二氧化硅。 本文描述的发明还包括合成特定的催化剂及其在合适的电荷原料中选择性地生产低分子量烯烃和/或对二甲苯的用途。

公开(公告)号：US20230202851A1

公开(公告)日：2023-06-29

申请号：US17996178

申请日：2021-04-13

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC

发明人： Yibin LUO ,  Chengqiang WANG ,  Ying OUYANG ,  Enhui XING ,  Xingtian SHU

IPC分类号： C01B39/10 ,  C01B39/38 ,  B01J29/40 ,  B01J29/80 ,  B01J6/00 ,  C10G11/05

CPC分类号： C01B39/10 ,  C01B39/38 ,  B01J29/40 ,  B01J29/80 ,  B01J6/001 ,  C10G11/05 ,  C01P2002/85 ,  C01P2002/86 ,  C01P2006/16

摘要： A phosphorus-containing or phosphorus-modified ZSM-5 molecular sieve is characterized in that in its 27Al MAS-NMR, the ratio of peak area for the resonance signal having a chemical shift of 39±3 ppm to peak area for the resonance signal having a chemical shift of 54 ppm±3 ppm is ≥1; or in its surface XPS elemental analysis, the value of n1/n2 is ≤0.1. n1 represents the mole number of phosphorus, n2 represents the total mole number of silicon and aluminum. A cracking auxiliary or cracking catalyst contains the phosphorus-containing/phosphorus-modified ZSM-5 molecular sieve can be made using the phosphorus-containing or phosphorus-modified ZSM-5 molecular sieve.

公开(公告)号：US10280089B1

公开(公告)日：2019-05-07

申请号：US16016400

申请日：2018-06-22

申请人： UOP LLC

发明人： Benjamin D. Yuhas ,  Kristine N. Wilson ,  Mimoza Sylejmani-Rekaliu ,  John P. S. Mowat ,  Wharton Sinkler

IPC分类号： C01B39/54 ,  B01J29/85 ,  C01B39/10 ,  B01J20/18 ,  B01J29/83 ,  B01J29/84 ,  B60H1/32 ,  B01J20/04 ,  B01J20/02 ,  C10G11/04 ,  B01J20/08 ,  F24F5/00 ,  C10G47/02 ,  C10G35/06 ,  B01D53/26 ,  C10G11/02

摘要： A new family of crystalline microporous metallophosphates designated AlPO-92 has been synthesized. These metallophosphates are represented by the empirical formula Cc+Aa+Mm2+EPxSiyOz where M is a divalent framework metal such as magnesium, C is a cyclic organoammonium cation, A is an acyclic organoammonium cation, and E is a trivalent framework element such as aluminum or gallium. The AlPO-92 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

公开(公告)号：US09254481B2

公开(公告)日：2016-02-09

申请号：US14236734

申请日：2012-07-26

申请人： John L. Casci ,  Hai-Ying Chen ,  Joseph Michael Fedeyko ,  Jillian Elaine Collier ,  Raj Rao Rajaram ,  David Thompsett ,  Robert P. Hodgkins

发明人： John L. Casci ,  Hai-Ying Chen ,  Joseph Michael Fedeyko ,  Jillian Elaine Collier ,  Raj Rao Rajaram ,  David Thompsett ,  Robert P. Hodgkins

IPC分类号： C01B39/54 ,  B01J29/85 ,  B01J29/88 ,  C01B39/10 ,  B01J37/28 ,  B01D53/94 ,  B01J29/70 ,  B01J29/76 ,  C01B39/04 ,  B01D53/86 ,  B01J37/02

CPC分类号： B01J29/763 ,  B01D53/8628 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/707 ,  B01J29/7015 ,  B01J29/85 ,  B01J29/88 ,  B01J35/04 ,  B01J37/0246 ,  B01J37/28 ,  B01J2229/183 ,  B01J2229/186 ,  C01B39/04 ,  C01B39/10 ,  C01B39/54 ,  Y02T10/24

摘要： A catalyst composition is provided having a CHA crystal structure; about 0.5 to about 5.0 mol % phosphorus; and SiO2 and Al2O3 in a mole ratio of about 5 to about 40. The catalyst composition is capable of NOx conversion at elevated temperatures. A catalytically active washcoat includes such catalyst compositions and one or more promoters or stabilizers, and may be applied to a monolith substrate to produce a catalytically active article. Methods of reducing NOx employing the catalyst compositions are also provided.

摘要翻译： 提供具有CHA晶体结构的催化剂组合物; 约0.5至约5.0mol％的磷; 和摩尔比为约5至约40的SiO 2和Al 2 O 3。催化剂组合物能够在升高的温度下进行NOx转化。 催化活性的修补基面涂料包括这样的催化剂组合物和一种或多种促进剂或稳定剂，并且可以应用于整料基材以产生催化活性制品。 还提供了使用催化剂组合物还原NOx的方法。

公开(公告)号：US07758847B2

公开(公告)日：2010-07-20

申请号：US10577672

申请日：2004-10-28

申请人： Yibin Luo ,  Ying Ouyang ,  Xingtian Shu ,  Mingyuan He ,  Dianzhong Wang ,  Baoning Zong ,  Minggang Li

发明人： Yibin Luo ,  Ying Ouyang ,  Xingtian Shu ,  Mingyuan He ,  Dianzhong Wang ,  Baoning Zong ,  Minggang Li

IPC分类号： C01B39/10 ,  C01B39/38 ,  B01J29/072 ,  B01J29/46

CPC分类号： C01B39/026 ,  B01J29/084 ,  B01J29/405 ,  B01J29/46 ,  B01J29/48 ,  B01J29/80 ,  B01J2229/18 ,  B01J2229/42 ,  C10G11/02

摘要： A MFI-structured molecular sieve containing phosphorus and metal components has a formula expressed in anhydrous form and on the basis of oxide weight, as follows: (0˜0.3) Na2O (0.5˜5.5) Al2O3 (1.3˜10) P2O5 (0.7˜15) M1xOy (0.01˜5) M2mOn (70˜97) SiO2, wherein M1 is one of transition metals selected from the group consisting of Fe, Co and Ni, and M2 is any one of metals selected from the group consisting of Zn, Mn, Ga and Sn. Preparation processes and uses of the instant molecular sieve are also provided. The molecular sieve has an excellent performance for increasing the yield of lower olefins and increasing the aromatics content in gasoline, and can be used as a shape-selective active component for the catalytic cracking catalyst of petroleum hydrocarbons or its additives.

摘要翻译： 含有磷和金属组分的MFI结构分子筛具有无水形式和氧化物重量的表达式：（0〜0.3）Na 2 O（0.5〜5.5）Al 2 O 3（1.3〜10）P 2 O 5（0.7〜 15）M1xOy（0.01〜5）M2mOn（70〜97）SiO2，其中M1是选自Fe，Co和Ni中的过渡金属之一，M2是选自Zn， Mn，Ga和Sn。 还提供了即时分子筛的制备方法和用途。 该分子筛具有优异的提高低级烯烃的产率和提高汽油中芳烃含量的性能，可用作石油烃或其添加剂的催化裂化催化剂的形状选择性活性成分。

公开(公告)号：US5345021A

公开(公告)日：1994-09-06

申请号：US2800

申请日：1993-01-11

申请人： John L. Casci ,  Ivan J. S. Lake ,  Timothy R. Maberly

发明人： John L. Casci ,  Ivan J. S. Lake ,  Timothy R. Maberly

IPC分类号： B01J29/04 ,  B01J29/06 ,  B01J29/076 ,  B01J29/70 ,  B01J29/74 ,  B01J29/76 ,  B01J29/80 ,  B01J29/89 ,  C01B33/40 ,  C01B39/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/10 ,  C01B39/12 ,  C01B39/24 ,  C01B39/26 ,  C01B39/46 ,  C07B61/00 ,  C07C1/24 ,  C07C2/00 ,  C07C2/66 ,  C07C2/70 ,  C07C2/84 ,  C07C2/86 ,  C07C4/06 ,  C07C4/18 ,  C07C5/27 ,  C07C6/12 ,  C07C9/00 ,  C07C11/02 ,  C07C15/02 ,  C07C41/06 ,  C07C43/04 ,  C07C209/16 ,  C10G11/05 ,  C10G45/64 ,  C10G50/00

CPC分类号： C10G50/00 ,  B01J29/04 ,  B01J29/70 ,  B01J29/74 ,  B01J29/76 ,  C07C2/00 ,  C07C2/66 ,  C07C2/864 ,  C07C209/16 ,  C07C4/06 ,  C07C41/06 ,  C07C5/2724 ,  C07C5/2791 ,  C07C6/123 ,  C07C6/126 ,  C10G11/05 ,  C10G45/64 ,  B01J2229/26 ,  B01J2229/37 ,  B01J2229/42 ,  C07C2529/70 ,  C10G2300/70 ,  Y02P20/588

摘要： A catalyst comprising a novel zeolite NU-87, is useful in a wide variety of hydrocarbon conversion reactions including isomerisation, transalkylation and alkylation.

摘要翻译： 包含新型沸石NU-87的催化剂可用于多种烃转化反应，包括异构化，烷基转移和烷基化。

公开(公告)号：US5013537A

公开(公告)日：1991-05-07

申请号：US437308

申请日：1989-11-17

申请人： Joel Patarin ,  Jean-Louis Guth ,  Henri Kessler ,  Gisele Coudurier ,  Francis Raatz

发明人： Joel Patarin ,  Jean-Louis Guth ,  Henri Kessler ,  Gisele Coudurier ,  Francis Raatz

IPC分类号： B01J29/04 ,  B01J29/00 ,  B01J29/86 ,  B01J29/88 ,  B01J29/89 ,  C01B33/20 ,  C01B39/00 ,  C01B39/04 ,  C01B39/08 ,  C01B39/10 ,  C01B39/12 ,  C01B39/24 ,  C01B39/36 ,  C01B39/40 ,  C07B61/00 ,  C07C1/00 ,  C07C1/20 ,  C07C2/12 ,  C07C2/86 ,  C07C11/02 ,  C07C15/02 ,  C07C67/00 ,  C10G11/05 ,  C10G35/095 ,  C10G45/64 ,  C10G47/16 ,  C10G50/00

CPC分类号： C07C2/12 ,  B01J29/88 ,  C07C1/20 ,  C07C2/864 ,  C07C2529/88 ,  Y02P20/52 ,  Y10S423/22

摘要： The invention relates to a novel process for the synthesis of zeolites of the ferrisilicate type called ferrizeosilites, to the products obtained by this process as well as their uses. Ferrizeosilite according to the invention is characterized by (a) a chemical formula close to the following:M.sub.2/n O, Fe.sub.2 O.sub.3, x SiO.sub.2whereM represents a proton and/or a metal cationn is the valence of said cationx is a number between 40 and 1000(b) an x-ray diffraction diagram, and (c) a fluorine content between about 0.01% and 16% by weight. Uses are in processes for the conversion of methanol into hydrocarbons, alkylation of toluene with methanol and catalytic cracking of hydrocarbons.

摘要翻译： 本发明涉及一种用于合成所谓的铁硅酸盐型沸石的新颖方法，涉及通过该方法获得的产物及其用途。 其特征在于：（a）接近于下列的化学式：M2 / nO，Fe2O3，xSiO2，其中M表示质子和/或金属阳离子，n是所述阳离子的价数x是在 40和1000（b）x射线衍射图，（c）氟含量在约0.01％和16％之间。 用途是将甲醇转化成烃，甲醇与甲醇的烷基化和烃的催化裂解。