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公开(公告)号:US11934759B2
公开(公告)日:2024-03-19
申请号:US17424043
申请日:2020-02-04
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Teppei Oguni , Takeshi Osada , Takahiro Fukutome
IPC: G06F7/50 , G06F30/367 , G06N3/042 , G06N3/08
CPC classification number: G06F30/367 , G06N3/042 , G06N3/08
Abstract: A parameter candidate for a semiconductor element is provided. A data set of measurement data is provided to a parameter extraction portion, and a model parameter is extracted. A first netlist is provided to a circuit simulator, simulation is performed using the first netlist and the model parameter, and a first output result is output. A classification model learns the model parameter and the first output result and classifies the model parameter. A second netlist and a model parameter are provided to the circuit simulator. A variable to be adjusted is supplied to a neural network, an action value function is output, and the variable is updated. The circuit simulator performs simulation using the second netlist and the model parameter. When a second output result to be output does not satisfy conditions, a weight coefficient of the neural network is updated. When the second output result satisfies the conditions, the variable is judged to be the best candidate.
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公开(公告)号:US11355784B2
公开(公告)日:2022-06-07
申请号:US16662083
申请日:2019-10-24
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Teppei Oguni , Junya Goto , Ai Nakagawa
IPC: H01M10/058 , H01M10/0525 , H01M10/0569 , H01M10/44
Abstract: In initial charge and discharge, decomposition products or a gas is generated, degrading a battery. At least one of solvents (e.g., ethylene carbonate) used for an electrolytic solution is brought into contact with a positive electrode and a negative electrode and then charge is performed to some degree, and after that, a different solvent or electrolytic solution (e.g., ethyl methyl carbonate or vinylene carbonate) was added to adjust the electrolytic solution and then charge is performed. Through this process, stable coating films are formed in initial charge and discharge, which stably inhibits a side reaction between the electrolytic solution and an active material.
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公开(公告)号:US10944110B2
公开(公告)日:2021-03-09
申请号:US16454116
申请日:2019-06-27
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Yumiko Yoneda , Teppei Oguni , Takuya Miwa , Masaki Yamakaji , Ayae Tsuruta
IPC: H01M4/587 , C01B32/23 , C01B32/225 , H01M10/0587 , H01M10/0525 , H01M4/1393 , H01M2/16 , H01M4/62 , H01M4/04 , H01M4/36 , H01M2/14 , H01M10/052 , H01M4/133 , H01M4/02
Abstract: To provide a manufacturing method of graphene oxide that allows mass production through a relatively simple process, at low costs, and with safety and efficiency. A hydrogen peroxide solution, sulfuric acid, and flake graphite are put in a reaction container, and the mixture is stirred to obtain expansion graphite. The synthesized expansion graphite is washed not with pure water but with a saturated aqueous solution of magnesium sulfate (MgSO4) or an organic solvent, whereby a large amount of sulfuric acid is contained between graphite layers. The expansion graphite is subjected to heat treatment or microwave irradiation to form expanded graphite, and a graphite layer is peeled by ultrasonic treatment and then oxidized to form a graphene compound.
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公开(公告)号:US10529990B2
公开(公告)日:2020-01-07
申请号:US15668743
申请日:2017-08-04
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Kai Kimura , Kazutaka Kuriki , Teppei Oguni , Aya Uchida
IPC: H01M4/13 , H01M4/62 , H01G11/28 , H01G11/24 , H01G11/26 , H01G11/38 , H01M4/133 , H01M10/0525 , H01M10/0566 , H01M10/44 , H01M4/02 , H01M10/42
Abstract: A power storage device with high capacity or high energy density is provided. A highly reliable power storage device is provided. A long-life power storage device is provided. An electrode includes an active material, a first binder, and a second binder. The specific surface area of the active material is S [m2/g]. The weight of the active material, the weight of the first binder, and the weight of the second binder are a, b, and c, respectively. The solution of {(b+c)/(a+b+c)}×100÷S is 0.3 or more. The electrode includes a first film in contact with the active material. The first film preferably includes a region in contact with the active material. The first film preferably includes a region with a thickness of 2 nm or more and 20 nm or less. The first film contains a water-soluble polymer.
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公开(公告)号:US10381646B2
公开(公告)日:2019-08-13
申请号:US15381152
申请日:2016-12-16
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Yumiko Yoneda , Teppei Oguni , Takuya Miwa , Masaki Yamakaji , Ayae Tsuruta
IPC: H01M10/0525 , H01M4/36 , H01M2/14 , H01M4/587 , H01M2/16 , H01M4/04 , H01M4/1393 , H01M10/0587 , H01M4/62 , C01B32/225 , C01B32/23 , H01M4/133 , H01M4/02 , H01M10/052
Abstract: To provide a manufacturing method of graphene oxide that allows mass production through a relatively simple process, at low costs, and with safety and efficiency. A hydrogen peroxide solution, sulfuric acid, and flake graphite are put in a reaction container, and the mixture is stirred to obtain expansion graphite. The synthesized expansion graphite is washed not with pure water but with a saturated aqueous solution of magnesium sulfate (MgSO4) or an organic solvent, whereby a large amount of sulfuric acid is contained between graphite layers. The expansion graphite is subjected to heat treatment or microwave irradiation to form expanded graphite, and a graphite layer is peeled by ultrasonic treatment and then oxidized to form a graphene compound.
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公开(公告)号:US10050273B2
公开(公告)日:2018-08-14
申请号:US14187574
申请日:2014-02-24
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Teppei Oguni , Takeshi Osada , Toshihiko Takeuchi
IPC: H01M4/00 , H01M4/583 , H01B1/04 , H01M4/133 , H01M4/134 , H01M4/1393 , H01M4/1395 , H01M4/38 , H01M4/587 , H01M4/62
CPC classification number: H01M4/583 , H01B1/04 , H01M4/133 , H01M4/134 , H01M4/1393 , H01M4/1395 , H01M4/386 , H01M4/587 , H01M4/626
Abstract: An electrode for a power storage device with good cycle characteristics and high charge/discharge capacity is provided. In addition, a power storage device including the electrode is provided. The electrode for the power storage device includes a conductive layer and an active material layer provided over the conductive layer, the active material layer includes graphene and an active material including a plurality of whiskers, and the graphene is provided to be attached to a surface portion of the active material including a plurality of whiskers and to have holes in part of the active material layer. Further, in the electrode for the power storage device, the graphene is provided to be attached to a surface portion of the active material including a plurality of whiskers and to cover the active material including a plurality of whiskers. Further, the power storage device including the electrode is manufactured.
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公开(公告)号:US10026966B2
公开(公告)日:2018-07-17
申请号:US13691929
申请日:2012-12-03
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Tetsuya Kakehata , Ryota Tajima , Teppei Oguni , Takeshi Osada , Shunpei Yamazaki , Shunsuke Adachi , Takuya Hirohashi
IPC: H01M4/70 , H01M4/04 , H01M4/66 , H01M4/134 , H01M4/1395 , H01M4/36 , H01M4/62 , B82Y30/00 , H01M10/052 , H01M4/02
Abstract: A lithium secondary battery which has high charge-discharge capacity, can be charged and discharged at high speed, and has little deterioration in battery characteristics due to charge and discharge is provided. A negative electrode includes a current collector and a negative electrode active material layer. The current collector includes a plurality of protrusion portions extending in a substantially perpendicular direction and a base portion connected to the plurality of protrusion portions. The protrusion portions and the base portion are formed using the same material containing titanium. A top surface of the base portion and at least a side surface of the protrusion portion are covered with the negative electrode active material layer. The negative electrode active material layer may be covered with graphene.
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公开(公告)号:US09787126B2
公开(公告)日:2017-10-10
申请号:US14173029
申请日:2014-02-05
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Shunpei Yamazaki , Teppei Oguni
IPC: H02J7/00
CPC classification number: H02J7/0093 , H02J7/0075
Abstract: When a hole in a separator is clogged, the cycle characteristics of a battery might be lowered and the internal resistance of a battery might be increased to reduce the output. Thus, a means for suppression of or recovery from degradation due to a clogged separator in a battery such as a lithium-ion secondary battery is provided. When reverse pulse current is supplied multiple times during charge, a separator is prevented from being clogged and a voltage increase (increase in internal resistance) during charge is suppressed, so that charge can be normally performed repeatedly.
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公开(公告)号:US09577268B2
公开(公告)日:2017-02-21
申请号:US14886185
申请日:2015-10-19
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Kazutaka Kuriki , Teppei Oguni
IPC: H01M4/70 , H01M4/134 , H01M4/64 , H01M4/04 , H01M4/66 , H01G11/66 , H01M10/0562 , H01M10/0565 , H01M10/0585 , H01M10/0587 , H01M10/052 , H01M10/058
CPC classification number: H01M4/70 , H01G11/66 , H01M4/04 , H01M4/134 , H01M4/64 , H01M4/661 , H01M10/052 , H01M10/0562 , H01M10/0565 , H01M10/058 , H01M10/0585 , H01M10/0587 , H01M2220/30 , Y02E60/122 , Y02E60/13 , Y02P70/54 , Y10T29/49108
Abstract: A power storage device is reduced in weight. A metal sheet serving as a negative electrode current collector is separated and another negative electrode current collector is formed. For example, through the step of forming silicon serving as a negative electrode active material layer over a titanium sheet and then performing heating, the titanium sheet can be separated. Then, another negative electrode current collector with a thickness of more than or equal to 10 nm and less than or equal to 1 μm is formed. Thus, light weight of the power storage device can be achieved.
Abstract translation: 蓄电装置重量减轻。 分离用作负极集电体的金属片,形成另一负极集电体。 例如,通过在钛板上形成作为负极活性物质层的硅,然后进行加热的步骤,可以分离钛片。 然后,形成厚度大于等于10nm且小于等于1μm的另一负极集电体。 因此,可以实现蓄电装置的轻量化。
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公开(公告)号:US09461300B2
公开(公告)日:2016-10-04
申请号:US13626054
申请日:2012-09-25
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Takeshi Osada , Ryota Tajima , Teppei Oguni , Shunpei Yamazaki
CPC classification number: H01M4/134 , H01M2/1673 , H01M2/18 , H01M4/366 , H01M4/587 , H01M4/625 , H01M10/0525 , H01M2004/025 , H01M2004/027 , Y02E60/122
Abstract: Provided are an electrode for a power storage device having much better charge/discharge characteristics and a power storage device using the electrode. A plurality of cavities is provided in a surface of an active material layer over a current collector. A graphene covering the active material layer facilitates rapid charge/discharge and prevents breakdown of the current collector caused by charge/discharge. With improved charge/discharge characteristics, an electrode for a power storage device which does not easily deteriorate and a power storage device using the electrode can be provided.
Abstract translation: 提供一种具有更好的充电/放电特性的蓄电装置的电极和使用该电极的蓄电装置。 在集电体上方的活性物质层的表面设有多个空腔。 覆盖活性材料层的石墨烯有助于快速充电/放电,并防止由充电/放电引起的集电器故障。 具有改善的充电/放电特性,可以提供不容易劣化的蓄电装置用电极和使用电极的蓄电装置。
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