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    Process for the production of polyurethanes
    31.
    发明授权
    Process for the production of polyurethanes 失效
    聚氨酯生产工艺

    公开(公告)号：US4644016A

    公开(公告)日：1987-02-17

    申请号：US761278

    申请日：1985-08-01

    申请人： Werner Rasshofer ,  Hans-Albrecht Freitag

    发明人： Werner Rasshofer ,  Hans-Albrecht Freitag

    IPC分类号： C08G18/18 ,  C08G18/14 ,  C08G18/20

    CPC分类号： C08G18/1866

    摘要： Polyurethanes are made by reacting a polyisocyanate with a compound containing at least two isocyanate-reactive hydrogen atoms having a molecular weight of from 400 to 10,000 in the presence of a catalyst containing tertiary amino groups. The required catalyst corresponds to the formula ##STR1## in which R, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 represent a specified group or radical. A blowing agent and/or stabilizer and/or chain extending agent and/or other additives commonly used in the production of polyurethanes may optionally be included in the reaction mixture. The catalyst employed in the process is particularly advantageous in that it does not have a noticeable amine odor.

    摘要翻译： 聚氨酯通过使多异氰酸酯与含有至少两个分子量为400至10,000的异氰酸酯反应性氢原子的化合物在含有叔氨基的催化剂存在下反应而制备。 所需的催化剂对应于其中R，R 1，R 2，R 3，R 4，R 5，R 6和R 7表示指定基团或基团的式“IMAGE”。 在制备聚氨酯中通常使用的发泡剂和/或稳定剂和/或增链剂和/或其它添加剂可任选地包括在反应混合物中。 在该方法中使用的催化剂特别有利的是它不具有明显的胺气味。

    Homogeneous storage stable salt-containing mixture
    32.
    发明授权
    Homogeneous storage stable salt-containing mixture 失效
    均相储存稳定含盐混合物

    公开(公告)号：US4575518A

    公开(公告)日：1986-03-11

    申请号：US682221

    申请日：1984-12-17

    申请人： Werner Rasshofer ,  Reiner Paul

    发明人： Werner Rasshofer ,  Reiner Paul

    IPC分类号： C08G18/00 ,  C08G18/08 ,  C08G18/66 ,  C08L71/02 ,  C08G18/14

    CPC分类号： C08L71/02 ,  C08G18/6666 ,  C08G2120/00 ,  C08G2130/00 ,  Y10S521/914

    摘要： Homogeneous storable mixtures containing small quantities of salts and having a high mixed hydroxyl number of mixed hydroxyl/amine number are made by mixing (a) a polyoxyalkylene polyol and/or polyolamine and/or polyamine based on an alkyloxirane having a molecular weight of from 400 to 12,000, (b) a low molecular weight polyol which is not completely miscible with (a) and a solution-promoting additive in quantities such that for every 100 parts of (a), from 1 to 200 parts of (b) and from 0.01 to 10 parts of (c) are present. The solution-promoting additives are salts of cations of Groups IA, IIA and IIIA of the Periodic System of Elements or ammonium or mono- to tetra-alkylammonium ions and anions formed by removing at least one proton from an acid having a K.sub.s -value of at least 10.sup.-7. These mixtures are particularly useful in the production of polyurethanes.

    摘要翻译： 通过混合（a）基于分子量为400的烷基环氧乙烷和/或多胺胺和/或多胺的聚氧化烯多元醇和/或多胺来制备含有少量盐并具有高混合羟基/羟基数的混合羟值的均匀的可储存混合物 至（12），（b）与（a）不完全混溶的低分子量多元醇和一种溶液促进添加剂，其数量使得每100份（a），1至200份（b）和 存在0.01〜10份（c）。 溶液促进添加剂是元素周期体系的IA，IIA和IIIA族的阳离子盐，或铵或单烷基铵盐和一至四烷基铵离子，以及通过从具有Ks值的Ks值的酸除去至少一个质子形成的阴离子 至少10-7。 这些混合物在聚氨酯的生产中特别有用。

    Homogeneous, storage-stable polyol compositions of high ethylene glycol content and their use for the production of polyurethanes
    34.
    发明授权
    Homogeneous, storage-stable polyol compositions of high ethylene glycol content and their use for the production of polyurethanes 失效
    具有高乙二醇含量的均相，储存稳定的多元醇组合物及其用于生产聚氨酯的用途

    公开(公告)号：US4518521A

    公开(公告)日：1985-05-21

    申请号：US497626

    申请日：1983-05-24

    申请人： Rudolf Heusch ,  Werner Rasshofer ,  Wolfgang Reichmann ,  Adolf Richartz

    发明人： Rudolf Heusch ,  Werner Rasshofer ,  Wolfgang Reichmann ,  Adolf Richartz

    IPC分类号： C08G18/32 ,  C08G18/66 ,  C08G18/65

    CPC分类号： C08G18/667 ,  C08G18/3206 ,  C08G18/6674 ,  C08G2120/00 ,  C08G2130/00

    摘要： A homogeneous, storage-stable, emulsifier-free polyol mixture having a high mixed OH-number and a high ethylene glycol content comprising 100 parts of a relatively high molecular weight polyalkylene oxide polyol having an OH-number of from 20 to 210, which contains at least 5%, and less than 80%, by weight, of terminal ethylene oxide blocks, from 0.1 to 30 parts of a low molecular weight diol mixture having an OH-number of 1200 to 1650 in the form of a reaction product of 1 mole of ethylene glycol with 0.1 to 0.5 moles of propylene oxide, optionally, up to 5 parts of di- and/or tri-functional compounds containing reactive hydrogen atoms and having a molecular weight of from 32 to 399, and optionally, other auxiliaries and additives known in the production of polyurethanes. Also, polyurethanes produced using these polyol mixtures.

    摘要翻译： 具有高混合OH-数和高乙二醇含量的均匀，储存稳定，无乳化剂的多元醇混合物，其包含100份具有20至210的OH-数的相对高分子量的聚环氧烷多元醇，其含有 至少5重量％和小于80重量％的末端环氧乙烷嵌段，0.1至30重量份的羟基数为1200至1650的低分子量二醇混合物，其反应产物为1 摩尔的乙二醇与0.1至0.5摩尔的环氧丙烷，任选的至多5份含有反应性氢原子且分子量为32至399的二官能和/或三官能化合物，以及任选的其它助剂和 在聚氨酯生产中已知的添加剂。 此外，使用这些多元醇混合物制备的聚氨酯。

    Process for the preparation of polyamines from N-monoaryl-N',N'-dialkyl urea compounds and their use for the synthesis of polyurethanes
    35.
    发明授权
    Process for the preparation of polyamines from N-monoaryl-N',N'-dialkyl urea compounds and their use for the synthesis of polyurethanes 失效
    由N-单芳基-N'，N'-二烷基脲化合物制备多胺的方法及其在聚氨酯合成中的应用

    公开(公告)号：US4472568A

    公开(公告)日：1984-09-18

    申请号：US437398

    申请日：1982-10-28

    申请人： Werner Rasshofer ,  Gerhard Grogler

    发明人： Werner Rasshofer ,  Gerhard Grogler

    IPC分类号： C08G18/00 ,  C07C67/00 ,  C07C239/00 ,  C07C273/18 ,  C07C275/28 ,  C08G18/10 ,  C08G18/38 ,  C08G18/50 ,  C08G18/83 ,  C07C127/15 ,  C07C127/24

    CPC分类号： C08G18/83 ,  C07C273/1854 ,  C08G18/10 ,  C08G18/3819 ,  C08G18/5036

    摘要： This invention relates to an improved process for the preparation of aromatic polyamines containing urethane and/or biuret and/or urea and/or isocyanurate groups and preferably also ether groups by the hydrolysis of poly-N-monoaryl-N',N'-dialkyl urea compounds (1-aryl-3,3-dialkyl ureas). The ureas are obtained by the reaction of secondary aliphatic, cycloaliphatic or saturated heterocyclic amines with divalent to tetravalent isocyanate compounds containing isocyanate end groups attached to aromatic residues. The ureas correspond to the general formula: ##STR1## wherein R.sup.1, R.sup.2 denote alkyl or cycloalkyl groups, or together form a ring andA denotes a divalent to tetravalent residue attached to the ureas by aromatic groups.Hydrolysis is carried out in the presence of water and up to two equivalents of a base containing hydroxide ions and/or up to two equivalents of a compound containing tertiary amino groups, optionally in the presence of solvents. The use of the polyamines obtained by this process for the synthesis of polyurethanes is also described.

    摘要翻译： 本发明涉及一种改进的制备含氨基甲酸酯和/或缩二脲和/或脲和/或异氰脲酸酯基团的芳族多胺的方法，优选通过水解聚-N-单芳基-N'，N'-二烷基 脲化合物（1-芳基-3,3-二烷基脲）。 脲通过仲脂族，脂环族或饱和杂环胺与含有连接到芳族残基的异氰酸酯端基的二价至四价异氰酸酯化合物的反应获得。 脲对应于以下通式：其中R 1，R 2表示烷基或环烷基，或一起形成环，A表示通过芳族基团连接到脲上的二价至四价残基。 任选在溶剂存在下，在水的存在下和至多两当量的含氢氧根离子的碱和/或至多两当量的含有叔氨基的化合物进行水解。 还描述了通过该方法获得的用于合成聚氨酯的多胺的用途。

    Single-phase, storage-stable polyol compositions containing salts and the use thereof in the production of polyurethanes
    36.
    发明授权
    Single-phase, storage-stable polyol compositions containing salts and the use thereof in the production of polyurethanes 失效
    含有盐的单相，储存稳定的多元醇组合物及其在生产聚氨酯中的用途

    公开(公告)号：US4436841A

    公开(公告)日：1984-03-13

    申请号：US497640

    申请日：1983-05-24

    申请人： Werner Rasshofer ,  Wolfgang Reichmann ,  Adolf Richartz ,  Manfred Dietrich

    发明人： Werner Rasshofer ,  Wolfgang Reichmann ,  Adolf Richartz ,  Manfred Dietrich

    IPC分类号： C08G18/66 ,  C08K5/053 ,  C09K3/00 ,  C08G18/14 ,  C08G18/65

    CPC分类号： C08G18/6674 ,  C08K5/053 ,  C08G2120/00 ,  C08G2130/00 ,  Y10S521/914

    摘要： A single-phase, storage-stable, emulsifier-free polyol mixture comprising 100 parts of a relatively high molecular weight polyoxyalkylene polyol of OH number from 20 to 120, which has at least 5% and less than 80% by weight, of terminal oxyethylene blocks; from 1 to 100 parts of a low molecular weight diol mixture which is a reaction product of ethylene glycol, butane diol-1,4, or a mixture of ethylene glycol and butane diol-1,4, with from 0.05 to 0.50 mols of alkyl oxiranes; from 0.1 to 5 parts of solubilizing additives comprising one or more salts, the cations of which are from Groups I, II and III of the Periodic Table, ammonium or mono- to tetra-alkyl ammonium ions, and the anions of which are produced by removing at least one proton from an acid having a K.sub.s value of at least 10.sup.-7 ; and, optionally, other compounds having isocyanate-reactive hydrogen atoms and other auxiliaries and additives for polyurethane production. Also polyurethanes produced using these polyol mixtures.

    摘要翻译： 一种单相，储存稳定，不含乳化剂的多元醇混合物，其包含100份具有20-120的OH数量的相对高分子量的聚氧化烯多元醇，其具有至少5重量％且小于80重量％的末端氧化乙烯 块 1至100份低分子量二醇混合物，其是乙二醇，丁二醇-1,4-或乙二醇和丁二醇-1,4-的混合物与0.05至0.50摩尔烷基的反应产物 环氧乙烷 0.1至5份包含一种或多种盐的增溶添加剂，其阳离子来自周期表第I，II和III族，铵或一至四烷基铵离子，其阴离子由 从Ks值至少为10-7的酸中除去至少一个质子; 和任选的具有异氰酸酯反应性氢原子的其它化合物和用于聚氨酯生产的其它助剂和添加剂。 还使用这些多元醇混合物制备聚氨酯。

    Polyamines and processes for the production of such polyamines and of polyurethane plastics therefrom
    37.
    发明授权
    Polyamines and processes for the production of such polyamines and of polyurethane plastics therefrom 失效
    用于生产这种多胺和聚氨酯塑料的多胺和方法

    公开(公告)号：US4386218A

    公开(公告)日：1983-05-31

    申请号：US308326

    申请日：1981-10-05

    申请人： Werner Rasshofer ,  Dieter Dieterich ,  Holger Meyborg

    发明人： Werner Rasshofer ,  Dieter Dieterich ,  Holger Meyborg

    IPC分类号： C07C275/62 ,  B01J23/02 ,  B01J31/08 ,  C07B61/00 ,  C07C271/20 ,  C07C271/26 ,  C07C273/18 ,  C07C275/00 ,  C07C275/14 ,  C08G18/00 ,  C08G18/10 ,  C08G18/32 ,  C08G18/50 ,  C08G18/65 ,  C08G18/83 ,  C07C127/15 ,  C07C127/24

    CPC分类号： C08G18/83 ,  C07C273/1809 ,  C08G18/10 ,  C08G18/5048

    摘要： A compound having a terminal isocyanate group is hydrolyzed to produce a polyamine having a urethane and/or a urea and/or a biuret group. More particularly, a carbamate is made by mixing an isocyanate prepolymer having urethane and/or urea and/or biuret groups present with aqueous base solutions at a temperature of from 0.degree. to 0.degree. C. and in quantities such that the equivalent ratio of hydroxyl to isocyanate groups is between from 0.3:1 to .gtoreq.1.01 to 1. The carbamate is then treated with an acid ion exchanger to form an amine. The amine is then removed from any other material which may be present. A preferred polyamine thus-produced corresponds to the general formula: ##STR1## in which each R radical may represent a divalent straight or branched-chain aliphatic radical; a divalent cycloaliphatic radical; a 4,4'- and/or a 2,4'-dicyclohexylmethane radical; or a 2,4- and/or 2,6-methyl cyclohexane radical. Such an amine may be reacted with a polyisocyanate and optionally with other known additives to form a polyurethane plastic or foam.

    摘要翻译： 将具有末端异氰酸酯基的化合物水解以制备具有氨基甲酸酯和/或脲和/或缩二脲基的多胺。 更具体地，氨基甲酸酯是通过在0℃至0℃的温度下混合存在有氨基甲酸酯和/或脲和/或缩二脲基的异氰酸酯预聚物和/或缩二脲基与碱水溶液形成的，其量使得羟基的当量比 到异氰酸酯基团之间的比例为0.3:1至> / = 1.01:1。然后用酸式离子交换剂处理氨基甲酸酯以形成胺。 然后将胺从可能存在的任何其它材料中除去。 如此制备的优选的多胺对应于通式：其中每个R基团可以表示二价直链或支链脂族基团; 二价脂环族基团; 4,4'-和/或2,4'-二环己基甲基基团; 或2,4-和/或2,6-甲基环己烷基。 这样的胺可以与多异氰酸酯和任选地与其它已知的添加剂反应以形成聚氨酯塑料或泡沫。

    Process for the preparation of compounds having s-triazine units and epoxide groups
    38.
    发明授权
    Process for the preparation of compounds having s-triazine units and epoxide groups 失效
    制备具有三嗪单元和环氧基团的化合物的方法

    公开(公告)号：US4384102A

    公开(公告)日：1983-05-17

    申请号：US336659

    申请日：1982-01-04

    申请人： Werner Rasshofer ,  Gerhard Grogler ,  Richard Kopp

    发明人： Werner Rasshofer ,  Gerhard Grogler ,  Richard Kopp

    IPC分类号： C07D405/14 ,  C07D405/12 ,  C08G18/00 ,  C08G18/79 ,  C08G18/80 ,  C08G18/77

    CPC分类号： C07D405/12 ,  C08G18/003 ,  C08G18/8058

    摘要： Compounds having both s-triazine units and epoxide groups present are prepared by reacting an epoxide containing an isocyanate-reactive group with a triisocyanate corresponding to the formula: ##STR1## in which X is as defined herein. These reactants are used in quantities such that the equivalent ratio of isocyanate groups to isocyanate-reactive groups is maintained at less than or equal to 1 to 1. The compounds thus produced are particularly useful as reactive cross-linkers in the production of polyurethanes and polyepoxides.

    摘要翻译： 通过使含有异氰酸酯反应性基团的环氧化物与对应于下式的其中X如本文所定义的下式的三异氰酸酯反应来制备具有均三嗪单元和环氧基团的化合物。 这些反应物的用量使得异氰酸酯基团与异氰酸酯反应性基团的当量比保持在小于或等于1比1。由此制备的化合物特别可用作聚氨酯和聚环氧化物生产中的反应性交联剂 。