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公开(公告)号：US07446232B2
公开(公告)日：2008-11-04
申请号：US11827952
申请日：2007-07-13
Applicant: Jihad Mohammed Dakka , Doron Levin , John Scott Buchanan , Jon Edmond Randolph Stanat
Inventor： Jihad Mohammed Dakka , Doron Levin , John Scott Buchanan , Jon Edmond Randolph Stanat
IPC: C07C409/02 , C07C37/68
CPC classification number: C07C409/08 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/10 , C07C49/04 , C07C49/403 , C07C39/04
Abstract: In a process for oxidizing alkylaromatic compounds to the corresponding hydroperoxide, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, with oxygen in the presence of an added catalyst comprising tert-butyl hydroperoxide and in the absence of any other catalyst, to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I). The hydroperoxide may then be converted into a phenol and a ketone of the general formula R1COCH2R2 (III), in which R1 and R2 have the same meaning as in formula (I).
Abstract translation: 在将烷基芳族化合物氧化成相应的氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示具有 如果R 1和R 2可以连接形成具有4至10个碳原子的环状基团，则所述环状基团任选被取代 R 3表示氢，一个或多个具有1至4个碳原子的烷基或环己基，在含有叔丁基过氧化氢的加成催化剂存在下，在不存在 任何其它催化剂，以制备通式（II）的氢过氧化物：其中R 1，R 2和R 3 3具有相同的含义 如式（I）所示。 然后将氢过氧化物转化成通式为R 1，R 2，R 2，（III）的苯酚和酮，其中R ＆lt; SUP＆gt;和＆lt; 2＆gt;具有与式（I）中相同的含义。
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32.发明授权Molecular sieve compositions, catalyst thereof, their making and use in conversion processes 有权分子筛组合物，其催化剂，其制备和在转化过程中的应用公开(公告)号：US07307196B2
公开(公告)日：2007-12-11
申请号：US10910739
申请日：2004-08-03
Applicant: Doron Levin , James Clark Vartuli
Inventor： Doron Levin , James Clark Vartuli
CPC classification number: C07C1/20 , B01J21/10 , B01J23/10 , B01J29/85 , B01J35/0006 , C07C2521/06 , C07C2529/83 , C07C2529/85 , Y02P30/42 , C07C11/02
Abstract: The invention relates to a catalyst composition, a method of making the same and its use in the conversion of a feedstock, preferably an oxygenated feedstock, into one or more olefin(s), preferably ethylene and/or propylene The catalyst composition comprises a molecular sieve and at least one oxide of a metal from Group 4, optionally in combination with at least one metal from Groups 2 and 3, of the Periodic Table of Elements.
Abstract translation: 本发明涉及一种催化剂组合物，其制备方法及其在将原料，优选氧化原料转化为一种或多种烯烃，优选乙烯和/或丙烯中的用途。催化剂组合物包含分子 筛和至少一种来自组4的金属的氧化物，任选地与元素周期表中的至少一种第2和3族的金属组合。
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公开(公告)号：US07282192B2
公开(公告)日：2007-10-16
申请号：US11644619
申请日：2006-12-22
Applicant: James Clarke Vartuli , Jeffrey T. Elks , El-Mekki El-Malki , William G. Borghard , Doron Levin , Stephen John McCarthy
Inventor： James Clarke Vartuli , Jeffrey T. Elks , El-Mekki El-Malki , William G. Borghard , Doron Levin , Stephen John McCarthy
CPC classification number: B01J23/002 , B01J23/10 , B01J27/053 , B01J35/002 , B01J2523/00 , C07C1/20 , C07C29/10 , C07C11/02 , B01J2523/3712 , B01J2523/48 , B01J2523/62 , C07C31/10
Abstract: The invention relates to a composition of matter comprising at least one metal from Group 3, at least one metal from Group 4, sulfur and oxygen, particularly useful as a catalyst for ether decomposition to alkanols and alkenes.
Abstract translation: 本发明涉及包含至少一种第3族金属，至少一种第4族金属，硫和氧的物质组合物，特别可用作乙醚分解成链烷醇和烯烃的催化剂。
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34.发明申请Molecular sieve compositions, catalyst thereof, their making and use in conversion processes 有权分子筛组合物，其催化剂，其制备和在转化过程中的应用公开(公告)号：US20070161840A1
公开(公告)日：2007-07-12
申请号：US11713873
申请日：2007-03-05
Applicant: Teng Xu , Stephen Vaughn , Richard Hall , Doron Levin , James Vartuli
Inventor： Teng Xu , Stephen Vaughn , Richard Hall , Doron Levin , James Vartuli
IPC: C07C1/00
CPC classification number: B01J37/0009 , B01J21/06 , B01J21/10 , B01J23/10 , B01J29/85 , B01J35/0006 , B01J35/023 , B01J35/10 , B01J2229/42 , C07C1/20 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2521/16 , C07C2523/10 , C07C2529/83 , C07C2529/85 , Y02P30/42 , C07C11/02
Abstract: The invention relates to a catalyst composition, a method of making the same and its use in the conversion of a feedstock, preferably an oxygenated feedstock, into one or more olefin(s), preferably ethylene and/or propylene The catalyst composition comprises a molecular sieve and at least one metal oxide, such as a magnesium oxide that, when saturated with acetone and contacted with said acetone for 1 hour at 25° C., converts more than 80% of the acetone.
Abstract translation: 本发明涉及一种催化剂组合物，其制备方法及其在将原料，优选氧化原料转化为一种或多种烯烃，优选乙烯和/或丙烯中的用途。催化剂组合物包含分子 筛和至少一种金属氧化物，例如氧化镁，当用丙酮饱和并与所述丙酮在25℃下接触1小时时，其转化超过80％的丙酮。
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35.发明授权公开(公告)号：US07208442B2
公开(公告)日：2007-04-24
申请号：US10364172
申请日：2003-02-10
Applicant: Teng Xu , Stephen N. Vaughn , Richard B. Hall , Doron Levin , James Clark Vartuli
Inventor： Teng Xu , Stephen N. Vaughn , Richard B. Hall , Doron Levin , James Clark Vartuli
IPC: B01J29/06
CPC classification number: B01J37/0009 , B01J21/06 , B01J21/10 , B01J23/10 , B01J29/85 , B01J35/0006 , B01J35/023 , B01J35/10 , B01J2229/42 , C07C1/20 , C07C2521/04 , C07C2521/06 , C07C2521/10 , C07C2521/16 , C07C2523/10 , C07C2529/83 , C07C2529/85 , Y02P30/42 , C07C11/02
Abstract: The invention relates to a catalyst composition, a method of making the same and its use in the conversion of a feedstock, preferably an oxygenated feedstock, into one or more olefin(s), preferably ethylene and/or propylene The catalyst composition comprises a molecular sieve and at least one metal oxide, such as a magnesium oxide that, when saturated with acetone and contacted with said acetone for 1 hour at 25° C., converts more than 80% of the acetone.
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Patent Agency Ranking
36.发明授权公开(公告)号：US07199277B2
公开(公告)日：2007-04-03
申请号：US10883438
申请日：2004-07-01
Applicant: Teng Xu , Nicolas P. Coute , Kenneth R. Clem , Doron Levin , James C. Vartuli
Inventor： Teng Xu , Nicolas P. Coute , Kenneth R. Clem , Doron Levin , James C. Vartuli
IPC: C07C1/00 , B01J27/182 , B01J21/00
CPC classification number: C07C1/20 , C07C2529/85 , C10G3/48 , C10G3/49 , C10G3/62 , C10G2300/1088 , C10G2300/703 , C10G2400/20 , Y02P30/42 , C07C11/02
Abstract: This invention relates to processes for converting oxygenates to olefins that include a step of pretreating catalyst, which comprises molecular sieve and one or more active metal oxides of one or more metals, with a hydrocarbon composition to provide an integrated hydrocarbon co-catalyst within the molecular sieve. The combination of molecular sieve and hydrocarbon co-catalyst converts oxygenate to an olefin product with high selectivity to light olefins (i.e., ethylene or propylene, or mixture thereof).
Abstract translation: 本发明涉及将含氧化合物转化为烯烃的方法，包括将包含分子筛和一种或多种金属的一种或多种活性金属氧化物的催化剂预处理成烃类组合物以在分子内提供整合的烃助催化剂的步骤 筛。 分子筛和烃助催化剂的组合将含氧化合物转化为对轻质烯烃（即乙烯或丙烯或其混合物）具有高选择性的烯烃产物。
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公开(公告)号：US07102037B2
公开(公告)日：2006-09-05
申请号：US11013482
申请日：2004-12-16
Applicant: Doron Levin , Shifang Luo , James Clarke Vartuli , Charles Morris Yarbrough , Dane Clark Grenoble
Inventor： Doron Levin , Shifang Luo , James Clarke Vartuli , Charles Morris Yarbrough , Dane Clark Grenoble
IPC: C07C33/02
CPC classification number: B01J21/066 , B01J23/002 , B01J23/10 , B01J23/24 , B01J23/30 , B01J23/88 , B01J37/03 , B01J2523/00 , C07C1/20 , C07C29/10 , C07C2521/06 , C07C2523/10 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/72 , C07C2523/745 , C07C2527/053 , Y02P20/52 , C07C11/02 , B01J2523/3712 , B01J2523/48 , B01J2523/69 , B01J2523/842 , C07C11/09 , C07C11/06 , C07C31/10 , C07C31/12 , C07C31/04
Abstract: A process for selectively converting a dialkyl ether to the corresponding alkene and alkanol comprises contacting a feed containing at least one dialkyl ether with a catalyst comprising a mixed metal oxide which comprises at least one metal selected from Group 4 of the Periodic Table of Elements and at least one metal selected from Group 3 (including the Lanthanides and Actinides) and Group 6 of the Periodic Table of Elements.
Abstract translation: 选择性地将二烷基醚转化为相应的烯烃和链烷醇的方法包括将含有至少一种二烷基醚的进料与包含混合金属氧化物的催化剂接触，所述混合金属氧化物包含至少一种选自元素周期表第4族的金属和 选自第3族（包括镧系元素和锕系元素）中的至少一种金属和元素周期表第6族。
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公开(公告)号：US20060025644A1
公开(公告)日：2006-02-02
申请号：US10903717
申请日：2004-07-30
Applicant: Shun Fung , Doron Levin , Jose Santiesteban , Nicolas Coute
Inventor： Shun Fung , Doron Levin , Jose Santiesteban , Nicolas Coute
IPC: C07C1/00
CPC classification number: C10G3/62 , C10G3/42 , C10G3/48 , C10G3/49 , C10G3/55 , C10G2300/708 , C10G2400/20 , Y02P30/20 , Y02P30/40 , Y02P30/42
Abstract: A process is described for converting an oxygenate-containing feedstock into one or more olefins in a moving bed reactor system operating in countercurrent flow using a catalyst composition comprising a molecular sieve and at least one metal oxide having an uptake of carbon dioxide at 100° C. of at least 0.03 mg/m2 of the metal oxide.
Abstract translation: 描述了一种用于使用包含分子筛和至少一种在100℃摄入二氧化碳的金属氧化物的催化剂组合物将逆境流反应器中的含氧化合物原料转化为一种或多种烯烃的方法 至少为0.03mg / m 2的金属氧化物。
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公开(公告)号：US20050177009A1
公开(公告)日：2005-08-11
申请号：US11013482
申请日：2004-12-16
Applicant: Doron Levin , Shifang Luo , James Vartuli , Charles Yarbrough , Dane Grenoble
Inventor： Doron Levin , Shifang Luo , James Vartuli , Charles Yarbrough , Dane Grenoble
IPC: B01J21/06 , B01J23/00 , B01J23/10 , B01J23/24 , B01J23/30 , B01J23/88 , B01J37/03 , C07C1/20 , C07C29/10
CPC classification number: B01J21/066 , B01J23/002 , B01J23/10 , B01J23/24 , B01J23/30 , B01J23/88 , B01J37/03 , B01J2523/00 , C07C1/20 , C07C29/10 , C07C2521/06 , C07C2523/10 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/72 , C07C2523/745 , C07C2527/053 , Y02P20/52 , C07C11/02 , B01J2523/3712 , B01J2523/48 , B01J2523/69 , B01J2523/842 , C07C11/09 , C07C11/06 , C07C31/10 , C07C31/12 , C07C31/04
Abstract: A process for selectively converting a dialkyl ether to the corresponding alkene and alkanol comprises contacting a feed containing at least one dialkyl ether with a catalyst comprising a mixed metal oxide which comprises at least one metal selected from Group 4 of the Periodic Table of Elements and at least one metal selected from Group 3 (including the Lanthanides and Actinides) and Group 6 of the Periodic Table of Elements.
Abstract translation: 选择性地将二烷基醚转化为相应的烯烃和链烷醇的方法包括将含有至少一种二烷基醚的进料与包含混合金属氧化物的催化剂接触，所述混合金属氧化物包含至少一种选自元素周期表第4族的金属和 选自第3族（包括镧系元素和锕系元素）中的至少一种金属和元素周期表第6族。
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40.发明授权Molecular sieve compositions, catalyst thereof, their making and use in conversion processes 有权分子筛组合物，其催化剂，其制备和在转化过程中的应用公开(公告)号：US06844291B2
公开(公告)日：2005-01-18
申请号：US10364156
申请日：2003-02-10
Applicant: Doron Levin , James Clark Vartuli
Inventor： Doron Levin , James Clark Vartuli
IPC: B01J21/06 , B01J21/10 , B01J23/10 , B01J29/85 , B01J35/00 , B01J35/10 , B01J37/00 , C07C1/20 , B01J27/12
CPC classification number: B01J37/0009 , B01J21/06 , B01J21/066 , B01J21/10 , B01J23/10 , B01J29/85 , B01J35/0006 , B01J35/10 , B01J2229/42 , C07C1/20 , C07C2521/06 , C07C2521/10 , C07C2529/83 , C07C2529/85 , Y02P30/42 , C07C11/02
Abstract: The invention relates to a catalyst composition, a method of making the same and its use in the conversion of a feedstock, preferably an oxygenated feedstock, into one or more olefin(s), preferably ethylene and/or propylene. The catalyst composition comprises a molecular sieve and at least one oxide of a metal from Group 4, optionally in combination with at least one metal from Groups 2 and 3, of the Periodic Table of Elements.
Abstract translation: 本发明涉及一种催化剂组合物，其制备方法及其用于将原料，优选氧化原料转化为一种或多种烯烃，优选乙烯和/或丙烯的方法。 催化剂组合物包含分子筛和至少一种第4族金属的氧化物，任选与元素周期表第2和3族的至少一种金属组合。
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