摘要:
An ion implantation system is provided having an ion source configured to form an ion beam from aluminum iodide. A beamline assembly selectively transports the ion beam to an end station configured to accept the ion beam for implantation of aluminum ions into a workpiece. The ion source has a solid-state material source having aluminum iodide in a solid form. A solid source vaporizer vaporizes the aluminum iodide, defining gaseous aluminum iodide. An arc chamber forms a plasma from the gaseous aluminum iodide, where arc current from a power supply is configured to dissociate aluminum ions from the aluminum iodide. One or more extraction electrodes extract the ion beam from the arc chamber. A water vapor source further introduces water to react residual aluminum iodide to form hydroiodic acid, where the residual aluminum iodide and hydroiodic acid is evacuated from the system.
摘要:
This invention is directed to compositions of matter comprising a hydride ion having a binding energy greater than about 0.8 eV. The claimed hydride ions may be combined with cations, including a proton, to form novel hydrides.
摘要:
A method for producing a metal oxide powder which comprises heating a metal or metals in an atmosphere gas comprising a halogen gas, a hydrogen halide gas or a mixture of these gases in a concentration of from 0.5% by volume or more to 99.5% by volume or less; and oxygen, water vapor or a mixture of these gases in a concentration of from 0.5% by volume or more to 99.5% by volume or less.
摘要:
A process for producing refined hydrogen iodide having organic components of 0.2 ppm by volume or less and water of 0.1 ppm by volume or less by contacting crude hydrogen iodide with a zeolite is disclosed. Crude hydrogen iodide is obtained by reducing iodine with a hydrogenated naphthalene, wherein all of the iodine is dissolved in advance in a portion of the hydrogenated naphthalene to prepare an iodine solution, and the reaction is carried out while adding continuously or intermittently the iodine solution to the balance of the hydrogenated naphthalene. The same operation may be repeated in succession using unreacted hydrogenated naphthalene and fresh iodide. The zeolite is contacted in advance with crude hydrogen iodide, the amount of which is at least 1/3 (weight ratio) relative to the amount of the zeolite, to convert impurities of sulfur components contained in the zeolite to hydrogen sulfide, thereby removing the sulfur components. Further, an activated carbon may be combined with the zeolite at the rear stage thereof.
摘要:
Aqueous iodine-iodide etching solutions are employed in the recovery of precious metals. Elemental iodine is precipitated from spent etching solutions and used to supply both the iodine and iodide of new etching solutions. Prior to extraction of the elemental iodine, used solutions, if not substantially contaminated, may be oxidized and recycled for further precious metal recovery. Aqueous etching solutions of hydriodic acid and iodine, or of ammonium iodide and iodine may be employed. Etching in such solutions, as well as in solutions of iodine and an alkali metal iodide, such as potassium iodide, may be accelerated by the use of small amounts of hydrogen peroxide (or equivalents) during etching.
摘要:
A process for the preparation of amino halogeno aromatic compounds, according to which a halogenonitro-aromatic compound is brought into the presence of a nickel-, cobalt- or iron-based catalyst, preferably nickel-based, and, more preferably, Raney nickel, in the presence of an effective amount of iodide, at a temperature and hydrogen pressure sufficient to form said halogenoamino-aromatic compound.
摘要:
A process for drying a gaseous hydrogen halide of the formula HX, wherein X is bromine, Chlorine, FLuorine, or iodine, to remove water impurity therefrom, in which a scavenger precursor composition is provided, including a support having associated therewith partially or fully alkylated metal alkyl compounds or pendant groups. The precursor composition is reacted with gaseous hydrogen halide to convert the metal alkyl compounds and/or pendant functional groups to the corresponding metal halide compounds and/or pendant functional groups, which in turn react with the water impurity to produce an essentially completely water-free (below 0.1 ppm) gaseous hydrogen halide effluent. The process of the invention has utility for producing high purity, anhydrous gaseous hydrogen halides for semiconductor manufacturing operations.
摘要:
1. A PROCESS FOR PRODUCING AQUEOUS HYDROGEN IODIDE WHICH COMPRISES REACTING HYDROGEN AND IODINE IN WATER AT A TEMPERATURE FROM ABOUT 70* TO ABOUT 125*C. AND A PRESSURE FROM ABOUT 50 TO ABOUT 80 P.S.I.G. IN CONTACT WITH A CATALYST CONSISTING ESSENTIALLY OF A METAL SELECTED FROM THE GROUP CONSISTING OF RHODIUM AND RUTHENIUM SUPPORTED ON AN INERT MATERIAL, THE AMOUNT OF METAL IN SAID CATLSYT BEING IN THE RANGE FROM ABOUT 0.00001 MOLE TO ABOUT 0.01 MOLE PER MOLE OF IODINE.
摘要:
CHROMIUM-DIOXIDE OF RUTILE-TYPE CRYSTAL-STRUCTURE AND MODIFIED CHROMIUM-DIOXIDE CONTAINING OXIDES AND/OR FLUORIDES OF CATIONS WHICH HAVE RADII IN THE RANGE BETWEEN 0.46 AND 0.91 A. CAN BE USED AS CATALYSTS WITH HIGH AND PERMANENT ACTIVITY TO PROMOTE OXIDATION-PROCESSES SUCH AS OXIDATION OF HYDROGEN-CHLORIDE TO CHLORINE AND WATER, CONVERSION OF SULFUR-DIOXIDE TO SULFUR-TRIOXIDE OXIDATION OF CARBON-MONOXIDE TO CARON-DIOXIDE, OXIDATION OF AMMONIA TO NITRIC OXIDES OXIDATION AND OXYCLORINATION OF HYDROCARBONS, COMBUSTION OF HYDROGEN OR ALCOHOLS AND THE LIKE. THE CHROMIUM-DIOXIDE OR THE MODIFIED CHROMIUM-DIOXIDE CAN BE USED AS SUCH OR TOGETHER WITH CARRIERS. FURTHERMORE IT IS POSSIBLE TO COMBINE THE CHROMIUM-DIOXIDE CATALYSTS WITH OTHER CATALYTICALLY ACTIVE MATERIALS.