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    Process for selective formation of C.sub.4 compounds and thiol-containing catalyst system used therein
    31.
    发明授权
    Process for selective formation of C.sub.4 compounds and thiol-containing catalyst system used therein 失效
    用于选择性形成C4化合物和其中使用的含硫醇催化剂体系的方法

    公开(公告)号：US4339610A

    公开(公告)日：1982-07-13

    申请号：US215555

    申请日：1980-12-11

    申请人： Wayne R. Pretzer ,  Thaddeus P. Kobylinski ,  John E. Bozik

    发明人： Wayne R. Pretzer ,  Thaddeus P. Kobylinski ,  John E. Bozik

    IPC分类号： C07C29/32 ,  C07C45/49 ,  C07C27/22 ,  C07C45/50

    CPC分类号： C07C29/32 ,  C07C45/49 ,  C12C11/02 ,  Y02P20/52

    摘要： C.sub.4 compounds including n-butanol and n-butanal are produced by reacting methanol, hydrogen, and carbon monoxide, in the presence of a cobalt catalyst selected from the group consisting of (a) a cobalt carbonyl, (b) a hydrido cobalt carbonyl and (c) a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, an iodine promotor and a thiol defined by the formula:RSHwherein R is selected from the group consisting of saturated or unsaturated, straight or branched chain alkyl radicals having from one to 24 carbon atoms, cycloalkyl radicals having from three to 40 carbon atoms, aryl radicals having from six to 20 carbon atoms, aralkyl and alkaryl radicals having from six to 40 carbon atoms and halogen substituted derivatives thereof. A high degree of selectivity towards the formation of butanol and butanal is provided by using the cobalt entity and the thiol in a molar ratio in the range of about 2:1 to about 10:1, based on elemental cobalt and sulfur. The reaction is conducted at elevated temperature and pressure conditions for a time sufficient to convert methanol to n-butanol and n-butanal.

    摘要翻译： 包括正丁醇和正丁醛的C 4化合物通过甲醇，氢气和一氧化碳在钴催化剂存在下制备，所述钴催化剂选自（a）羰基钴，（b）羰基钴和 （c）可转化为羰基钴或羰基钴的钴的物质，碘促进剂和由下式定义的硫醇：其中R选自饱和或不饱和的直链或支链烷基 具有1至24个碳原子，具有3至40个碳原子的环烷基，具有6至20个碳原子的芳基，具有6至40个碳原子的芳烷基和烷芳基及其卤素取代的衍生物。 基于元素钴和硫，通过使用钴实体和硫醇以约2:1至约10:1的摩尔比来提供对形成丁醇和丁醛的高度选择性。 反应在升高的温度和压力条件下进行足以将甲醇转化为正丁醇和正丁醛的时间。

    Hydrocarbon synthesis using a rare earth promoted metal silicate
    40.
    发明授权
    Hydrocarbon synthesis using a rare earth promoted metal silicate 失效
    使用稀土促进金属硅酸盐的合成

    公开(公告)号：US4116995A

    公开(公告)日：1978-09-26

    申请号：US745630

    申请日：1976-11-29

    申请人： Thaddeus P. Kobylinski ,  Harold E. Swift

    发明人： Thaddeus P. Kobylinski ,  Harold E. Swift

    IPC分类号： B01J29/04 ,  C07C1/04 ,  C07C1/12 ,  C07C27/06

    CPC分类号： B01J29/049 ,  C07C1/0435 ,  C07C1/12 ,  C07C2521/16 ,  C07C2523/10 ,  C07C2523/755

    摘要： The conversion of carbon monoxide and hydrogen to produce a mixture of low molecular weight hydrocarbons which, on a methane-free basis, contain a predominance of C.sub.2 -C.sub.6 paraffins is achieved using as the catalyst a rare earth metal promoted layered complex metal silicate composition characterized as having repeating units of the structural formula[(1-x)Ni.sup.a + xRu.sup.6 ].sub.n (OH).sub.4 Si.sub.2 O.sub.5.wH.sub.2 Owhere x is a number from 0 to 1, this number expressing the atomic fraction of the metals nickel and ruthenium; a is the valence of nickel; b is the valence of ruthenium; n is a number equal in value to that defined by the ratio6/[a(1-x) + bx]and w is a number ranging from 0 to 4. A rare earth promoted nickel chrysotile is the preferred catalyst.