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31.发明授权Liquid diene polymers and copolymers terminated by reaction with fused-ring polynuclear aromatic compounds 失效通过与稠环多核芳族化合物反应终止的液体二烯聚合物和共聚物
公开(公告)号：US5334665A
公开(公告)日：1994-08-02
申请号：US58340
申请日：1993-05-06
CPC分类号： C08C19/44
摘要： A terminally functionalized liquid polymer is prepared by reacting a low molecular weight living diene polymer or copolymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer with a fused-ring polynuclear aromatic compound. The resultant terminally functionalized liquid diene polymers or copolymers can be utilized as dispersants for particulates such as carbon black or graphite and may also be employed as viscosity modifiers for lubricating oils or in electrorheological devices or damping devices.
摘要翻译： 通过二烯单体或二烯单体和乙烯基芳烃单体的混合物的阴离子聚合得到的低分子量活性二烯聚合物或共聚物与稠环多核芳族化合物反应来制备末端官能化液体聚合物。 得到的末端官能化液态二烯聚合物或共聚物可用作颗粒物如炭黑或石墨的分散剂，也可用作润滑油的粘度改进剂或电流变学装置或阻尼装置。
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32.发明授权Diene polymers and copolymers terminated with compounds having multiple-bonded nitrogen atoms and partially crosslinked with polyfunctional reagents 失效二烯聚合物和共聚物用具有多键氮原子并与多官能试剂部分交联的化合物封端
公开(公告)号：US5310798A
公开(公告)日：1994-05-10
申请号：US106729
申请日：1993-08-16
IPC分类号： C08F8/30 , C08C19/44 , C08F236/04 , C08F236/10 , C08F8/40
CPC分类号： C08C19/44
摘要： Diene polymers or copolymers having improved raw polymer viscosity and reduced hysteresis in the cured and carbon black reinforced state are provided. These diene polymers or copolymers are prepared by a method which involves first terminating substantially all of the living diene polymer or copolymer chains obtained by anionic polymerization with a compound having multiple-bonded nitrogen atoms selected from the group consisting of aromatic nitriles and substituted imines having the formula ##STR1## and then coupling a portion of the resultant terminated polymer chains with a polyfunctional reagent selected from the groups consisting of silicon polyhalides, polyisocyanates, phosphoryl halides and polycarboxylic acid halides.
摘要翻译： 提供了在固化和炭黑增强状态下具有改进的原料聚合物粘度和降低的滞后的二烯聚合物或共聚物。 这些二烯聚合物或共聚物是通过一种方法制备的，该方法包括首先使具有多键键氮原子的化合物基本上所有的通过阴离子聚合得到的活性二烯聚合物或共聚物链终止，所述化合物具有选自芳族腈和具有 然后将一部分所得的封端的聚合物链与选自多硅卤化物，多异氰酸酯，磷酰卤和多羧酸卤化物的多官能试剂偶联。
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33.发明授权Diene polymers and copolymers terminated by reaction with fused-ring polynuclear aromatic compounds 失效用熔融多环芳香化合物反应终止的二烯聚合物和共聚物
公开(公告)号：US5210145A
公开(公告)日：1993-05-11
申请号：US812258
申请日：1991-12-20
CPC分类号： C08C19/44
摘要： A terminally functionalized polymer is prepared by reacting a living polymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer with a fused-ring polynuclear aromatic compound. The resultant terminally functionalized polymers have reduced hysteresis in the carbon black reinforced and cured state and can be utilized to form elastomer compositions for tire treads having reduced rolling resistance.
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公开(公告)号：US5153159A
公开(公告)日：1992-10-06
申请号：US506305
申请日：1990-04-09
IPC分类号： B60C1/00 , C08C19/26 , C08C19/44 , C08F4/00 , C08F4/42 , C08F4/48 , C08F8/42 , C08F12/00 , C08F12/08 , C08F36/00 , C08F36/04 , C08F36/06 , C08F297/04 , C08K3/02 , C08K3/04 , C08L21/00
摘要： An anionic polymerization initiator comprising the reaction product of a functionalizing agent selected from the group consisting of substituted aldimines, ketimines and secondary amines and, an organolithium compound. Elastomeric polymers prepared with these initiators have functional sites incorporated at the initiator end of the polymer chain and provide vulcanizable rubber compounds exhibiting reduced hysteresis. Articles such as tires, produced with low hysteresis elastomeric polymers have lower rolling resistance. Methods are also provided for preparing the initiators, fuctionalized polymers and vulcanizable elastomeric compounds having reduced hysteresis.
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35.发明授权
公开(公告)号：US4137330A
公开(公告)日：1979-01-30
申请号：US876385
申请日：1978-02-09
IPC分类号： C01B21/097 , C01B21/098 , C01B25/10
CPC分类号： C01B21/0986 , C01B21/097
摘要： A process for producing benzene-soluble substantially linear dichlorophosphazene polymer having the formula (NPCl.sub.2).sub.x, in which x is greater than 20 and may be as high as 50,000 or higher, from a cyclic oligomer having the formula (NPCl.sub.2).sub.n, in which n is from 3 to 9, particularly the trimer (NPCl.sub.2).sub.3 or tetramer (NPCl.sub.2).sub.4, in the presence of a small but significant amount of an inorganic salt, preferably a halide of a metal such as Cr, Ni, Co, Cu, Fe, Mn or Mg which affords control of the molecular weight and avoids the formation of large amounts of gel.
摘要翻译： 从具有式（NPCl2）n的环状低聚物生产具有式（NPCl2）x的苯可溶性基本线性二氯膦腈聚合物的方法，其中x大于20并可高达50,000或更高，其中 n为3至9，特别是三聚物（NPCl2）3或四聚体（NPCl2）4，在少量但显着量的无机盐存在下，优选金属如Cr，Ni，Co，Cu的卤化物 ，Fe，Mn或Mg，可以控制分子量，避免形成大量的凝胶。
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36.发明授权Functionalized polymer and rubber compositions produced from solubilized anionic polymerization initiators 失效由溶解的阴离子聚合引发剂制备的官能化聚合物和橡胶组合物
公开(公告)号：US5552473A
公开(公告)日：1996-09-03
申请号：US469389
申请日：1995-06-05
CPC分类号： C08F4/086 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08F36/04 , Y10S152/905
摘要： The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL).sub.y. SOL is a solubilizing component and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y is from about 1 to 4. The cyclic amine has an alkylene, oxy- or amino-alkylene group having from about 3 to about 16 methylene groups. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer wtih a multifunctionality.
摘要翻译： 本发明涉及可溶于无环烷烃溶剂的阴离子聚合引发剂。 引发剂包括具有通式（A）Li（SOL）y的溶解的锂胺。 SOL是增溶组分，A是烷基，二烷基或环烷基胺基或环状胺，y约为1-4。环状胺具有约3至约16的亚烷基，氧基或氨基亚烷基 亚甲基。 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以提供聚合物多功能性。
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公开(公告)号：US5616704A
公开(公告)日：1997-04-01
申请号：US639980
申请日：1996-04-29
CPC分类号： C08F4/086 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08F36/04 , Y10S152/905
摘要： The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL).sub.y. SOL is a solubilizing component and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y is from about 1 to 4. The cyclic amine has an alkylene, oxy- or amino-alkylene group having from about 3 to about 16 methylene groups. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译： 本发明涉及可溶于无环烷烃溶剂的阴离子聚合引发剂。 引发剂包括具有通式（A）Li（SOL）y的溶解的锂胺。 SOL是增溶组分，A是烷基，二烷基或环烷基胺基或环状胺，y约为1-4。环状胺具有约3至约16的亚烷基，氧基或氨基亚烷基 亚甲基。 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。
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公开(公告)号：US5332810A
公开(公告)日：1994-07-26
申请号：US955969
申请日：1992-10-02
IPC分类号： C07F1/02 , B60C1/00 , C08C19/44 , C08F4/00 , C08F4/08 , C08F4/42 , C08F4/48 , C08F36/04 , C08K3/04 , C08L9/00 , C08L21/00 , C07D295/02
CPC分类号： C08F4/086 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08F36/04
摘要： The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL).sub.y. SOL is a solubilizing component and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y is from about 1 to 4. The invention is also directed toward polymers and other products made using the initiator, and methods therefore. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译： 本发明涉及可溶于无环烷烃溶剂的阴离子聚合引发剂。 引发剂包括具有通式（A）Li（SOL）y的溶解的锂胺。 SOL是增溶组分，A是烷基，二烷基或环烷基胺基或环胺，y约为1-4。本发明还涉及使用引发剂制备的聚合物和其它产物，因此也涉及方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。
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公开(公告)号：US5329005A
公开(公告)日：1994-07-12
申请号：US955582
申请日：1992-10-02
IPC分类号： B60C1/00 , C07F1/02 , C08F4/00 , C08F4/08 , C08F4/42 , C08F4/48 , C08F36/00 , C08F36/04 , C08K3/04 , C08L9/00 , C08L21/00 , C07D487/08 , C07D295/00
CPC分类号： C08F36/04
摘要： The present invention is directed toward anionic polymerization initiators which are soluble in hydrocarbon solvents. The initiators include a lithio amine having the general formula ALi. The component A is a dialkyl or dicycloalkyl amine radical or a cyclic amine. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译： 本发明涉及可溶于烃溶剂的阴离子聚合引发剂。 引发剂包括具有通式ALi的锂胺。 组分A是二烷基或二环烷基胺基或环胺。 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。
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40.发明授权
公开(公告)号：US4123503A
公开(公告)日：1978-10-31
申请号：US771221
申请日：1977-03-23
IPC分类号： C01B21/097 , C01B21/098 , C01B25/10
CPC分类号： C01B21/0986 , C01B21/097
摘要： Thermal polymerization of (NPCl.sub.2).sub.3,4 is improved by conducting the polymerization in the presence of Lewis Acid type compounds of Al or B.
摘要翻译： （NPCl2）3,4的热聚合通过在路易斯酸型Al或B的化合物存在下进行聚合而得到改善。
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