ZEOLITIC MATERIAL HAVING A FRAMEWORK STRUCTURE COMPRISING SI, O, AND TI

    公开(公告)号:US20230191378A1

    公开(公告)日:2023-06-22

    申请号:US17912868

    申请日:2021-03-22

    申请人: BASF SE

    IPC分类号: B01J29/70 C01B39/02 B01J29/06

    摘要: The present invention relates to a zeolitic material having a framework structure comprising Si, O, and Ti, obtained or obtainable from a Ti containing compound, wherein the Ti containing compound has an APHA color number of ≤ 300. In a second aspect, the invention relates to the Ti containing compound having an APHA color number of ≤ 300. A third aspect of the present invention is related to the use of the Ti containing compound having an APHA color number of ≤ 300 of the second aspect for the preparation of a zeolitic material having framework structure comprising Si, O, and Ti, as well as to a process for preparation of a zeolitic material as in the first aspect having a framework structure comprising Si, O, and Ti, wherein the zeolitic material having a framework structure comprising Si, O, and Ti, is prepared from a Ti containing compound having an APHA color number of ≤ 300 as of the second aspect. A fourth aspect of the invention is directed to a molding comprising the zeolitic material having a framework structure comprising Si, O, and Ti as of the first aspect, as well as to the use of the molding as an adsorbent, an absorbent, a catalyst or a catalyst component. A fifth aspect of the invention relates to a process for oxidizing an organic compound comprising bringing an organic compound in contact with a catalyst comprising a molding as of the fourth aspect, wherein a sixth aspect relates to propylene oxide obtained or obtainable from the process according to the fifth aspect.

    PROPENE RECOVERY BY SCRUBBING WITH A SOLVENT/WATER MIXTURE

    公开(公告)号:US20210002241A1

    公开(公告)日:2021-01-07

    申请号:US16500313

    申请日:2018-04-13

    申请人: BASF SE

    IPC分类号: C07D301/32 C07D301/19

    摘要: The invention relates to a process for preparing propylene oxide, comprising (i) providing a stream comprising propene, propane, hydrogen peroxide or a source of hydrogen peroxide, water, and an organic solvent; (ii) passing the liquid feed stream provided in (i) into an epoxidation zone comprising an epoxidation catalyst comprising a titanium zeolite, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising propene, propane, propylene oxide, water, and the organic solvent; (iii) removing an effluent stream from the epoxidation zone, the effluent stream comprising propene, propane, propylene oxide, water, and the organic solvent; (iv) separating propene and propane from the effluent stream by distillation, comprising subjecting the effluent stream to distillation conditions in a distillation unit, obtaining a gaseous stream (S1) which is enriched in propene and propane compared to the effluent stream subjected to distillation conditions, and a liquid bottoms stream (S2) which is enriched in propylene oxide, water and organic solvent compared to the effluent stream subjected to distillation conditions; (v) separating propane from the stream (S1) in a separation zone, comprising subjecting the stream (S1) to washing conditions in a scrubber, wherein a solvent mixture comprising organic solvent and water is added as entraining agent, obtaining a bottoms stream (S3), which comprises organic solvent, water and at least 70 weight-% of the propene comprised in (S1); and a gaseous top stream (S4), which comprises at least 5 weight-% of the propane comprised in stream (S1).

    PROCESS FOR PREPARING A TITANIUM-CONTAINING ZEOLITIC MATERIAL HAVING AN MWW FRAMEWORK STRUCTURE
    39.
    发明申请
    PROCESS FOR PREPARING A TITANIUM-CONTAINING ZEOLITIC MATERIAL HAVING AN MWW FRAMEWORK STRUCTURE 审中-公开
    制备含有MWW框架结构的含钛的ZEOLITIC材料的方法

    公开(公告)号:US20150368115A1

    公开(公告)日:2015-12-24

    申请号:US14764354

    申请日:2014-02-05

    申请人: BASF SE

    IPC分类号: C01B39/48 B01J29/89

    摘要: A process for the preparation of a titanium-containing zeolitic material having an MWW framework structure, the process comprising (i) providing a zeolitic material having an MWW framework structure comprising SiO2 and B2O3, (ii) incorporating titanium into the zeolitic material provided in (i) comprising (ii.1) preparing an aqueous synthesis mixture containing the zeolitic material provided in (i), an MWW template compound and a titanium source, (ii.2) hydrothermally synthesizing a titanium-containing zeolitic material having an MWW framework structure from the aqueous synthesis mixture prepared in (ii.1), obtaining a mother liquor comprising the titanium-containing zeolitic material having an MWW framework structure; (iii) spray-drying the mother liquor obtained from (ii.2) comprising the titanium-containing zeolitic material having an MWW framework structure.

    摘要翻译: 一种制备具有MWW骨架结构的含钛沸石材料的方法,该方法包括(i)提供具有包含SiO 2和B 2 O 3的MWW骨架结构的沸石材料,(ii)将钛掺入提供于( i)包括(ii.1)制备含有(i)中提供的沸石材料的水性合成混合物,MWW模板化合物和钛源,(ii.2)水热合成具有MWW骨架结构的含钛沸石材料 从(ii.1)中制备的水性合成混合物得到含有具有MWW骨架结构的含钛沸石材料的母液; (iii)喷雾干燥由(ii.2)得到的母液,该母液包含具有MWW骨架结构的含钛沸石材料。