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公开(公告)号:US20230246310A1
公开(公告)日:2023-08-03
申请号:US17696567
申请日:2022-03-16
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Yong LU , Zhe LI , Mengyan HOU , Qili SU , Meiyuan WU , Xiaochao QUE , Haijing LIU , Si CHEN
IPC: H01M50/543 , H01M10/0525 , H01M50/411 , H01M50/46 , H01M50/449 , H01M4/131 , H01M4/583
CPC classification number: H01M50/543 , H01M10/0525 , H01M50/411 , H01M50/46 , H01M50/449 , H01M4/131 , H01M4/583 , H01M2300/0082 , H01M2004/029
Abstract: A high-power gel-assisted battery stack that cycles lithium ions is provided with two terminal electrodes having opposite polarities and at least one bipolar electrode assembly disposed therebetween. A first electrode is disposed on a first side of a bipolar current collector and a second electrode with an opposite polarity to the first electrode is disposed on a second side of the bipolar current collector. Each electrode includes a porous layer having an electroactive material and a solid-state electrolyte disposed in a polymeric binder. A polymer gel electrolyte is distributed in pores of the porous. The stack also includes at least two free-standing gel separator layers each being disposed between the at least one bipolar electrode assembly and terminal electrodes. Each respective free-standing gel separator layer comprises polyacrylonitrile (PAN) and an electrolyte distributed therein. The high-power gel-assisted battery stack has a maximum voltage rating of ≥about 12V.
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公开(公告)号:US20230074112A1
公开(公告)日:2023-03-09
申请号:US17710213
申请日:2022-03-31
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Qili SU , Zhe LI , Yong LU , Haijing LIU
IPC: H01M10/0565 , H01M10/0525
Abstract: The present disclosure provides a polymeric gel electrolyte for an electrochemical cell that cycles lithium ions. The polymeric gel electrolyte includes greater than or equal to about 0.1 wt. % to less than or equal to about 10 wt. % of a non-lithium salt. The non-lithium salt includes a non-lithium cation having an ion radius that is greater than or equal to about 80% to less than or equal to about 250% of an ion radius of a lithium ion. The polymeric gel electrolyte further includes greater than or equal to about 50 wt. % to less than or equal to about 99.9 wt. % of a non-volatile gel. The non-volatile gel includes greater than or equal to 0 wt. % to less than or equal to about 50 wt. % of a polymeric host and greater than or equal to about 5 wt. % to less than or equal to about 100 wt. % of a liquid electrolyte.
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公开(公告)号:US20230025830A1
公开(公告)日:2023-01-26
申请号:US17697135
申请日:2022-03-17
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Qili SU , Mengyan HOU , Zhe LI , Haijing LIU
IPC: H01M10/0585 , H01M4/04 , H01M4/36 , H01M4/62 , H01M10/0565
Abstract: The present disclosure provides a method for forming a solid-state battery. The method includes stacking two or more cell units, where each cell unit is formed by substantially aligning a first electrode and a second electrode, where the first electrode includes one or more first electroactive material layers disposed on or adjacent to one or more surfaces of a releasable substrate and the second electrode includes one or more second electroactive material layers disposed on or adjacent to one or more surfaces of a current collector; disposing an electrolyte layer between exposed surfaces of the first electrode and the second electrode; and removing the releasable substrate to form the cell unit.
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公开(公告)号:US20230015143A1
公开(公告)日:2023-01-19
申请号:US17688445
申请日:2022-03-07
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Qili SU , Mengyan HOU , Meiyuan WU , Haijing LIU
IPC: H01M10/0562 , H01M10/0525 , H01M10/0583 , H01M10/04 , H01M4/04
Abstract: A method for forming a solid-state battery is provided. The method includes disposing one or more cell units along a continuous current collector to form a stack precursor. In some examples, disposing of the one or more cell units along the continuous current collector includes concurrently disposing the one or more cell units along the continuous current collector and winding the continuous current collector to form a stack. In other examples, the continuous current collector is a z-folded current collector and the disposing the one or more cell units along the continuous current collector includes inserting the one or more cell units into one or more pockets formed by folds of the continuous current collector. The method may further include applying heat, pressure, or a combination of heat and pressure to the stack precursor to form a compressed stack, and cutting the continuous current collector to form the solid-state battery.
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公开(公告)号:US20220123352A1
公开(公告)日:2022-04-21
申请号:US17481179
申请日:2021-09-21
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Zhe LI , Yong LU , Qili SU , Meiyuan WU , Haijing LIU
IPC: H01M10/056 , H01M10/0525 , H01M4/62 , H01M4/66
Abstract: A high-temperature stable solid-state bipolar battery is provided. The battery includes two or more electrodes, one or more solid-state electrolyte layers, and an ionogel disposed within void spaces within the battery. Each electrode includes a plurality of solid-state electroactive particles. Each solid-state electrolyte layer includes a plurality of solid-state electrolyte particles and a first solid-state electrolyte layer of the one or more solid-state electrolyte layers may be disposed between a first electrode and a second electrode of the two or more electrodes. The ionogel is disposed within void spaces between the two or more electrodes, the solid-state electroactive particles of the two or more electrodes, the solid-state electrolyte particles of the one or more solid-state electrolyte layers, and the one or more solid-state electrolyte layers, such that the battery has an reduced interparticle porosity. The ionogel may have an ionic conductivity between about 0.1 mS/Cm and about 10 mS/cm.
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公开(公告)号:US20250149539A1
公开(公告)日:2025-05-08
申请号:US18521119
申请日:2023-11-28
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Qili SU , Zhe LI , Haijing LIU
Abstract: A solid-state battery cell includes A anode electrodes including an anode active material layer arranged on an anode current collector, C cathode electrodes including a cathode active material layer arranged on a cathode current collector. The cathode active material layer includes cathode active material comprising particles including an outer layer of a material selected from a group consisting of LiNbO3, Li2ZrO3, Li3PO4, and combinations thereof. A solid electrolyte has a D50 size in a range from 4 μm to 12 μm. S separators are arranged between the A anode electrodes and the C cathode electrodes, where A, C, and S are integers greater than one.
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37.
公开(公告)号:US20240379996A1
公开(公告)日:2024-11-14
申请号:US18446219
申请日:2023-08-08
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Qili SU , Zhe Li , Yong Lu , Haijing Liu
IPC: H01M10/0562 , H01M4/505 , H01M4/58 , H01M4/66 , H01M50/491
Abstract: An oxide-based solid-state battery cell includes a cathode electrode comprising a cathode current collector. A cathode active layer is arranged adjacent to the cathode current collector and comprising cathode active material that exchanges lithium ions and a solid oxide electrolyte and an in-situ polymerization gel. A separator layer comprises a solid oxide electrolyte, a porous layer, and the in-situ polymerization gel. An anode electrode comprises an anode current collector, a silicon film, and the in-situ polymerization gel.
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38.
公开(公告)号:US20240274980A1
公开(公告)日:2024-08-15
申请号:US18365377
申请日:2023-08-04
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Zhe LI , Meiyuan WU , Qili SU , Dave G. Rich , Yong Lu , Haijing LIU
IPC: H01M50/457 , H01G11/52 , H01M10/052 , H01M10/0562 , H01M50/414 , H01M50/446
CPC classification number: H01M50/457 , H01G11/52 , H01M10/052 , H01M10/0562 , H01M50/414 , H01M50/446 , H01M2300/0068
Abstract: A functionalized separator for a battery cell includes a separator layer including a first side and a second side. A functionalized layer is arranged on at least one of the first side and the second side of the separator layer. The functionalized layer comprises a lithium-ion conducting solid electrolyte and a capacitor active material.
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公开(公告)号:US20240270121A1
公开(公告)日:2024-08-15
申请号:US18359411
申请日:2023-07-26
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Jingyuan LIU , Qili SU , Dave G. RICH , Si CHEN , James MORRISON , Dewen KONG , Haijing LIU
CPC classification number: B60L58/22 , B60L58/12 , B60L58/19 , B60L2240/547
Abstract: A state of charge (SOC) balancing system includes: first and second batteries; first and second capacitors; an SOC module configured to determine first and second SOCs of the first and second batteries, respectively; and a switching module configured to selectively, when the first SOC is greater than the second SOC: (i) electrically connect the first and second capacitors in parallel; (ii) electrically connect the first battery to the first and second capacitors while the first and second capacitors are electrically connected in parallel; (iii) electrically disconnect the first battery from the first and second capacitors; (iv) electrically connect the first and second capacitors in series; (v) electrically connect the second battery to the first and second capacitors while the first and second capacitors are electrically connected in series; and (vi) electrically disconnect the second battery from the first and second capacitors.
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公开(公告)号:US20240154095A1
公开(公告)日:2024-05-09
申请号:US18127444
申请日:2023-03-28
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Inventor: Zhe LI , Xingcheng XIAO , Qili SU , Yong LU
IPC: H01M4/36 , H01M4/04 , H01M4/38 , H01M4/583 , H01M10/0525
CPC classification number: H01M4/364 , H01M4/0404 , H01M4/0471 , H01M4/386 , H01M4/583 , H01M10/0525 , H01M2004/027
Abstract: An electrochemical cell includes a first electrode that includes a first current collector and a first electroactive material layer disposed on or near the first current collector, a second electrode that includes a second current collector and a second electroactive material layer disposed on or near the second current collector, and a separating layer disposed between the first electroactive material layer and the second electroactive material layer. The second electroactive material layer includes a plurality of hierarchical silicon columns, each of the hierarchical silicon columns has a longest dimension perpendicular to a major axis of the second current collector. The second electroactive material layer also includes a carbonaceous network that at least partially fills interstices defined between hierarchical silicon columns of the plurality of hierarchical silicon columns. The carbonaceous network includes linked carbon atoms that define a plurality of pores.
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