公开(公告)号：US4818509A

公开(公告)日：1989-04-04

申请号：US921704

申请日：1986-10-21

申请人： Francis G. Dwyer ,  Albert B. Schwartz

发明人： Francis G. Dwyer ,  Albert B. Schwartz

IPC分类号： C01B39/02 ,  C01B33/28

CPC分类号： C01B39/02

摘要： A continuous process is described for manufacturing a wide variety of zeolites having selected crystal sizes and other desired characteristics. Selected raw materials are fed to a precursor tank of relatively large capacity, wherein the resultant zeolite precursor slurry is held at temperatures of up to 180.degree. F. for 4-16 hours, with high shear agitation, as an induction period. The slurry is sent to a plurality of crystallization tanks before it possesses a total solids content exceeding 10% by weight and a crystalline content exceeding 15% by weight of the total solids content. The crystallization tanks are preferably operated in two stages. The first crystallizing stage is held at a temperature of 180.degree.-250.degree. F. for 2-72 hours. The second crystallizing stage is held at a temperature greater than 250.degree. F. for 2-16 hours.

摘要翻译： 描述了用于制造具有选定的晶体尺寸和其它期望特性的多种沸石的连续方法。 将选择的原料进料到相对大容量的前体罐中，其中所得沸石前体浆料在高剪切搅拌下作为诱导期保持在高达180°F的温度下4-16小时。 在其具有超过10重量％的总固体含量和超过总固体含量的15重量％的结晶含量之前，将浆料送至多个结晶槽。 结晶槽优选在两个阶段中操作。 第一结晶阶段在180-250°F的温度下保持2-72小时。 第二结晶阶段在大于250°F的温度下保持2-16小时。

公开(公告)号：US4556477A

公开(公告)日：1985-12-03

申请号：US662660

申请日：1984-10-19

申请人： Francis G. Dwyer

发明人： Francis G. Dwyer

IPC分类号： B01J29/70 ,  C10G45/64 ,  C10G47/16

CPC分类号： B01J29/7042 ,  C10G45/64

摘要： A new zeolite, designated ZSM-22, is disclosed and claimed. The new zeolite has the composition, in the anhydrous state, expressed in terms of mole ratios of oxides as follows:(x)Q.sub.2 O:(y)M.sub.2/n O:(z)L.sub.2 O.sub.3 :100SiO.sub.2wherein Q.sub.2 O is the oxide form of an organic compound containing an element of Group 5-B (as defined in the Table of the Elements--National Bureau of Standards, Fischer Scientific Co. Catalog No. 5-702-10), e.g., N or P, preferably N, containing at least one alkyl or aryl group having at least 2 carbon atoms, M is an alkali or alkaline earth metal having a valence n, e.g., Na, K, Cs or Li and wherein x=0.01-2.0, y=0-2.0, z=0-5, and L=Al. The new zeolite, ZSM-22, can be used in catalytic dewaxing of petroleum stocks in the presence or absence of added hydrogen.

摘要翻译： 公开并要求保护名为ZSM-22的新型沸石。 新型沸石的组成为无水状态，以氧化物的摩尔比表示如下：（x）Q2O：（y）M2 / nO：（z）L2O3：100SiO2其中Q2O是有机物的氧化物形式 含有5-B族元素的化合物（如元素 - 国家标准局表，Fischer Scientific Co.目录号5-702-10中所定义），例如N或P，优选N，至少含有 一个具有至少2个碳原子的烷基或芳基，M是价数n的碱金属或碱土金属，例如Na，K，Cs或Li，其中x = 0.01-2.0，y = 0-2.0，z = 0-5，L = Al。 新型沸石ZSM-22可用于在存在或不加入氢气的情况下对石油储备物进行催化脱蜡。

公开(公告)号：US4463101A

公开(公告)日：1984-07-31

申请号：US444260

申请日：1982-11-24

申请人： Francis G. Dwyer ,  William E. Garwood

发明人： Francis G. Dwyer ,  William E. Garwood

IPC分类号： B01J29/40 ,  C07C1/04 ,  B01J29/28 ,  B01J29/30

CPC分类号： C07C1/04 ,  B01J29/40 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2529/072

摘要： An improved catalyst composition is disclosed for converting synthesis gas to hydrocarbon mixtures. The catalyst comprises an iron-containing, Fischer-Tropsch catalyst and a crystalline zeolite having a silica-to-alumina ratio of greater than 200 (including zeolites containing essentially no alumina) and an (R.sub.2 O+M.sub.2 /.sub.n O):SiO.sub.2 rate of less than 1.1:1 where M is a metal other than a metal of Group IIIA, n is the valence of said metal, and R is an alkyl ammonium radical, said organosilicate being characterized by a specified X-ray diffraction pattern.

摘要翻译： 公开了一种改进的催化剂组合物，用于将合成气转化为烃混合物。 催化剂包含含铁的费 - 托催化剂和二氧化硅与氧化铝之比大于200的结晶沸石（包括基本上不含氧化铝的沸石）和（R2O + M2 / nO）：SiO 2的比例较小 超过1.1:1，其中M是不同于IIIA族金属的金属，n是所述金属的化合价，R是烷基铵基团，所述有机硅酸盐的特征在于规定的X射线衍射图。

公开(公告)号：US4441991A

公开(公告)日：1984-04-10

申请号：US435424

申请日：1982-10-20

申请人： Francis G. Dwyer ,  William E. Garwood

发明人： Francis G. Dwyer ,  William E. Garwood

IPC分类号： C10G45/64 ,  C10G47/16

CPC分类号： C10G45/64 ,  C10G2400/02

摘要： Straight-chain hydrocarbons and slightly branched chain hydrocarbons are selectively converted utilizing highly siliceous porous crystalline materials of the zeolite type having SiO.sub.2 /Al.sub.2 O.sub.3 ratio of greater than 200, unique molecular sieving properties and superior resistance to ammonia deactivation. The catalyst preferably contains acidic cations and can also contain a component having a hydrogenation/dehydrogenation function. The process of this invention is particularly useful for the dewaxing of hydrocarbon oils, including removal of high freezing point paraffins from jet fuel to lower freezing point, as well as improving the octane rating of naphtha fractions.

摘要翻译： 使用SiO 2 / Al 2 O 3比例大于200的沸石型高度硅质多孔结晶材料，独特的分子筛分性质和优异的氨失活性，可以选择性地转化直链烃和轻支链烃。 催化剂优选含有酸性阳离子，并且还可以含有具有氢化/脱氢功能的组分。 本发明的方法特别适用于烃油的脱蜡，包括从喷气燃料中除去高凝固点石蜡至较低的凝固点，以及提高石脑油馏分的辛烷值。

公开(公告)号：US4401572A

公开(公告)日：1983-08-30

申请号：US274971

申请日：1981-06-18

申请人： Pochen Chu ,  Francis G. Dwyer

发明人： Pochen Chu ,  Francis G. Dwyer

IPC分类号： B01D15/00 ,  B01D53/02 ,  C02F1/28 ,  B01D15/04

CPC分类号： B01D15/00 ,  B01D53/02 ,  C02F1/281

摘要： A method for selectively sorbing Group V-B element hydrides and derivatives thereof from an aqueous solution containing same which comprises contacting said solution under ion-exchange conditions with a crystalline zeolite material having a pore dimension greater than about 5 Angstroms, a Constraint Index between 1 and 12 and a SiO.sub.2 /Al.sub.2 O.sub.3 mole ratio greater than 12.

摘要翻译： 从含有它的水溶液中选择性吸附VB族元素氢化物及其衍生物的方法，其包括在离子交换条件下使所述溶液与孔尺寸大于约5埃的结晶沸石材料接触，约束指数为1至12 和SiO 2 / Al 2 O 3摩尔比大于12。

公开(公告)号：US4347397A

公开(公告)日：1982-08-31

申请号：US257693

申请日：1981-04-27

申请人： Francis G. Dwyer ,  Albin Huss, Jr.

发明人： Francis G. Dwyer ,  Albin Huss, Jr.

IPC分类号： C10G3/00 ,  C07C5/22

CPC分类号： C10G3/49 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2400/02 ,  Y02P30/20

摘要： A novel process for the reduction of durene produced in a methanol to gasoline conversion process is disclosed wherein either the total effluent from said process or a bottoms fraction containing durene is contacted with an isomerization catalyst at elevated temperatures in order to convert said durene.

摘要翻译： 公开了一种用于还原在甲醇至汽油转化方法中生产的杜烯的新方法，其中将所述方法的总流出物或含有杜烯的塔底馏分与升高的温度下的异构化催化剂接触以转化所述杜烯。

公开(公告)号：US4335020A

公开(公告)日：1982-06-15

申请号：US222848

申请日：1981-01-06

申请人： Pochen Chu ,  Francis G. Dwyer ,  Albin Huss

发明人： Pochen Chu ,  Francis G. Dwyer ,  Albin Huss

IPC分类号： C07C1/20 ,  B01J29/00 ,  B01J29/06 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J37/06 ,  C01B39/04 ,  C01B39/36 ,  C01B39/38 ,  C01B39/42 ,  C01B39/44 ,  C07B61/00 ,  C07C1/00 ,  C07C67/00 ,  B01J29/28

CPC分类号： B01J37/06 ,  B01J29/40 ,  B01J2229/26 ,  B01J2229/42 ,  B01J29/65 ,  B01J29/70

摘要： A method of removing the organic cation from an organic cation-containing zeolite which comprises contacting the zeolite at low temperatures with an aqueous solution of a compound of a class of chemical treating agents that will improve the dispersive and catalytic properties of the zeolite.

摘要翻译： 一种从含有机阳离子的沸石中除去有机阳离子的方法，该方法包括使低沸点沸石与一类化学处理剂的化合物的水溶液接触，这些化学处理剂将改善沸石的分​​散性和催化性能。

公开(公告)号：US4258218A

公开(公告)日：1981-03-24

申请号：US6408

申请日：1979-01-25

申请人： Francis G. Dwyer ,  Albert B. Schwartz

发明人： Francis G. Dwyer ,  Albert B. Schwartz

IPC分类号： B01J23/10 ,  B01J29/40 ,  C07C41/09 ,  C07C43/04

CPC分类号： B01J23/10 ,  B01J29/405 ,  C07C41/09 ,  B01J2229/42

摘要： An improved process using a rare earth-containing catalyst is provided. The catalyst comprises a composite of matrix and rare earth or of zeolite, rare earth and matrix, usually alumina. The rare earth can be a single metal or a mixture of rare earth metals. The process involved is the conversion of alcohols or ethers to gasoline boiling range hydrocarbons.

摘要翻译： 提供了使用含稀土催化剂的改进方法。 该催化剂包括基质和稀土或沸石，稀土和基质（通常为氧化铝）的复合物。 稀土可以是单一金属或稀土金属的混合物。 所涉及的方法是将醇或醚转化为汽油沸程烃。