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公开(公告)号：US5616704A
公开(公告)日：1997-04-01
申请号：US639980
申请日：1996-04-29
CPC分类号： C08F4/086 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08F36/04 , Y10S152/905
摘要： The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL).sub.y. SOL is a solubilizing component and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y is from about 1 to 4. The cyclic amine has an alkylene, oxy- or amino-alkylene group having from about 3 to about 16 methylene groups. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译： 本发明涉及可溶于无环烷烃溶剂的阴离子聚合引发剂。 引发剂包括具有通式（A）Li（SOL）y的溶解的锂胺。 SOL是增溶组分，A是烷基，二烷基或环烷基胺基或环状胺，y约为1-4。环状胺具有约3至约16的亚烷基，氧基或氨基亚烷基 亚甲基。 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。
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公开(公告)号：US6025450A
公开(公告)日：2000-02-15
申请号：US112913
申请日：1998-07-09
申请人： David F. Lawson , Mark L. Stayer, Jr. , David Saffles , Koichi Morita , Yoichi Ozawa , Ryota Fujio , Thomas A. Antkowiak
发明人： David F. Lawson , Mark L. Stayer, Jr. , David Saffles , Koichi Morita , Yoichi Ozawa , Ryota Fujio , Thomas A. Antkowiak
CPC分类号： C08C19/44 , B60C1/00 , B60C1/0016 , B60C1/0025 , B60C15/06 , C08F36/04 , Y10S152/905
摘要： A functionalized polymer includes a polymer chain carrying at least one functional group selected from alkyl, dialkyl and cycloalkyl amine radicals having the general formula ##STR1## and cyclic amine radicals having the general formula ##STR2## where R.sub.1 is an alkyl, cycloalkyl or aralkyl having from 1 to about 12 carbon atoms, and R.sub.2 is an alkylene, substituted alkylene, oxy- or N-alkylamino-alkylene group having from about 3 to about 16 methylene groups. The invention also provides products based upon such polymers.
摘要翻译： 官能化聚合物包括携带至少一种选自具有通式的烷基，二烷基和环烷基胺基的官能团的聚合物链和具有以下通式的环胺基：其中R1是具有1至约12个碳原子的烷基，环烷基或芳烷基 原子，并且R 2是具有约3至约16个亚甲基的亚烷基，取代的亚烷基，氧基或N-烷基氨基 - 亚烷基。 本发明还提供了基于这样的聚合物的产品。
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3.发明授权Functionalized polymer and rubber compositions produced from solubilized anionic polymerization initiators 失效由溶解的阴离子聚合引发剂制备的官能化聚合物和橡胶组合物
公开(公告)号：US5552473A
公开(公告)日：1996-09-03
申请号：US469389
申请日：1995-06-05
CPC分类号： C08F4/086 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08F36/04 , Y10S152/905
摘要： The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL).sub.y. SOL is a solubilizing component and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y is from about 1 to 4. The cyclic amine has an alkylene, oxy- or amino-alkylene group having from about 3 to about 16 methylene groups. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer wtih a multifunctionality.
摘要翻译： 本发明涉及可溶于无环烷烃溶剂的阴离子聚合引发剂。 引发剂包括具有通式（A）Li（SOL）y的溶解的锂胺。 SOL是增溶组分，A是烷基，二烷基或环烷基胺基或环状胺，y约为1-4。环状胺具有约3至约16的亚烷基，氧基或氨基亚烷基 亚甲基。 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以提供聚合物多功能性。
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公开(公告)号：US5332810A
公开(公告)日：1994-07-26
申请号：US955969
申请日：1992-10-02
IPC分类号： C07F1/02 , B60C1/00 , C08C19/44 , C08F4/00 , C08F4/08 , C08F4/42 , C08F4/48 , C08F36/04 , C08K3/04 , C08L9/00 , C08L21/00 , C07D295/02
CPC分类号： C08F4/086 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08F36/04
摘要： The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL).sub.y. SOL is a solubilizing component and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y is from about 1 to 4. The invention is also directed toward polymers and other products made using the initiator, and methods therefore. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译： 本发明涉及可溶于无环烷烃溶剂的阴离子聚合引发剂。 引发剂包括具有通式（A）Li（SOL）y的溶解的锂胺。 SOL是增溶组分，A是烷基，二烷基或环烷基胺基或环胺，y约为1-4。本发明还涉及使用引发剂制备的聚合物和其它产物，因此也涉及方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。
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5.发明授权
公开(公告)号：US6080835A
公开(公告)日：2000-06-27
申请号：US936364
申请日：1997-09-24
申请人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
发明人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
CPC分类号： B60C1/0016 , B60C1/00 , B60C1/0025 , B60C15/06 , C08C19/44 , C08F36/04 , C08F4/48 , Y10T152/10
摘要： A functionialized polymer according to the invention includes a polymer molecule having the general formula AYLi where A is a cyclic amine-containing radical having the general formula ##STR1## wherein R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and Y is a divalent polymer radical and Li is a lithium atom bonded to a carbon atom of Y.
摘要翻译： 根据本发明的官能化聚合物包括具有通式AYLi的聚合物分子，其中A是具有通式的含环胺基团，其中R 1是二价亚烷基，氧基或氨基亚烷基或具有6个 至约20个碳原子; R2是具有约2-约20个碳原子的直链，支链或环 - 亚烷基; Y是二价聚合物基团，Li是与Y的碳原子键合的锂原子。
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6.发明授权
公开(公告)号：US5610237A
公开(公告)日：1997-03-11
申请号：US658242
申请日：1996-06-04
申请人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
发明人： David F. Lawson , Thomas A. Antkowiak , James E. Hall , Mark L. Stayer, Jr. , John R. Schreffler
IPC分类号： B60C1/00 , C08C19/44 , C08F2/04 , C08F2/06 , C08F4/42 , C08F4/48 , C08F36/04 , C08K3/04 , C08L19/00 , C08L101/00 , C08L101/02 , C08F293/00
CPC分类号： C08F4/48 , B60C1/00 , B60C1/0016 , B60C1/0025 , C08C19/44 , C08F36/04 , Y10T152/10
摘要： A functionalized polymer according to the invention includes a polymer molecule having the general formula AYLi where A is a cyclic amine-containing radical having the general formula ##STR1## wherein R.sub.1 is a divalent alkylene, an oxy- or amino-alkylene, or substituted alkylene having from 6 to about 20 carbon atoms; R.sub.2 is a linear-, branched-, or cyclo-alkylene having from about 2 to about 20 carbon atoms; and Y is a divalent polymer radical and Li is a lithium atom bonded to a carbon atom of Y.
摘要翻译： 根据本发明的官能化聚合物包括具有通式AYLi的聚合物分子，其中A是具有通式“IMAGE”的含环胺基团，其中R 1是二价亚烷基，氧基或氨基亚烷基或取代的亚烷基 具有6至约20个碳原子; R2是具有约2-约20个碳原子的直链，支链或环 - 亚烷基; Y是二价聚合物基团，Li是与Y的碳原子键合的锂原子。
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7.发明授权Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom 失效含有环状仲胺和共轭二烯的加合物的阴离子聚合引发剂及其产物
公开(公告)号：US5491230A
公开(公告)日：1996-02-13
申请号：US175294
申请日：1993-12-29
IPC分类号： C08F4/08 , C07F1/02 , C08F4/42 , C08F4/46 , C08F4/48 , C08F236/04 , C08F236/10 , C07D225/00
CPC分类号： C07F1/02
摘要： An anionic polymerization initiator includes a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A method of preparing an anionic polymerization initiator includes reacting an excess of a cyclic secondary amine with a conjugated diene to form an adduct; and, reacting the adduct with an organolithium compound. A method of preparing a polymer includes forming a solution of one or more anionically polymerizable monomers in a hydrocarbon solvent; and, polymerizing the monomer with an anionic polymerization initiator comprising a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A functionalized polymer includes the termination product of a living polymer having the general formula AYLi, wherein A is a functional group derived from an anionic polymerization initiator; and, Y is a divalent polymer radical; wherein the anionic polymerization initiator is a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene.
摘要翻译： 阴离子聚合引发剂包括环状仲胺与共轭二烯的加合物的碳 - 硫酸盐。 制备阴离子聚合引发剂的方法包括使过量的环状仲胺与共轭二烯反应形成加合物; 并使加合物与有机锂化合物反应。 制备聚合物的方法包括在烃溶剂中形成一种或多种阴离子聚合单体的溶液; 并且用包含环状仲胺加成物的碳 - 硫醇盐与共轭二烯的阴离子聚合引发剂聚合单体。 官能化聚合物包括具有通式AYLi的活性聚合物的终止产物，其中A是衍生自阴离子聚合引发剂的官能团; Y为二价聚合物基团; 其中所述阴离子聚合引发剂是环状仲胺与共轭二烯的加合物的碳 - 锂盐。
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8.发明授权Allyl-and xylyl-amine containing elastomers and products having reduced hysteresis 失效含烯丙基和二甲苯胺的弹性体和具有降低滞后的产物
公开(公告)号：US5536801A
公开(公告)日：1996-07-16
申请号：US469128
申请日：1995-06-06
申请人： Thomas A. Antkowiak , James E. Hall , David F. Lawson , John R. Schreffler , Mark L. Stayer, Jr.
发明人： Thomas A. Antkowiak , James E. Hall , David F. Lawson , John R. Schreffler , Mark L. Stayer, Jr.
IPC分类号： B60C1/00 , C08C19/44 , C08F4/08 , C08F4/42 , C08F4/48 , C08F8/00 , C08F10/00 , C08F10/08 , C08F10/14 , C08F12/00 , C08F12/04 , C08F36/04 , C08K3/00 , C08K3/02 , C08K3/04 , C08L3/04 , C08L15/00 , C08L23/18 , C08L25/04 , C08L101/00
CPC分类号： C08F12/04 , C08C19/44 , C08F36/04 , Y02T10/862 , Y10T152/10495
摘要： An anionic polymerization initiator includes the C-lithio reaction product of an organolithium compound and a tertiary-amino allyllithium or a tertiary-amino xylyllithium. When used in an anionic polymerization, a functional group from the initiator is incorporated onto the head of the growing polymer and a lithium atom is incorporated at the "living" end of the polymer chain prior to quenching. The initiator may be used to polymerize a monomer(s) including diolefin monomers, monovinyl aromatic monomers and trienes, and the living ends of the polymers are effectively maintained even at temperatures of up to 300.degree. F. and higher. Such polymers exhibit an increased efficiency in coupling termination reactions, and products prepared from such polymers exhibit improved hysteresis characteristics. Products such as tires and the like can be prepared from such polymers and from vulcanizable elastomer compositions employing the polymers.
摘要翻译： 阴离子聚合引发剂包括有机锂化合物和叔氨基烯丙基锂或叔氨基二羟基锂的C - 锂反应产物。 当用于阴离子聚合时，将来自引发剂的官能团引入生长的聚合物的头部上，并且在淬火之前将锂原子并入聚合物链的“活性”端。 引发剂可以用于聚合包含二烯烃单体，单乙烯基芳族单体和三烯的单体，并且甚至在高达300°F或更高的温度下也能有效地保持聚合物的活性末端。 这种聚合物表现出增加的偶联终止反应的效率，并且由这种聚合物制备的产物表现出改善的滞后特性。 诸如轮胎等的产品可以由这样的聚合物和使用聚合物的可硫化的弹性体组合物制备。
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9.发明授权Method of preparing polymer using allyl-and xylyl-amine containing initiators 失效使用烯丙基 - 和二甲苯胺的起始剂制备聚合物的方法
公开(公告)号：US5502131A
公开(公告)日：1996-03-26
申请号：US469150
申请日：1995-06-06
申请人： Thomas A. Antkowiak , James E. Hall , David F. Lawson , John R. Schreffler , Mark L. Stayer, Jr.
发明人： Thomas A. Antkowiak , James E. Hall , David F. Lawson , John R. Schreffler , Mark L. Stayer, Jr.
IPC分类号： B60C1/00 , C08C19/44 , C08F4/08 , C08F4/42 , C08F4/48 , C08F8/00 , C08F10/00 , C08F10/08 , C08F10/14 , C08F12/00 , C08F12/04 , C08F36/04 , C08K3/00 , C08K3/02 , C08K3/04 , C08L3/04 , C08L15/00 , C08L23/18 , C08L25/04 , C08L101/00 , C08F36/02 , C08F36/22
CPC分类号： C08F12/04 , C08C19/44 , C08F36/04 , Y02T10/862 , Y10T152/10495
摘要： An anionic polymerization initiator includes the C-lithio reaction product of an organolithium compound and a tertiary-amino allyllithium or a tertiary-amino xylyllithium. When used in an anionic polymerization, a functional group from the initiator is incorporated onto the head of the growing polymer and a lithium atom is incorporated at the "living" end of the polymer chain prior to quenching. The initiator may be used to polymerize a monomer(s) including diolefin monomers, monovinyl aromatic monomers and trienes, and the living ends of the polymers are effectively maintained even at temperatures of up to 300.degree. F. and higher. Such polymers exhibit an increased efficiency in coupling termination reactions, and products prepared from such polymers exhibit improved hysteresis characteristics. Products such as tires and the like can be prepared from such polymers and from vulcanizable elastomer compositions employing the polymers.
摘要翻译： 阴离子聚合引发剂包括有机锂化合物和叔氨基烯丙基锂或叔氨基二羟基锂的C - 锂反应产物。 当用于阴离子聚合时，将来自引发剂的官能团引入生长的聚合物的头部上，并且在淬火之前将锂原子并入聚合物链的“活性”端。 引发剂可以用于聚合包含二烯烃单体，单乙烯基芳族单体和三烯的单体，并且甚至在高达300°F或更高的温度下也有效地保持聚合物的活性末端。 这种聚合物表现出增加的偶联终止反应的效率，并且由这种聚合物制备的产物表现出改善的滞后特性。 诸如轮胎等的产品可以由这样的聚合物和使用聚合物的可硫化的弹性体组合物制备。
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公开(公告)号：US5268413A
公开(公告)日：1993-12-07
申请号：US791910
申请日：1991-11-13
摘要： An anionic polymerization initiator comprising the reaction product of a functionalizing agent selected from the group consisting of substituted aldimines, ketimines and secondary amines and, an organolithium compound. Elastomeric polymers prepared with these initiators have functional sites incorporated at the initiator end of the polymer chain and provide vulcanizable rubber compounds exhibiting reduced hysteresis. Articles such as tires, produced with low hysteresis elastomeric polymers have lower rolling resistance. Methods are also provided for preparing the initiators, functionalized polymers and vulcanizable elastomeric compounds having reduced hysteresis.
摘要翻译： 一种阴离子聚合引发剂，其包含选自取代的醛亚胺，酮亚胺和仲胺的官能化试剂的反应产物和有机锂化合物。 用这些引发剂制备的弹性体聚合物具有并入聚合物链的引发剂末端的功能性位点，并提供具有降低的滞后性的可硫化橡胶化合物。 用低滞后弹性体聚合物制成的轮胎等制品具有较低的滚动阻力。 还提供了用于制备具有降低的滞后的引发剂，官能化聚合物和可硫化弹性体化合物的方法。
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