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    Aromatics alkylation process
    2.
    发明授权
    Aromatics alkylation process 失效
    芳烃烷基化方法

    公开(公告)号：US5191135A

    公开(公告)日：1993-03-02

    申请号：US673925

    申请日：1991-03-25

    申请人： Francis G. Dwyer ,  Quang N. Le

    发明人： Francis G. Dwyer ,  Quang N. Le

    IPC分类号： C07C2/66

    CPC分类号： C07C2/66 ,  C07C2529/08 ,  C07C2529/70

    摘要： Long chain alkyl substituted aromatic compounds, particularly alkylated naphthalenes, are produced by the alkylation of aromatics, e.g. naphthalene, with an olefin or other alkylating agent possessing at least 6 carbon atoms, usually 12 to 20 carbon atoms, in the presence of a zeolite alkylation catalyst, preferably a large pore size zeolite such as zeolite Y and in the presence of from about 0.5 to 3.0 weight percent water, preferably 1.0 to 3.0 weight percent. The use of the water co-feed increases the selectivity of the alkylation for the production of long chain mono-alkyl substituted naphthalenes in preference to more highly substituted products and also increases activity and catalyst stability.

    摘要翻译： 长链烷基取代的芳族化合物，特别是烷基化萘，通过芳族化合物的烷基化，例如， 萘与具有至少6个碳原子，通常12-20个碳原子的烯烃或其它烷基化剂在沸石烷基化催化剂，优选大孔沸石如沸石Y的存在下并在约0.5的存在下反应 至3.0重量％的水，优选1.0至3.0重量％。 使用水共进料增加了烷基化用于生产长链单烷基取代萘的选择性，优于更高取代的产物，并且还增加了活性和催化剂的稳定性。

    Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha
    5.
    发明授权
    Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha 失效
    将合成气转化为高辛烷值主要是烯烃石脑油的催化剂

    公开(公告)号：US4361503A

    公开(公告)日：1982-11-30

    申请号：US220923

    申请日：1980-12-29

    申请人： Francis G. Dwyer ,  William E. Garwood

    发明人： Francis G. Dwyer ,  William E. Garwood

    IPC分类号： B01J29/40 ,  B01J29/46 ,  C07C1/04 ,  B01J29/28 ,  B01J29/30

    CPC分类号： C07C1/044 ,  B01J29/40 ,  B01J29/46 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2529/072

    摘要： An improved catalyst composition is disclosed for converting synthesis gas to hydrocarbon mixtures. The catalyst comprises an iron-containing, Fischer-Tropsch catalyst and a crystalline zeolite having a silica-to-alumina ratio of greater than 200 (including zeolites containing essentially no alumina) and an (R.sub.2 O+M.sub.2 /.sub.n O):SiO.sub.2 rate of less than 1.1:1 where M is a metal other than a metal of Group IIIA, n is the valence of said metal, and R is an alkyl ammonium radical, said organosilicate being characterized by a specified x-ray diffraction pattern.

    摘要翻译： 公开了一种改进的催化剂组合物，用于将合成气转化为烃混合物。 催化剂包含含铁的费 - 托催化剂和二氧化硅与氧化铝之比大于200的结晶沸石（包括基本上不含氧化铝的沸石）和（R2O + M2 / nO）：SiO 2的比例较小 超过1.1:1，其中M是不同于IIIA族金属的金属，n是所述金属的化合价，R是烷基铵基团，所述有机硅酸盐的特征在于规定的x射线衍射图。

    Preparation of zeolites
    7.
    发明授权
    Preparation of zeolites 失效
    沸石的制备

    公开(公告)号：US4091007A

    公开(公告)日：1978-05-23

    申请号：US627158

    申请日：1975-10-30

    申请人： Francis G. Dwyer ,  Albert B. Schwartz

    发明人： Francis G. Dwyer ,  Albert B. Schwartz

    IPC分类号： B01J29/40 ,  B01J29/70 ,  C01B39/34 ,  C01B39/40 ,  C07C2/00 ,  C01B33/28 ,  C07F5/06

    CPC分类号： C01B39/40 ,  B01J29/40 ,  B01J29/7011 ,  C01B39/34 ,  C07C2/00 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2529/40 ,  Y10S423/22 ,  Y10S423/26

    摘要： An improved method for preparing a crystalline aluminosilicate zeolite having uniform pores and greater than 40 percent crystallinity which comprises forming a critical reaction mixture containing a source of at least two cations, silica, alumina and water, wherein at least about 70 weight percent of the alumina is provided to the reaction mixture by an alumina-containing clay being added thereto, and maintaining the reaction mixture at a temperature and pressure for a time necessary to crystallize the crystalline aluminosilicate from the reaction mixture. It is desirable to preform said reaction mixture into discrete particles such as pellets or extrudates which retain their shape and acquire substantial strength in the crystallization process.

    摘要翻译： 一种制备具有均匀孔和大于40％结晶度的结晶硅铝酸盐沸石的改进方法，其包括形成含有至少两种阳离子源，二氧化硅，氧化铝和水的临界反应混合物，其中至少约70重量％的氧化铝 通过向其中加入的含氧化铝粘土提供给反应混合物，并将反应混合物保持在温度和压力下使反应混合物中结晶硅铝酸盐结晶所需的时间。 期望将所述反应混合物预制成离散的颗粒，例如颗粒或挤出物，其保持其形状并在结晶过程中获得显着的强度。

    Highly siliceous porous crystalline material
    8.
    发明授权
    Highly siliceous porous crystalline material 失效
    高度硅质多孔结晶材料

    公开(公告)号：US5336478A

    公开(公告)日：1994-08-09

    申请号：US101791

    申请日：1993-08-02

    申请人： Francis G. Dwyer ,  Ernest W. Valyocsik

    发明人： Francis G. Dwyer ,  Ernest W. Valyocsik

    IPC分类号： B01J29/70 ,  C01B39/48 ,  C07C2/12 ,  C10G45/64 ,  C01B33/34

    CPC分类号： B01J29/7042 ,  B01J29/7484 ,  C01B39/48 ,  C07C2/12 ,  C10G45/64 ,  C07C2529/70

    摘要： A new zeolite, designated ZSM-22, is disclosed and claimed. The new zeolite has the composition, in the anhydrous state, expressed in terms of mole ratios of oxides as follows:(x)Q.sub.2 O:(y)M.sub.2/n O:(z)L.sub.2 O.sub.3 :100SiO.sub.2wherein Q.sub.2 O is the oxide form of an organic compound, M is an alkali or alkaline earth metal having a valence n, e.g., Na, K, Cs or Li and wherein x=0-2.0, y=0-2.0, z=0-5, and L=Al. Also disclosed are methods of preparing ZSM-22, e.g., with an alkane diamine directing agent, and uses of ZSM-22 as catalysts, e.g., in hydrocarbon conversion reactions.

    摘要翻译： 公开并要求保护名为ZSM-22的新型沸石。 新型沸石的组成为无水状态，以氧化物的摩尔比表示如下：（x）Q2O：（y）M2 / nO：（z）L2O3：100SiO2其中Q2O是有机物的氧化物形式 化合物，M是价数n的碱金属或碱土金属，例如Na，K，Cs或Li，其中x = 0-2.0，y = 0-2.0，z = 0-5，L = Al。 还公开了制备ZSM-22的方法，例如用烷二胺导向剂，以及ZSM-22作为催化剂，例如在烃转化反应中的用途。