Alkylation process utilizing HF regenerator stream to a multi-tray
isoparaffin stripper
    21.
    发明授权
    Alkylation process utilizing HF regenerator stream to a multi-tray isoparaffin stripper 失效
    使用HF再生器流到多塔板异构烷烃脱蜡器的烷基化方法

    公开(公告)号:US3956416A

    公开(公告)日:1976-05-11

    申请号:US533421

    申请日:1974-12-16

    申请人: Bipin V. Vora

    发明人: Bipin V. Vora

    摘要: In prior art HF alkylation processes, an HR regenerator overhead vapor stream is processed in various ways including combining it with overhead vapor streams of an isoparaffin stripper or an HF stripper, or condensing, settling, and pumping it in a regenerator overhead system to an HF alkylation reaction zone. In the present HF alkylation system comprising a reaction and settling zone, an acid regeneration zone, and a products fractionation zone including an isoparaffin stripper from which a side-cut recycle stream containing principally isoparaffin is withdrawn, an improvement is made by taking overhead vapor from the regenerator and introducing the vapor directly into the isoparaffin stripper at a locus above that at which the side-cut recycle stream is withdrawn.

    摘要翻译: 在现有技术的HF烷基化方法中,HR再生器塔顶蒸气流以各种方式加工,包括将其与异链烷烃汽提塔或HF汽提塔的塔顶蒸气流组合,或冷凝,沉降并在再生塔架系统中将其泵入HF 烷基化反应区。 在包括反应和沉降区,酸再生区和包含异链烷烃脱附器的产物分馏区的本发明的HF烷基化体系中,取出主要为异链烷烃的侧馏分循环流,通过从塔顶蒸气 再生器,并将蒸汽直接引入异烷烃汽提器中,高于侧馏分循环流被抽出的位置。

    Separation of monomer from oligomer with lower bottoms temperature
    24.
    发明授权
    Separation of monomer from oligomer with lower bottoms temperature 失效
    单体与低聚物的分离与较低的底部温度

    公开(公告)号:US06590132B1

    公开(公告)日:2003-07-08

    申请号:US09844208

    申请日:2001-04-27

    申请人: Bipin V. Vora

    发明人: Bipin V. Vora

    IPC分类号: C07C704

    摘要: The process disclosed separates light olefins from heavy oligomers in a distillation column with an intermediary having a boiling point between the light olefin and the heavy oligomer in the column feed. The invention contemplates separating C4 hydrocarbons from C8 hydrocarbons in an effluent from an oligomerization reactor. The effluent includes or is supplemented with an intermediary that can include C5 hydrocarbon, C6 hydrocarbon or mixtures of both. Consequently, the bottoms reboiler temperature can be lower.

    摘要翻译: 所公开的方法在具有在色谱柱进料中的轻质烯烃和重低聚物之间的沸点的中间体的蒸馏塔中分离轻烯烃与重低聚物。 本发明考虑在来自低聚反应器的流出物中分离C4烃与C8烃。 流出物包括或补充有可以包括C 5烃,C 6烃或两者的混合物的中间体。 因此,底部再沸器温度可以更低。

    Process for the purification of a diolefin hydrocarbon stream from a naphtha steam cracker
    25.
    发明授权
    Process for the purification of a diolefin hydrocarbon stream from a naphtha steam cracker 失效
    从石脑油蒸汽裂解器纯化二烯烃流的方法

    公开(公告)号:US06194626B1

    公开(公告)日:2001-02-27

    申请号:US09455424

    申请日:1999-12-06

    IPC分类号: C07C7163

    CPC分类号: C10G69/06 C10G45/34

    摘要: A cyclic process for the purification of a diolefin hydrocarbon stream produced in a naphtha steam cracker to produce a high quality diolefin hydrocarbon stream having extremely low levels of acetylene over an extended period because of the ability to readily cyclically regenerate catalyst contained in an off-line selective hydrogenation reaction zone. The spent or partially spent catalyst is contacted with a stream containing naphtha and hydrogen to restore at least a portion of the fresh catalyst activity by the extraction of polymer compounds therefrom.

    摘要翻译: 用于净化石脑油蒸汽裂化器中生产的二烯烃烃流的循环方法,以在延长的时间内产生具有极低水平乙炔的高质量二烯烃烃流,这是因为能够容易地循环再生包含在离线中的催化剂 选择性加氢反应区。 将消耗或部分废弃的催化剂与含有石脑油和氢气的流体接触,以通过从其中提取聚合物化合物来恢复至少一部分新鲜催化剂活性。

    Balanced alkylation feed from etherification and isomerization
    26.
    发明授权
    Balanced alkylation feed from etherification and isomerization 失效
    平衡烷基化进料从醚化和异构化

    公开(公告)号:US5672795A

    公开(公告)日:1997-09-30

    申请号:US533291

    申请日:1995-09-25

    IPC分类号: C07C41/06 C10L1/02 C07C41/05

    CPC分类号: C10L1/023 C07C41/06

    摘要: An etherification process combines an alkylation zone with a skeletal olefin isomerization zone in an arrangement that rejects isoalkanes and normal alkanes with only minor loss of valuable olefin isomers. The invention also provides a balanced feed to an alkylation zone for the production of high octane gasoline components. This invention can be used to provide ethers and gasoline boiling range alkylates from either C.sub.4 or C.sub.5 feedstocks. The invention fully utilizes all olefin isomers improve octane and vapor pressure charactristics of the gasoline components.

    摘要翻译: 醚化方法将烷基化区与骨架烯烃异构化区结合在一起,其排斥异烷烃和正烷烃,只有少量有价值的烯烃异构体损失。 本发明还提供了用于生产高辛烷值汽油组分的烷基化区的平衡进料。 本发明可用于从C4或C5原料提供醚和汽油沸程烷基化物。 本发明充分利用所有烯烃异构体提高汽油组分的辛烷值和蒸气压特性。

    High selectivity process for dehydrogenation of paraffinic hydrocarbons
    27.
    发明授权
    High selectivity process for dehydrogenation of paraffinic hydrocarbons 失效
    链烷烃脱氢的高选择性方法

    公开(公告)号:US4761509A

    公开(公告)日:1988-08-02

    申请号:US17964

    申请日:1987-02-24

    IPC分类号: C07C5/333 C07C11/02 C07C5/00

    CPC分类号: C07C11/02 C07C5/3337

    摘要: An improved process for the catalytic dehydrogenation of paraffinic hydrocarbons is disclosed. Feed paraffinic hydrocarbons are dehydrogenated to yield an olefin containing vapor stream which is partially condensed to produce a liquid phase process stream which contains byproduct diolefins along with the intended product monoolefins. The liquid phase process stream in admixture with hydrogen and a sulfur compound is passed through a selective hydrogenation zone in which diolefins are catalytically converted to monoolefins. This selective hydrogenation in the presence of trace quantities of a sulfur compound increases the quality of the product monoolefin stream. The selective hydrogenation zone is located between the vapor-liquid separator and the stripper column of the dehydrogenation zone.

    摘要翻译: 公开了一种用于链烷烃的催化脱氢的改进方法。 进料链烷烃被脱氢以产生含烯烃的蒸气流,其部分冷凝以产生液相工艺流,其中含有副产物二烯烃以及预期的产物单烯烃。 将与氢气和硫化合物混合的液相工艺流通过选择性氢化区,其中二烯烃被催化转化成单烯烃。 在微量硫化合物的存在下的这种选择性氢化增加了产物单烯烃流的质量。 选择性加氢区位于气液分离器和脱氢区的汽提塔之间。

    Light paraffin dehydrogenation process
    28.
    发明授权
    Light paraffin dehydrogenation process 失效
    轻链烷烃脱氢工艺

    公开(公告)号:US4695662A

    公开(公告)日:1987-09-22

    申请号:US848354

    申请日:1986-04-04

    申请人: Bipin V. Vora

    发明人: Bipin V. Vora

    CPC分类号: C07C41/06 C07C11/06

    摘要: A process is disclosed for the catalytic dehydrogenation of propane or butanes. The vapor phase reaction zone effluent stream is contacted with a heavy absorption liquid and then with a light absorption liquid. The light absorption liquid is composed of hydrocarbons recovered from the reaction zone effluent stream. This secondary contacting removes components of the heavy absorption liquid from the recycle gas, thus eliminating the deleterious effects of these compounds on the dehydrogenation catalyst. The heavy absorption liquid may be produced within the process by a catalytic olefin-consuming reaction zone.

    摘要翻译: 公开了用于丙烷或丁烷的催化脱氢的方法。 气相反应区流出物流与重吸收液体接触,然后与光吸收液接触。 光吸收液体由从反应区流出物流中回收的烃组成。 这种二次接触从循环气体中除去重吸收液体的组分,从而消除了这些化合物对脱氢催化剂的有害影响。 重吸收液体可以通过催化烯烃消耗反应区在该过程中产生。

    Adsorbent regeneration in etherification processes
    29.
    发明授权
    Adsorbent regeneration in etherification processes 失效
    醚化过程中的吸附剂再生

    公开(公告)号:US4575566A

    公开(公告)日:1986-03-11

    申请号:US598122

    申请日:1984-04-09

    申请人: Bipin V. Vora

    发明人: Bipin V. Vora

    IPC分类号: C07C41/06 C07C41/00

    CPC分类号: C07C41/06 Y02P20/125

    摘要: An improved method is disclosed for regenerating adsorbents used in an integrated process for the production of ethers such as methyl tertiary butyl ether by the reaction of an alcohol with an isoolefin. The sorbents are used to remove such compounds as the product ether and the feed alcohol from a hydrocarbon-rich stream withdrawn from the etherification zone. The regeneration procedure includes contacting the sorbent with a heated portion of the treated hydrocarbon stream. The resultant contaminated hydrocarbon stream is passed into a stripping column used to remove light ends from the effluent of a dehydrogenation zone in which the isoolefin fed to the etherification zone is produced. The hydrocarbonaceous compounds collected on the sorbent are thus recycled rather than being destroyed or lost in low purity effluent streams.

    摘要翻译: 公开了一种用于再生吸附剂的改进方法,所述吸附剂用于通过醇与异烯烃的反应来生产醚如甲基叔丁基醚的一体化方法。 吸附剂用于从从醚化区取出的富烃流中除去产物醚和进料醇中的这些化合物。 再生方法包括使吸附剂与经处理的烃流的加热部分接触。 所得到的被污染的烃流被送入汽提塔,用于从其中产生进入醚化区的异烯烃的脱氢区的流出物除去轻馏分。 因此,在吸附剂上收集的烃类化合物被循环使用,而不是在低纯度流出物流中被破坏或丢失。

    Integrated HF regeneration in aromatic hydrocarbon alkylation process
    30.
    发明授权
    Integrated HF regeneration in aromatic hydrocarbon alkylation process 失效
    在芳烃烷基化方法中综合HF再生

    公开(公告)号:US4467128A

    公开(公告)日:1984-08-21

    申请号:US534912

    申请日:1983-09-22

    申请人: Bipin V. Vora

    发明人: Bipin V. Vora

    摘要: A process is disclosed for the production of alkylaromatic hydrocarbons by the HF catalyzed reaction of an aromatic hydrocarbon with a C.sub.8 -plus acyclic olefin. A portion of the HF used as catalyst is regenerated by passage into a stripping column which has a primary function of stripping dissolved HF out of a hydrocarbonaceous mixture produced in the alkylation zone. This eliminates the requirement for a separate HF regeneration column and the costs associated with this column.

    摘要翻译: 公开了通过芳族烃与C 8加无环烯烃的HF催化反应生产烷基芳烃的方法。 用作催化剂的HF的一部分通过进入汽提塔再生,汽提塔具有从烷基化区产生的烃类混合物中汽提溶解的HF的主要功能。 这消除了单独的HF再生柱的需求和与该柱相关的成本。