Production process for refined hydrogen iodide
    5.
    发明授权
    Production process for refined hydrogen iodide 失效
    精制碘化氢的生产工艺

    公开(公告)号:US5693306A

    公开(公告)日:1997-12-02

    申请号:US562084

    申请日:1995-11-22

    IPC分类号: C01B7/13

    CPC分类号: C01B7/135

    摘要: A process for producing refined hydrogen iodide having organic components of 0.2 ppm by volume or less and water of 0.1 ppm by volume or less by contacting crude hydrogen iodide with a zeolite is disclosed. Crude hydrogen iodide is obtained by reducing iodine with a hydrogenated naphthalene, wherein all of the iodine is dissolved in advance in a portion of the hydrogenated naphthalene to prepare an iodine solution, and the reaction is carried out while adding continuously or intermittently the iodine solution to the balance of the hydrogenated naphthalene. The same operation may be repeated in succession using unreacted hydrogenated naphthalene and fresh iodide. The zeolite is contacted in advance with crude hydrogen iodide, the amount of which is at least 1/3 (weight ratio) relative to the amount of the zeolite, to convert impurities of sulfur components contained in the zeolite to hydrogen sulfide, thereby removing the sulfur components. Further, an activated carbon may be combined with the zeolite at the rear stage thereof.

    摘要翻译: 公开了一种通过使粗碘化氢与沸石接触来制造有机成分为0.2ppm(体积)或更少的精制碘化氢和0.1ppm(体积)以下的水的方法。 通过用氢化萘还原碘获得粗碘化氢,其中所有碘预先溶解在氢化萘的一部分中以制备碘溶液,并且在连续或间歇地将碘溶液加入到 氢化萘的平衡。 可以使用未反应的氢化萘和新鲜碘化物连续地重复相同的操作。 预先将沸石与粗的碘化氢接触,其中的碘化氢至少为+ E,相对于沸石的量为1/3 + EE(重量比),将沸石中所含的硫成分的杂质转化为 硫化氢,从而除去硫成分。 此外,活性炭可以在其后段与沸石结合。

    Processes employing iodine-iodide etching solutions
    6.
    发明授权
    Processes employing iodine-iodide etching solutions 失效
    使用碘碘化物蚀刻溶液的方法

    公开(公告)号:US5137700A

    公开(公告)日:1992-08-11

    申请号:US342587

    申请日:1989-04-24

    申请人: Hilbert Sloan

    发明人: Hilbert Sloan

    IPC分类号: C01B7/13 C01B7/14 C01G7/00

    CPC分类号: C22B11/04 C01B7/13

    摘要: Aqueous iodine-iodide etching solutions are employed in the recovery of precious metals. Elemental iodine is precipitated from spent etching solutions and used to supply both the iodine and iodide of new etching solutions. Prior to extraction of the elemental iodine, used solutions, if not substantially contaminated, may be oxidized and recycled for further precious metal recovery. Aqueous etching solutions of hydriodic acid and iodine, or of ammonium iodide and iodine may be employed. Etching in such solutions, as well as in solutions of iodine and an alkali metal iodide, such as potassium iodide, may be accelerated by the use of small amounts of hydrogen peroxide (or equivalents) during etching.

    摘要翻译: 碘化碘水溶液用于回收贵金属。 元素碘从废蚀刻溶液中沉淀出来,用于提供新的蚀刻溶液的碘和碘化物。 在提取元素碘之前,使用的溶液(如果基本上不被污染)可以被氧化并再循环用于进一步的贵金属回收。 可以使用氢碘酸和碘的水蚀刻溶液,或碘化铵和碘。 在蚀刻期间,可以通过使用少量的过氧化氢(或等同物)来加速这种溶液中的碘化物和碘化钾等碱金属碘化物的溶液的蚀刻。

    Process and composition for drying of gaseous hydrogen halides
    8.
    发明授权
    Process and composition for drying of gaseous hydrogen halides 失效
    用于干燥气态卤化氢的方法和组合物

    公开(公告)号:US4925646A

    公开(公告)日:1990-05-15

    申请号:US357049

    申请日:1989-05-25

    摘要: A process for drying a gaseous hydrogen halide of the formula HX, wherein X is bromine, Chlorine, FLuorine, or iodine, to remove water impurity therefrom, in which a scavenger precursor composition is provided, including a support having associated therewith partially or fully alkylated metal alkyl compounds or pendant groups. The precursor composition is reacted with gaseous hydrogen halide to convert the metal alkyl compounds and/or pendant functional groups to the corresponding metal halide compounds and/or pendant functional groups, which in turn react with the water impurity to produce an essentially completely water-free (below 0.1 ppm) gaseous hydrogen halide effluent. The process of the invention has utility for producing high purity, anhydrous gaseous hydrogen halides for semiconductor manufacturing operations.

    摘要翻译: 一种用于干燥式HX的气态卤化氢的方法,其中X是溴,氯,氟嘌呤或碘,以除去其中含有杂质的水分杂质,其中提供了一种清除剂前体组合物,包括其部分或完全烷基化的载体 金属烷基化合物或侧基。 前体组合物与气态卤化氢反应以将金属烷基化合物和/或侧链官能团转化成相应的金属卤化物化合物和/或侧基官能团,其又与水杂质反应以产生基本上完全无水的 (低于0.1ppm)气态卤化氢流出物。 本发明的方法可用于生产用于半导体制造操作的高纯度无水气态卤化氢。

    Method for producing hydrogen iodide
    9.
    发明授权
    Method for producing hydrogen iodide 失效
    生产氢碘酸盐的方法

    公开(公告)号:US3848065A

    公开(公告)日:1974-11-12

    申请号:US29368672

    申请日:1972-09-29

    申请人: MONSANTO CO

    发明人: PAULIK F

    IPC分类号: C01B7/13 C01B7/18

    CPC分类号: C01B7/135

    摘要: 1. A PROCESS FOR PRODUCING AQUEOUS HYDROGEN IODIDE WHICH COMPRISES REACTING HYDROGEN AND IODINE IN WATER AT A TEMPERATURE FROM ABOUT 70* TO ABOUT 125*C. AND A PRESSURE FROM ABOUT 50 TO ABOUT 80 P.S.I.G. IN CONTACT WITH A CATALYST CONSISTING ESSENTIALLY OF A METAL SELECTED FROM THE GROUP CONSISTING OF RHODIUM AND RUTHENIUM SUPPORTED ON AN INERT MATERIAL, THE AMOUNT OF METAL IN SAID CATLSYT BEING IN THE RANGE FROM ABOUT 0.00001 MOLE TO ABOUT 0.01 MOLE PER MOLE OF IODINE.

    Chromium-dioxide-catalyst
    10.
    发明授权
    Chromium-dioxide-catalyst 失效
    二氧化铬催化剂

    公开(公告)号:US3667913A

    公开(公告)日:1972-06-06

    申请号:US3667913D

    申请日:1970-05-04

    申请人: BAYER AG

    发明人: HUND FRANZ

    摘要: CHROMIUM-DIOXIDE OF RUTILE-TYPE CRYSTAL-STRUCTURE AND MODIFIED CHROMIUM-DIOXIDE CONTAINING OXIDES AND/OR FLUORIDES OF CATIONS WHICH HAVE RADII IN THE RANGE BETWEEN 0.46 AND 0.91 A. CAN BE USED AS CATALYSTS WITH HIGH AND PERMANENT ACTIVITY TO PROMOTE OXIDATION-PROCESSES SUCH AS OXIDATION OF HYDROGEN-CHLORIDE TO CHLORINE AND WATER, CONVERSION OF SULFUR-DIOXIDE TO SULFUR-TRIOXIDE OXIDATION OF CARBON-MONOXIDE TO CARON-DIOXIDE, OXIDATION OF AMMONIA TO NITRIC OXIDES OXIDATION AND OXYCLORINATION OF HYDROCARBONS, COMBUSTION OF HYDROGEN OR ALCOHOLS AND THE LIKE. THE CHROMIUM-DIOXIDE OR THE MODIFIED CHROMIUM-DIOXIDE CAN BE USED AS SUCH OR TOGETHER WITH CARRIERS. FURTHERMORE IT IS POSSIBLE TO COMBINE THE CHROMIUM-DIOXIDE CATALYSTS WITH OTHER CATALYTICALLY ACTIVE MATERIALS.