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    Chromium-enriched oxide containing material and preoxidation method of making the same to mitigate corrosion and fouling associated with heat transfer components
    32.
    发明授权
    Chromium-enriched oxide containing material and preoxidation method of making the same to mitigate corrosion and fouling associated with heat transfer components 失效
    富含铬的氧化物材料和预氧化方法，以减少与传热组分相关的腐蚀和结垢

    公开(公告)号：US08037928B2

    公开(公告)日：2011-10-18

    申请号：US11641750

    申请日：2006-12-20

    Applicant: ChangMin Chun ,  Mark A. Greaney ,  Thomas Bruno ,  Ian A. Cody ,  Trikur A. Ramanarayanan

    Inventor： ChangMin Chun ,  Mark A. Greaney ,  Thomas Bruno ,  Ian A. Cody ,  Trikur A. Ramanarayanan

    IPC: F28F19/00 ,  F28D7/10

    CPC classification number: F28D7/16 ,  C10G9/203 ,  C10G2300/4075 ,  F28D2021/0059 ,  F28F19/00 ,  F28F19/002 ,  F28F19/02 ,  F28F19/06 ,  F28F21/082 ,  F28F21/083 ,  F28F25/08 ,  F28G7/00 ,  Y10T428/12549 ,  Y10T428/1259

    Abstract: A heat transfer component that is resistant to corrosion and fouling is disclosed. The heat transfer component includes a heat exchange surface formed from a chromium-enriched oxide containing material formed from the composition δ, ε, and ζ, wherein ζ is a steel containing at least about 5 to about 40 wt. % chromium, ε is a chromium enriched oxide (M3O4 or M2O3 or mixtures thereof) formed on the surface of the steel ζ, wherein M is a metal containing at least 5 wt. % Cr based on the total weight of the metal M, and δ is a top layer formed on the surface of the chromium-enriched oxide ε, comprising sulfide, oxide, oxysulfide, and mixtures thereof. The top layer δ comprises iron sulfide (Fe1-xS), iron oxide (Fe3O4), iron oxysulfide, iron-chromium sulfide, iron-chromium oxide, iron-chromium oxysulfide, and mixtures thereof. The metal M of the chromium enriched oxide (M3O4 or M2O3 or mixtures thereof) may comprise Fe, Cr, and constituting elements of the steel ζ. The steel ζ may be selected from low chromium steels, ferritic stainless steels, martensitic stainless steels, austenitic stainless steels, duplex stainless steels and precipitation-hardenable alloys.

    Abstract translation: 公开了耐腐蚀和结垢的传热部件。 传热组分包括由组合物δ，＆egr和ζ形成的含铬富氧材料形成的热交换表面，其中ζ是含有至少约5至约40重量％ ％铬， 是在钢ζ的表面上形成的富含铬的氧化物（M3O4或M2O3或其混合物），其中M是含有至少5wt。 ％Cr，基于金属M的总重量，δ是在富含铬的氧化物的表面上形成的顶层，其包含硫化物，氧化物，硫氧化物及其混合物。 顶层δ包括硫化铁（Fe1-xS），氧化铁（Fe3O4），硫氧化铁，铁 - 硫化铬，铁 - 铬氧化物，铁 - 硫氧化铬及其混合物。 富含铬的氧化物（M3O4或M2O3或其混合物）的金属M可以包含Fe，Cr和构成元素的ζ。 钢ζ可以选自低铬钢，铁素体不锈钢，马氏体不锈钢，奥氏体不锈钢，双相不锈钢和沉淀硬化合金。

    Method for demetallating refinery feedstreams
    36.
    发明授权
    Method for demetallating refinery feedstreams 失效
    炼油厂原料流脱矿方法

    公开(公告)号：US5529684A

    公开(公告)日：1996-06-25

    申请号：US440438

    申请日：1995-05-12

    Applicant: Mark A. Greaney ,  Michael C. Kerby, Jr. ,  William N. Olmstead ,  Irwin A. Wiehe

    Inventor： Mark A. Greaney ,  Michael C. Kerby, Jr. ,  William N. Olmstead ,  Irwin A. Wiehe

    IPC: C10G19/02 ,  C10G32/02 ,  C10G33/02 ,  C25C1/06 ,  C25C1/22 ,  C10G32/00

    CPC classification number: C10G32/02

    Abstract: The present invention provides for a method of decreasing the metals content of metal containing petroleum streams by forming a mixture of the petroleum fraction containing those metals and an essentially aqueous electrolysis medium, and passing an electric current through the mixture at a voltage, pH and time sufficient to remove the metals such as Ni, V and Fe from the stream (i.e. to produce a petroleum fraction having decreased content of the metals). The cathodic voltage is from 0 V to -3.0 V vs. SCE at a pH of from 6 to 14, preferably 7 to 14, most preferably above 7 to 14.The invention provides a method for enhancing the value of petroleum feeds that traditionally have limited use in refineries due to their Ni and V content.

    Abstract translation: 本发明提供了一种通过形成含有这些金属的石油馏分和基本上含水的电解介质并使电流在电压，pH和时间下通过混合物的混合物来降低含金属的石油流的金属含量的方法 足以从流中除去诸如Ni，V和Fe的金属（即产生具有降低的金属含量的石油馏分）。 pH为6至14，优选7至14，最优选高于7至14时，阴极电压为0 V至-3.0 V，相对于SCE。本发明提供了一种增强传统上具有 由于其Ni和V含量，炼油厂的使用受到限制。

    Process for separating solute material from an algal cell feed stream
    37.
    发明授权
    Process for separating solute material from an algal cell feed stream 有权
    从藻类细胞进料流中分离溶质的方法

    公开(公告)号：US08877058B2

    公开(公告)日：2014-11-04

    申请号：US13285834

    申请日：2011-10-31

    Applicant: Mark A. Greaney ,  James R. Bielenberg ,  Paul D. Oldenburg

    Inventor： Mark A. Greaney ,  James R. Bielenberg ,  Paul D. Oldenburg

    IPC: B01D11/00 ,  C07C51/48 ,  C11B1/10

    CPC classification number: C07C51/48 ,  C11B1/10 ,  C07C53/126 ,  C07C57/03

    Abstract: This invention provides a process for separating solute material from an algal cell feed stream. The algal cell feed stream, which contains the solute material, can be introduced into on portion of a mixer-settler vessel, and a solvent feed stream can be introduced into another portion of the vessel to mix with the algal cell feed stream, with a goal of separating at least a portion of the solute material from the algal feed stream.

    Abstract translation: 本发明提供了从藻类细胞进料流中分离溶质的方法。 将含有溶质材料的藻类细胞进料流引入混合器 - 沉降器容器的一部分上，并将溶剂进料流引入容器的另一部分以与藻类细胞进料流混合， 将溶质材料的至少一部分与藻类进料流分离的目标。

    Crude oil pre-heat train with improved heat transfer
    38.
    发明授权
    Crude oil pre-heat train with improved heat transfer 失效
    原油预热火车具有改善的热传递

    公开(公告)号：US08349267B2

    公开(公告)日：2013-01-08

    申请号：US12232946

    申请日：2008-09-26

    Applicant: Ian A Cody ,  Amar S. Wanni ,  Robert C. Welch ,  James E. Feather ,  Mark A. Greaney ,  Limin Song ,  Jasmina Poturovic

    Inventor： Ian A Cody ,  Amar S. Wanni ,  Robert C. Welch ,  James E. Feather ,  Mark A. Greaney ,  Limin Song ,  Jasmina Poturovic

    IPC: B01J8/00

    CPC classification number: C10G75/04 ,  C10G9/16

    Abstract: Targeted application of anti-fouling mechanisms in a heat exchange system produces higher rates of energy recovery. The anti-fouling mechanisms with high mitigation rates can be deployed at only the hottest portions of a pre-heat train that experience the highest rates of fouling and heat loss. In application, bundles of corrosion resistant smoothed tubes are deployed in the late pre-heat train to significantly reduce the formation of harder deposits. Vibration can be used as an adjunct approach in conjunction with the corrosion resistant, smooth tubes, or deployed alone on existing bundles. The use of high performing, more durable exchangers in select locations justifies the increased cost of these components.

    Abstract translation: 防污机构在热交换系统中的目标应用产生更高的能量回收率。 具有高缓解率的防污机制只能部署在经受最高污染和热损失率的预热列车的最热部分。 在应用中，在后期预热火车中部署了耐腐蚀平滑管束，以显着减少较硬沉积物的形成。 振动可以作为辅助方法与耐腐蚀，光滑的管一起使用，或单独部署在现有的束上。 在选择的位置使用高性能，更耐用的交换器证明了这些部件的成本增加。

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