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公开(公告)号:US20220219979A1
公开(公告)日:2022-07-14
申请号:US17572544
申请日:2022-01-10
Applicant: Honeywell International Inc.
Inventor: Yuon Chiu , Haiyou Wang , Haluk Kopkalli , Christian Jungong , Haridasan K. Nair , Rajiv Ratna Singh , Daniel C. Merkel , Tao Wang , Terris Yang , Richard Wilcox
Abstract: A method of removing water from a mixture of hydrogen iodide (HI) and water includes providing a mixture comprising hydrogen iodide and water and contacting the mixture with an adsorbent to selectively adsorb water from the mixture, contacting the mixture with a weak acid to absorb water from the mixture and/or separating the water from hydrogen iodide (HI) by azeotropic distillation to produce anhydrous hydrogen iodide (HI).
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公开(公告)号:US20220073803A1
公开(公告)日:2022-03-10
申请号:US17531476
申请日:2021-11-19
Inventor: Hang T. Pham , Ryan J. Hulse , Rajiv Ratna Singh , Haridasan K. Nair
Abstract: The present disclosure provides azeotrope or azeotrope-like compositions including trifluoroiodomethane (CF3I) and trifluoroacetyl chloride (CF3COCl), and a method of forming an azeotrope or azeotrope-like composition comprising the step of combining trifluoroacetyl chloride (CF3COCl) and trifluoroiodomethane (CF3I) to form an azeotrope or azeotrope-like composition.
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公开(公告)号:US10934233B2
公开(公告)日:2021-03-02
申请号:US16267722
申请日:2019-02-05
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: Haridasan K. Nair , Rajiv Ratna Singh , Glenn Matthies
IPC: C07C17/23
Abstract: The present invention relates to a process for the preparation of haloethylenes, and preferably perhaloethylenes, by the gas-phase dechlorination of haloethanes in the presence of a catalyst and optionally in the presence of an alkene or an alkane. In particular aspects, the invention relates to a gas-phase process for preparing chlorotrifluoroethylene (CTFE). More particularly, the present invention relates to a gas-phase process for preparing CTFE from 1,1,2-trichloro-1,2,2-trifluoroethane (CFC-113) by dechlorination in the presence of an alkene or an alkane and a catalyst.
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公开(公告)号:US20200377366A1
公开(公告)日:2020-12-03
申请号:US16887225
申请日:2020-05-29
Applicant: Honeywell International Inc.
Inventor: Haridasan K. Nair , Ryan J. Hulse
IPC: C01B7/13
Abstract: A process for the manufacture of hydrogen iodide (HI) from hydrogen (H2) and elemental iodine (I2) dissolved in a suitable solvent with use of at least one catalyst selected from the group of platinum, palladium, nickel, cobalt, iron, nickel oxide, cobalt oxide, and iron oxide.
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公开(公告)号:US20200062678A1
公开(公告)日:2020-02-27
申请号:US16549389
申请日:2019-08-23
Applicant: Honeywell International Inc.
Inventor: Haridasan K. Nair , Rajiv Banavali , Rajiv Ratna Singh
IPC: C07C17/087
Abstract: The present disclosure provides a gas-phase process for producing trifluoroiodomethane, the process comprising providing a reactant stream comprising hydrogen iodide and trifluoroacetyl halide selected from the group consisting of trifluoroacetyl chloride, trifluoroacetyl fluoride, trifluoroacetyl bromide, and combinations thereof, and reacting the reactant stream in the presence of a catalyst at a temperature from about 200° C. to about 600° C. to produce a product stream comprising the trifluoroiodomethane.
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公开(公告)号:US20190055442A1
公开(公告)日:2019-02-21
申请号:US16040908
申请日:2018-07-20
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: Rajiv R. Singh , Haridasan K. Nair , Raymond H. Thomas , Lawrence A. Ford , David P. Wilson
IPC: C09K5/04
Abstract: Disclosed are compositions comprising at least one iodocarbon compound and preferably at least one stabilization agent comprising a diene-based compound. These compositions are generally useful as refrigerants for heating and cooling, as blowing agents, as aerosol propellants, as solvent composition, and as fire extinguishing and suppressing agents.
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公开(公告)号:US10035743B1
公开(公告)日:2018-07-31
申请号:US15797015
申请日:2017-10-30
Applicant: Honeywell International inc.
Inventor: Haridasan K. Nair , Rajiv Ratna Singh
IPC: C07C17/087 , C07C17/20 , C07C21/18 , B01J27/128 , C07C19/08 , B01J27/10 , C07C17/25
CPC classification number: C07C17/087 , B01J27/10 , B01J27/128 , C07C17/206 , C07C17/208 , C07C17/25 , C07C19/08 , C07C21/18
Abstract: A method for converting 1, 3, 3, 3-tetrafluoropropene (HFO-1234ze) to 1-chloro-3, 3, 3-trifluoropropene (HCFC-1233zd) with high selectivity and without significant formation of 1, 1, 1, 3, 3-pentafluoropropane (HFC-245fa), by reacting 1234ze and hydrogen chloride (HCl) in a gas phase using a ferric chloride (FeCl3) catalyst or a ruthenium chloride (RuCl3) catalyst.
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公开(公告)号:US10005705B2
公开(公告)日:2018-06-26
申请号:US15807033
申请日:2017-11-08
Applicant: Honeywell International Inc.
Inventor: Haridasan K. Nair , Rajiv Banavali , Yian Zhai , Glenn Matthies
IPC: C07C17/275
CPC classification number: C07C17/275 , C07C2601/04 , Y02P20/582 , C07C23/06
Abstract: The production of 1, 1, 2-trifluoro-2-(trifluoromethyl)cyclobutane (TFMCB). More specifically, the present invention relates to a process for making 1, 1, 2-trifluoro-2-(trifluoromethyl)cyclobutane via a continuous catalytic reaction from commercially available raw materials ethylene and hexafluoropropene.
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公开(公告)号:US20160215191A1
公开(公告)日:2016-07-28
申请号:US14929916
申请日:2015-11-02
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: Rajiv R. Singh , Haridasan K. Nair , Raymond H. Thomas , Lawrence A. Ford , David P. Wilson
IPC: C09K5/04 , C10M171/00
CPC classification number: C09K5/044 , C09K5/045 , C09K2205/122 , C09K2205/126 , C10M171/008 , C10M2205/026 , C10M2205/08 , C10M2207/023 , C10M2207/026 , C10M2207/042 , C10M2209/1033 , C10M2211/022 , C10M2223/049 , C10N2220/302
Abstract: Disclosed are compositions comprising at least one iodocarbon compound and preferably at least one stabilization agent. These compositions are generally useful as refrigerants for heating and cooling, as blowing agents, as aerosol propellants, as solvent composition, and as fire extinguishing and suppressing agents.
Abstract translation: 公开了包含至少一种碘化碳化合物和优选至少一种稳定剂的组合物。 这些组合物通常可用作加热和冷却的制冷剂,作为发泡剂,作为气溶胶推进剂,作为溶剂组合物,以及灭火和抑制剂。
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公开(公告)号:US20160023973A1
公开(公告)日:2016-01-28
申请号:US14877225
申请日:2015-10-07
Applicant: HONEYWELL INTERNATIONAL INC.
Inventor: Haridasan K. Nair , Yian Zhai , Andrew J. Poss , Rajiv R. Singh , David Nalewajek
IPC: C07C19/16 , C07C323/03 , C07C43/13 , C07C309/06
CPC classification number: C07C19/16 , C07C21/18 , C07C41/03 , C07C43/137 , C07C43/1786 , C07C57/03 , C07C229/12 , C07C309/06 , C07C323/03 , C07C323/25 , C08F14/18 , C08F214/18
Abstract: To address the problem of insufficient biodegradability of perfluorinated surfactants, the present invention provides biodegradable fluorosurfactants derived from olefins having —CHR, —CHRf, —CHF, and/or —CH2 groups, where R is an alkyl group and Rf is a perfluoro or fluroroalkyl group. Preferably, the —CHR, —CHRf, —CHF, and/or —CH2 groups are contained within partially fluorinated alkenes.
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