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公开(公告)号：US4546552A
公开(公告)日：1985-10-15
申请号：US607408
申请日：1984-05-07
申请人： Robert P. Cahn , Jeffrey H. Siegell
发明人： Robert P. Cahn , Jeffrey H. Siegell
CPC分类号： B01J8/42 , B01D46/38 , B01J8/44 , F26B3/097 , Y10S423/16
摘要： Solids comprising a magnetically stabilized fluidized bed are transported in a direction transverse to the flow of the fluidizing fluid exiting the bed by contacting at least a portion of said solids with fluidizing fluid which enters the bed with a velocity component in the direction of solids flow; i.e. the transverse flow direction. In a preferred embodiment, the fluidizing fluid entering the bed is passed through a distribution means containing propulsion passages slanted in the desired direction of solids flow which serve to orient the fluidizing fluid in the transverse flow direction. Use of this invention eliminates the need for the costly and inconvenient pneumatic, hydraulic and mechanical transport devices employed in the prior art. Solids attrition and elutriation are also reduced.
摘要翻译： 包含磁稳定化流化床的固体通过使至少一部分所述固体与流入床的流化流体接触，所述流体沿固体流动方向上的速度分量沿横向于流出床流化流体的方向输送; 即横向流动方向。 在优选实施例中，进入床的流化流体通过分配装置，该分配装置包含倾斜于所需固体流动方向的推进通道，该推进通道用于使流化流体沿横向流动方向定向。 使用本发明消除了对现有技术中使用的昂贵和不便的气动，液压和机械输送装置的需要。 固体消耗和淘析也减少了。
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公开(公告)号：US4360448A
公开(公告)日：1982-11-23
申请号：US404716
申请日：1973-10-09
申请人： Norman N. Li , Robert P. Cahn , Adam L. Shrier
发明人： Norman N. Li , Robert P. Cahn , Adam L. Shrier
摘要： This invention relates to a process for the removal of dissolved species from aqueous solutions, which comprises contacting said aqueous solution with an emulsion, said emulsion comprising an exterior phase which is characterized as being immiscible with said aqueous solution and yet permeable to said dissolved species, and an interior phase which contains a reactant capable of converting said dissolved species to a nonpermeable form. The dissolved species permeate the exterior phase, into the interior phase where they are converted into nonpermeable forms and thus retained in the interior phase of said emulsion. The aqueous solution, depleted in said dissolved species, is separated from said emulsion and the emulsion cycled for reuse. In one preferred embodiment said dissolved species are ions, and an ion exchange compound is incorporated in the exterior phase of the emulsion, to promote the permeation of said ions through the exterior phase.
摘要翻译： 本发明涉及从水溶液中除去溶解物质的方法，该方法包括使所述水溶液与乳液接触，所述乳液包含外相，其特征在于与所述水溶液不混溶，并且对所述溶解物质是可渗透的， 以及含有能够将所述溶解物质转化成不渗透形式的反应物的内部相。 溶解的物质渗透到外部相中，进入内部相，在那里它们被转化为不透水的形式，因此保留在所述乳液的内部相中。 将所述溶解物质耗尽的水溶液与所述乳液分离，并将乳液循环使用。 在一个优选的实施方案中，所述溶解的物质是离子，并且离子交换化合物被引入到乳液的外部相中，以促进所述离子通过外部相的渗透。
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公开(公告)号：USRE30125E
公开(公告)日：1979-10-23
申请号：US951352
申请日：1978-10-13
申请人： Norman N. Li , Robert P. Cahn , Adam L. Shrier
发明人： Norman N. Li , Robert P. Cahn , Adam L. Shrier
摘要： This invention relates to a process for the removal of dissolved species from aqueous solutions, which comprises contacting said aqueous solution with an emulsion, said emulsion comprising an exterior phase which is characterized as being immiscible with said aqueous solution and yet permeable to said dissolved species, and an interior phase which contains a reactant capable of converting said dissolved species to a non-permeable form. The dissolved species permeate the exterior phase, into the interior phase where they are converted into nonpermeable forms and thus retained in the interior phase of said emulsion. The aqueous solution, depleted in said dissolved species, is separated from said emulsion and the emulsion cycled for reuse. In one preferred embodiment said dissolved species are ions, and an ion exchange compound is incorporated in the exterior phase of the emulsion, to promote the permeation of said ions through the exterior phase.
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公开(公告)号：US4155844A
公开(公告)日：1979-05-22
申请号：US845854
申请日：1977-10-27
申请人： Norman N. Li , Robert P. Cahn
发明人： Norman N. Li , Robert P. Cahn
摘要： The instant invention relates to a process for separating components from liquid mixtures which comprises emulsifying said liquid mixture in an immiscible liquid which is characterized as a solvent for the components. The emulsion is then contacted with an inert gas whereby the components of the mixture which, because of their solubility, permeate into said immiscible liquid, and are stripped therefrom by the inert gas. The components may then be separated from said inert gas stream by condensation and subsequent phase separation or fractionation, by absorption, distillation or by adsorption. In a preferred embodiment of the instant invention the liquid mixture comprises a hydrocarbon which is emulsified in an aqueous surfactant containing liquid. The hydrocarbon mixture contains hydrocarbons of different types, as well as hydrocarbons mixed with oxygenated compounds, i.e. alcohols, ketones, acids, and mixtures thereof. In a particular embodiment the hydrocarbon mixture contains toluene and heptane. In this embodiment the toluene preferentially permeates into said aqueous surfactant containing liquid and is removed therefrom by a stream of stripping steam.
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公开(公告)号：US4089744A
公开(公告)日：1978-05-16
申请号：US738604
申请日：1976-11-03
申请人： Robert P. Cahn
发明人： Robert P. Cahn
摘要： A method is described for storing the offpeak electrical output of an electricity generating plant in the form of heat by using it to raise the temperature level of a quantity of stored heat retention material and recalling said stored heat during periods of peak power demand in the form of electrical power. During low power demand periods hot water is drawn from a hot water storage means and cooled by flashing it at successively lower pressures. The cold condensate is sent to a cold water storage means while the various flash vapors are fed to appropriate stages of a steam compressor driven by excess power drawn from the electricity generating station. The steam which has been compressed by means of the excess electrical power is directed to heat exchanger means where it is used to heat a low vapor pressure (LVP) thermal energy retention material flowing from cold to hot storage means through the heat exchanger means. By the practice of this invention, heat is transferred, by means of the steam compressor powered by excess electrical power, from hot water (.about. 210.degree. F) to the LVP material raising its temperature from a cold storage temperature of about 190.degree.-300.degree. F to a hot storage temperature of about 450.degree.-600.degree. F. The hot LVP material is stored at atmospheric pressure preferably under an inert gas atmosphere. During peak energy demand periods, the process is reversed and the hot LVP material is used to generate steam which runs a turbine thereby producing electrical power from a generator.
摘要翻译： 描述了一种用于以发热的形式存储发电厂的截止电力输出的方法，通过使用它来提高一定量的储存保温材料的温度水平并且以形式的峰值功率需求期间召回所述储存的热量 的电力。 在低功率需求期间，热水从热水储存装置中抽出，并通过在连续较低的压力下闪蒸来冷却。 将冷凝水送入冷水存储装置，同时将各种闪蒸蒸汽送入由从发电站抽取的多余动力驱动的蒸汽压缩机的适当阶段。 已经通过过剩电力压缩的蒸汽被引导到热交换器装置，在该热交换器装置中用于加热从冷却到热存储装置通过热交换器装置流动的低蒸气压（LVP）热能保持材料。 通过本发明的实践，通过由过量电力供应的蒸汽压缩机将热量从热水（差异210°F）转移到LVP材料，使其温度从约190°-300的冷藏温度升高 DEG F至约450-600°F的储热温度。热LVP材料优选在惰性气体气氛下在大气压下储存。 在峰值能量需求期间，过程相反，并且热LVP材料用于产生运行涡轮机的蒸汽，从而产生来自发电机的电力。
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公开(公告)号：US4080791A
公开(公告)日：1978-03-28
申请号：US756183
申请日：1977-01-03
申请人： Murray Nadler , Robert P. Cahn
发明人： Murray Nadler , Robert P. Cahn
CPC分类号： H01M8/04 , F01K3/185 , H01M8/0612 , H01M8/04014 , H01M8/04029 , H01M8/04119 , H01M8/04186 , H01M8/04276
摘要： An integrated power generating plant includes a fuel cell for generating electrical energy directly, an auxiliary power generating plant that utilizes both the sensible heat and the heating value of effluents from the fuel cell by using working fluids in a closed cycle. The working fluid is vaporized by sensible heat and is superheated by combusting incompletely reacted fuels from the fuel cell.
摘要翻译： 集成发电厂包括用于直接产生电能的燃料电池，辅助发电设备，其通过在封闭循环中使用工作流体，利用来自燃料电池的流出物的显热和热值。 工作流体通过显热蒸发，并且通过燃烧来自燃料电池的未完全反应的燃料而过热。
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公开(公告)号：US4058575A
公开(公告)日：1977-11-15
申请号：US586177
申请日：1975-06-12
申请人： Robert P. Cahn , John P. Longwell
发明人： Robert P. Cahn , John P. Longwell
CPC分类号： B01J27/12 , C07C5/2721 , Y02P20/584
摘要： Partially deactivated hydrocarbon conversion catalysts comprising (a) one or more Lewis acids of the formula MX.sub.n where M is a metal selected from Group III-A, IV-B, V or VI-B elements of the Periodic Table, X is a halogen, n is the ratio of halogen atoms to atoms of M and varies from 1-8, and (b) a strong Bronsted acid are contacted with a hydrocarbon feedstock to recover the active or potentially active catalyst species from the partially deactivated catalyst stream prior to regeneration. In addition, potential organic and inorganic catalyst poisons present in said feedstock are removed therefrom during said contacting prior to introducing said feedstock into a hydrocarbon conversion process.
摘要翻译： 部分失活的烃转化催化剂，其包含（a）一种或多种式MXn的路易斯酸，其中M是选自元素周期表III-A，IV-B，V或VI-B族元素的金属，X是卤素， n是卤素原子与M原子的比率并且从1-8变化，和（b）强烈的布朗斯台德酸与烃原料接触以在再生之前从部分失活的催化剂物流中回收活性或潜在活性的催化剂物质 。 此外，在将所述原料引入烃转化过程之前，在所述接触期间，从所述原料中除去存在于所述原料中的潜在有机和无机催化剂毒物。
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公开(公告)号：US4003786A
公开(公告)日：1977-01-18
申请号：US613754
申请日：1975-09-16
申请人： Robert P. Cahn
发明人： Robert P. Cahn
摘要： The power output from a nuclear power plant or fossil fuel power plant operating under constant reactor (or furnace) and boiler conditions is varied by regulating the rate of turbine extraction steam and primary high pressure steam used to heat boiler feed water (BFW). During periods of low power demand excess extraction steam is drawn off to heat excess quantities of boiler feed water. One portion of the BFW is fed to the boiler while the other portion is used to reheat a low vapor pressure (LVP) organic material which hot material is stored under an inert atmosphere at atmospheric pressure in a high temperature storage location means. During periods of high power demand BFW preheat duties would be taken over entirely by the moving LVP organic material, moving from hot to cold storage location means, use of extraction steam for BFW reheat being curtailed and such untapped extraction steam being allowed instead to expand itself fully in the turbines. The boiler at all times receives a constant amount of uniformly preheated BFW.
摘要翻译： 来自在恒定反应堆（或炉）和锅炉条件下运行的核电站或化石燃料发电厂的输出功率通过调节用于加热锅炉给水（BFW）的涡轮机提取蒸汽和初级高压蒸汽的速率来改变。 在低功率需求期间，抽出的蒸汽被蒸发以加热过量的锅炉给水。 BFW的一部分被供给到锅炉，而另一部分用于对在高温储存位置的大气压下的惰性气氛下储存的热材料的低蒸气压（LVP）有机材料再加热。 在高功率需求期间，BFW预热功能将完全由移动的LVP有机材料从热存储位置转移到冷库，这意味着使用提取蒸汽来BFW再热被减少，并且允许这种未开发的提取蒸汽可以自我扩展 完全在涡轮机。 锅炉始终接受恒定量的均匀预热的BFW。
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公开(公告)号：US4001111A
公开(公告)日：1977-01-04
申请号：US452501
申请日：1974-03-19
申请人： Paul R. Geissler , Robert P. Cahn
发明人： Paul R. Geissler , Robert P. Cahn
CPC分类号： G01N30/482 , B01D15/08 , C07C7/13 , C10G25/03 , G01N30/28 , B01D15/166 , B01J2220/54
摘要： In a liquid chromatography commercial process for the separation of two or more components contained in admixture in a feedstream including the steps of (a) contacting the feedstream mixture containing the components to be separated with a bed of crystalline aluminosilicate adsorbent at conditions to effect the selective retention of two or more of the components by said adsorbent, (b) passing through said bed an eluent selected from the group consisting of aromatics and substituted aromatics, (c) increasing the strength of the eluting agent in the liquid carrier during the operation of the steps (a) and (b) above, (d) recovering from said bed a stream or streams containing at least a portion of the less selectively adsorbed components, and (e) recovering a stream substantially enhanced in concentration of said selectively adsorbed components relative to other components of feedstream wherein the improvement comprises preheating the eluting agent of step (c) above prior to passing it through said bed at temperatures of at least 160.degree. C., to thereby effect the desired separation under conditions that cause substantially lower elution volume to feed ratios. The improved liquid chromatography process is particularly applicable to the separation of paraxylene and ethylbenzene from a C8 aromatic isomer mixture containing ethylbenzene. The above process when operated with the eluting agent preheating step at temperatures of about 160.degree. C or higher causes temperature waves to flow through the bed with the final peak of each feed slug being eluted with the hotter eluting agent-carrier mixture, thus providing lower elution volume to feed ratios and thereby producing paraxylene more economically.
摘要翻译： 在用于在进料流中分离包含在混合物中的两种或更多种组分的液相色谱法商业方法中，包括以下步骤：（a）使含有待分离组分的进料流混合物与结晶硅铝酸盐吸附剂床接触， 通过所述吸附剂保留两种或更多种组分，（b）使所述床通过选自芳族化合物和取代的芳族化合物的洗脱液，（c）在操作期间提高液体载体中的洗脱剂的强度 上述步骤（a）和（b），（d）从所述床中回收含有至少一部分较少选择性吸附组分的物流或流，和（e）回收基本上增强所述选择性吸附组分浓度的物流 相对于进料流的其它组分，其中改进包括在通过步骤（c）之前预热上述步骤（c）的洗脱剂 通过所述床在至少160℃的温度下，从而在导致基本上较低的洗脱体积与进料比的条件下进行所需的分离。 改进的液相色谱方法特别适用于从含有乙苯的C8芳族异构体混合物中分离对二甲苯和乙苯。 当在约160℃或更高的温度下用洗脱剂预热步骤操作时，上述方法使温度波流过床，每个进料段的最终峰用较热的洗脱剂 - 载体混合物洗脱，从而提供较低的 洗脱体积与进料比，从而更经济地生产对二甲苯。
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