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公开(公告)号:US10899975B2
公开(公告)日:2021-01-26
申请号:US16368247
申请日:2019-03-28
Applicant: UOP LLC
Inventor: Gautam Madhusadan Pandey , Krishna Mani , Deepak Bisht , Priyesh Jayendrakumar Jani , Vikrant Vilasrao Dalal , Ram Ganesh Rokkam
Abstract: An integrated process for maximizing recovery of hydrogen is provided. The process comprises: providing a hydrocarbonaceous feed comprising naphtha, and a hydrogen stream to a reforming zone, wherein the hydrogen stream is obtained from at least one of a hydrocracking zone, a transalkylation zone, and an isomerization zone. The hydrocarbonaceous feed is reformed in the reforming zone in the presence of the hydrogen stream and a reforming catalyst to provide a reformate effluent stream. At least a portion of the reformate effluent stream is passed to a debutanizer column of the reforming zone to provide a net hydrogen stream and a fraction comprising liquid petroleum gas (LPG). At least a portion of the net hydrogen stream is recycled to the reforming zone as the hydrogen stream.
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公开(公告)号:US20180119036A1
公开(公告)日:2018-05-03
申请号:US15702568
申请日:2017-09-12
Applicant: UOP LLC
Inventor: Krishna Mani , Kanchan Dutta , Avnish Kumar , Anjan Ray
IPC: C10L1/08
CPC classification number: C10L1/08 , C10G3/46 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/805 , C10G2400/04 , C10L2270/026 , Y02P30/20
Abstract: Processes for the production of transportation fuel from a renewable feedstock. A catalyst is used which is more selective to hydrodeoxygenate the fatty acid side chains compared to decarboxylation and decarbonylation reactions. A gaseous mixture of carbon monoxide and hydrogen can be supplied to the conversion zone. Water may also be introduced into the conversion zone to increase the amount of hydrogen.
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23.
公开(公告)号:US20170037322A1
公开(公告)日:2017-02-09
申请号:US15226716
申请日:2016-08-02
Applicant: UOP LLC
Inventor: Kanchan Dutta , Paul T. Barger , David E. Mackowiak , Anjan Ray , Krishna Mani , Avnish Kumar
CPC classification number: C10G3/52 , C10G3/42 , C10G3/50 , C10G2300/1014 , C10G2300/1025 , C10G2300/202 , C10G2300/42 , C10G2300/807 , C10G2400/04 , C10G2400/28 , C10L2200/0484 , C10L2270/026 , C10L2290/04 , C10L2290/06 , C10L2290/141 , C10L2290/148 , Y02P30/20
Abstract: Processes for the production of transportation fuel from a renewable feedstock. A gaseous mixture of carbon monoxide and hydrogen is used to deoxygenate and hydrogenate the glycerides to produce long chain hydrocarbons. Water is also introduced into the reaction zone to increase the amount of hydrogen and to increase the utilization of carbon monoxide within the reaction zone. Synthesis gas may also be used to supply at least a portion of the gaseous mixture of carbon monoxide and hydrogen. The amount of hydrogen equivalents in the reaction zone is at least 100% of a stoichiometric hydrogen demand within the reaction zone.
Abstract translation: 从可再生原料生产运输燃料的过程。 使用一氧化碳和氢气的气体混合物使甘油酯脱氧并氢化以产生长链烃。 水也被引入反应区以增加氢的量并增加反应区内一氧化碳的利用。 合成气体也可用于供应至少一部分一氧化碳和氢气的气态混合物。 反应区中的氢当量的量为反应区内化学计量氢需求的至少100%。
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24.
公开(公告)号:US12173238B2
公开(公告)日:2024-12-24
申请号:US17349432
申请日:2021-06-16
Applicant: UOP LLC
Inventor: Krishan Pratap Jadaun , Hari S. Bajpai , Krishna Mani
Abstract: A process for hydrotreating a renewable feedstock with improved carbon monoxide management is disclosed. A mixture of renewable feedstock and hydrocarbon feedstock is treated in a hydrotreating reactor to produce a hydrotreated effluent stream and contacting the hydrotreated effluent stream with a water gas shift catalyst bed to produce a shift reactor effluent stream. The shift reactor effluent stream is passed to a cold separator to recover a cold vapor stream and recycling the cold vapor stream having reduced concentration of carbon monoxide to the hydrotreating zone. The subject matter disclosed provides an improved process and apparatus to reduce the accumulation of CO by converting CO present in the hydrotreated effluent stream to CO2 using the water shift gas reaction.
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公开(公告)号:US20240132785A1
公开(公告)日:2024-04-25
申请号:US18395128
申请日:2023-12-22
Applicant: UOP LLC
Inventor: Andrea G. Bozzano , Krishan Pratap Jadaun , Krishna Mani , Stanley Joseph Frey
CPC classification number: C10G3/50 , C07C2/64 , C07C2/76 , C07C15/107 , C10G3/42 , C10G45/02 , C10G45/58 , C10G2300/1014 , C10G2300/1051 , C10G2400/04 , C10G2400/08 , C10G2400/30
Abstract: Hydrodeoxygenating a biorenewable feed that is concentrated in free fatty acids with 12 and 14 carbon atoms at a moderate hydrodeoxygenation ratio that is less than the ratio of hydrodeoxygenation utilized for traditional biorenewable feeds such as vegetable oil or even mineral feedstocks, normal paraffins in the range desired by the detergents industry can be produced. Either hydroisomerization or an iso-normal separation can be performed to provide green fuel streams. Two reactors are proposed, one for hydrodeoxygenation of the biorenewable feed that is concentrated in free fatty acids with 12 and 14 carbon atoms and the other for a traditional biorenewable feed or even a mineral feed operated at a higher deoxygenation ratio.
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公开(公告)号:US20230250347A1
公开(公告)日:2023-08-10
申请号:US18135278
申请日:2023-04-17
Applicant: UOP LLC
Inventor: Andrea G. Bozzano , Haiyan Wang , Krishna Mani , Stanley Joseph Frey
CPC classification number: C10G69/04 , C10G3/42 , C10G3/50 , C10G7/00 , C10G45/58 , C10G2300/1011 , C10G2300/4081 , C10G2400/04 , C10G2400/08
Abstract: The apparatus produces a diesel stream from a biorenewable feedstock by hydrotreating to remove heteroatoms and hydroisomerization to improve cold flow properties. Heavy diesel can be hydrocracked to jet fuel range material or further hydroisomerized to increase its value lower its freeze point while light diesel may be taken as a motor fuel.
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公开(公告)号:US11655424B2
公开(公告)日:2023-05-23
申请号:US17497284
申请日:2021-10-08
Applicant: UOP LLC
Inventor: Andrea G. Bozzano , Haiyan Wang , Krishna Mani , Stanley Joseph Frey
CPC classification number: C10G69/04 , C10G3/42 , C10G3/50 , C10G7/00 , C10G45/58 , C10G2300/1011 , C10G2300/4081 , C10G2400/04 , C10G2400/08
Abstract: The process produces a diesel stream from a biorenewable feedstock by hydrotreating to remove heteroatoms and hydroisomerization to improve cold flow properties. Heavy diesel can be hydrocracked to jet fuel range material or further hydroisomerized to increase its value lower its freeze point while light diesel may be taken as a motor fuel.
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公开(公告)号:US11104855B2
公开(公告)日:2021-08-31
申请号:US16558060
申请日:2019-08-31
Applicant: UOP LLC
Inventor: Stanley Joseph Frey , Krishna Mani , Krishan Pratap Jadaun , Gautam Pandey , Mousumi Chanda
Abstract: Processes for co-processing a naphtha stream with a light cycle oil stream are disclosed. The processes include hydrocracking the light cycle oil stream under hydrocracking conditions to provide a hydrocracked effluent stream. A naphtha stream is hydrotreated under hydrotreating conditions to provide a hydrotreated effluent stream. The hydrocracked effluent stream and the hydrotreated effluent stream may be passed to a stripping column to recover a stripping bottom stream. The stripping bottom stream may be passed to a main fractionation column to recover an intermediate naphtha stream.
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公开(公告)号:US11040926B2
公开(公告)日:2021-06-22
申请号:US16517865
申请日:2019-07-22
Applicant: UOP LLC
Inventor: Gautam Pandey , Krishna Mani , Deepak Bisht , Priyesh Jayendrakumar Jani , Vikrant Vilasrao Dalal , Ram Ganesh Rokkam
Abstract: An integrated process for maximizing recovery of aromatics is provided. The process comprises passing at least a portion of a xylene column bottoms stream to a heavy aromatics column to provide a heavy aromatics column bottoms stream comprising C9+ aromatics and a heavy aromatics column overhead stream. The heavy aromatics column bottoms stream is passed to a second stage hydrocracking reactor of a two-stage hydrocracking reactor. In the second stage hydrocracking reactor, the heavy aromatics column bottoms stream is hydrocracked in the presence of a hydrocracking catalyst and hydrogen to provide a hydrocracked effluent stream.
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公开(公告)号:US10240099B2
公开(公告)日:2019-03-26
申请号:US15702568
申请日:2017-09-12
Applicant: UOP LLC
Inventor: Krishna Mani , Kanchan Dutta , Avnish Kumar , Anjan Ray
Abstract: Processes for the production of transportation fuel from a renewable feedstock. A catalyst is used which is more selective to hydrodeoxygenate the fatty acid side chains compared to decarboxylation and decarbonylation reactions. A gaseous mixture of carbon monoxide and hydrogen can be supplied to the conversion zone. Water may also be introduced into the conversion zone to increase the amount of hydrogen.
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