公开(公告)号：US08357813B2

公开(公告)日：2013-01-22

申请号：US13300112

申请日：2011-11-18

Applicant: William Herman Gerdes ,  John Robert Lockemeyer ,  Donald James Remus ,  Thomas Szymanski ,  Randall Clayton Yeates

Inventor： William Herman Gerdes ,  John Robert Lockemeyer ,  Donald James Remus ,  Thomas Szymanski ,  Randall Clayton Yeates

IPC: C07D301/03 ,  C07D301/10 ,  C07D317/44 ,  C07C27/00 ,  C07C29/00 ,  C07C29/03 ,  C07C31/18 ,  C07C41/00 ,  C07C43/00 ,  B01J23/48 ,  B01J23/50

CPC classification number: B01J23/66 ,  B01J21/04 ,  B01J21/12 ,  B01J23/50 ,  B01J23/688 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1071 ,  B01J35/108 ,  B01J37/0018 ,  C07C29/106 ,  C07D301/10 ,  Y02P20/52 ,  C07C31/202

Abstract: The invention provides a process for the epoxidation of an olefin, which process comprises reacting a feed comprising an olefin and oxygen in the presence of a catalyst comprising a carrier and silver deposited on the carrier, which carrier comprises at least 85 weight percent α-alumina and has a surface area of at least 1.3 m2/g, a median pore diameter of more than 0.8 μm, and a pore size distribution wherein at least 80% of the total pore volume is contained in pores with diameters in the range of from 0.1 to 10 μm and at least 80% of the pore volume contained in the pores with diameters in the range of from 0.1 to 10 μm is contained in pores with diameters in the range of from 0.3 to 10 μm.

Abstract translation: 本发明提供了烯烃环氧化方法，该方法包括在包含载体和沉积在载体上的银的催化剂存在下使包含烯烃和氧的进料反应，该载体包含至少85重量％的α-氧化铝 并且具有至少1.3m 2 / g的表面积，大于0.8μm的中值孔径以及孔径分布，其中总细孔容积的至少80％包含在直径范围为0.1的孔中 直径在0.3〜10μm范围内的孔中含有直径在0.1〜10μm范围内的细孔容积的至少80％。

公开(公告)号：US20120226057A1

公开(公告)日：2012-09-06

申请号：US13470867

申请日：2012-05-14

Applicant: Randall Clayton YEATES ,  John Robert Lockemeyer ,  Marek Matusz

Inventor： Randall Clayton YEATES ,  John Robert Lockemeyer ,  Marek Matusz

IPC: B01J27/135 ,  C07D301/10 ,  B01J27/06

CPC classification number: B01J21/04 ,  B01J23/02 ,  B01J23/10 ,  B01J23/50 ,  B01J23/688 ,  B01J27/138 ,  B01J35/002 ,  C07C29/106 ,  C07D301/10 ,  Y02P20/142 ,  C07C31/20

Abstract: A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.

Abstract translation: 提供了一种制备载体的方法，该方法包括在载体制备的任何阶段在载体中引入强度增强添加剂。 还提供了其中结合有强度增强添加剂的所得载体和包含载体的催化剂。 还提供了使用该催化剂对烯烃进行环氧化的方法。 还提供了使用如此制备的用于制备1,2-二醇，1,2-二醇醚或链烷醇胺的烯烃氧化物的方法。

公开(公告)号：US07507689B2

公开(公告)日：2009-03-24

申请号：US11746261

申请日：2007-05-09

Applicant: John Robert Lockemeyer

Inventor： John Robert Lockemeyer

IPC: B01J21/02 ,  B01J27/02 ,  B01J27/06 ,  B01J23/00 ,  B01J23/10 ,  B01J23/70 ,  B01J23/74 ,  B01J23/02 ,  B01J23/04 ,  B01J23/48 ,  B01J23/50

CPC classification number: B01J23/66 ,  B01J21/04 ,  B01J23/50 ,  B01J23/58 ,  B01J23/688 ,  B01J35/002 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1076 ,  B01J37/06 ,  B01J37/30 ,  C07D301/10

Abstract: There is provided a catalyst carrier comprising a refractory inorganic material having a sodium solubilization rate no greater than 5 ppmw/5 minutes. There is further a catalyst comprising a refractory inorganic material carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and one or more catalytically reactive metals deposited on said carrier. There is also provided a catalyst suitable for the vapor phase production of alkylene oxide from olefins and oxygen comprising an alumina-based carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and catalytically reactive silver deposited on said carrier.

公开(公告)号：US07504525B2

公开(公告)日：2009-03-17

申请号：US10935841

申请日：2004-09-08

Applicant: John Robert Lockemeyer

Inventor： John Robert Lockemeyer

IPC: C07D301/10 ,  B01J23/48 ,  B01J23/00 ,  B01J21/02

CPC classification number: B01J35/002 ,  B01J21/04 ,  B01J23/66 ,  B01J23/688 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1076 ,  B01J37/06

Abstract: There is provided a catalyst carrier comprising a refractory inorganic material having a sodium solubilization rate no greater than 5 ppmw/5 minutes. There is further a catalyst comprising a refractory inorganic material carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and one or more catalytically reactive metals deposited on said carrier. There is also provided a catalyst suitable for the vapor phase production of alkylene oxide from olefins and oxygen comprising an alumina-based carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and catalytically reactive silver deposited on said carrier.

公开(公告)号：US20080154051A1

公开(公告)日：2008-06-26

申请号：US11613741

申请日：2006-12-20

Applicant: Jeroen Willem Bolk ,  Alouisius Nicolaas Renee Bos ,  Wayne Errol Evans ,  John Robert Lockemeyer ,  Paul Michael Mcallister ,  Bernardus Franciscus Josef Marie Ramakers ,  Dominicus Maria Rekers ,  Mathias Jozef Paul Slapak

Inventor： Jeroen Willem Bolk ,  Alouisius Nicolaas Renee Bos ,  Wayne Errol Evans ,  John Robert Lockemeyer ,  Paul Michael Mcallister ,  Bernardus Franciscus Josef Marie Ramakers ,  Dominicus Maria Rekers ,  Mathias Jozef Paul Slapak

IPC: C07D301/06 ,  C07D301/10

CPC classification number: C07D301/10 ,  C07D301/06

Abstract: The present invention relates to an improved epoxidation process and an improved epoxidation reactor. The present invention makes use of a reactor which comprises a plurality of microchannels. Such process microchannels may be adapted such that the epoxidation and optionally other processes can take place in the microchannels and that they are in a heat exchange relation with channels adapted to contain a heat exchange fluid. A reactor comprising such process microchannels is referred to as a “microchannel reactor”. The invention also provides a method of installing an epoxidation catalyst in a microchannel reactor. The invention also provides a method of preparing an epoxidation catalyst. The invention also provides an epoxidation catalyst. The invention also provides a certain process for the epoxidation of an olefin and a process for the preparation of a chemical derivable from an olefin oxide. The invention also provides a microchannel reactor.

公开(公告)号：US07102022B2

公开(公告)日：2006-09-05

申请号：US10607346

申请日：2003-06-26

Applicant: Wayne Errol Evans ,  John Robert Lockemeyer ,  Dominicus Maria Rekers ,  Arend Jan Te Raa ,  Thijs Wermink

Inventor： Wayne Errol Evans ,  John Robert Lockemeyer ,  Dominicus Maria Rekers ,  Arend Jan Te Raa ,  Thijs Wermink

IPC: C07D301/10

CPC classification number: C07D301/10

Abstract: A method for the start-up of a process for the epoxidation of an olefin, which method comprises contacting a catalyst bed comprising a silver-based highly selective epoxidation catalyst, or a precursor of the catalyst comprising the silver in cationic form, with a feed comprising oxygen at a temperature of the catalyst bed above 260° C. for a period of at most 150 hours, and subsequently decreasing the temperature of the catalyst bed to a value of at most 260° C., and a process for the epoxidation of an olefin, which process, comprises contacting a catalyst bed comprising a silver-based highly selective epoxidation catalyst, or a precursor of the catalyst comprising the silver in cationic form, with a feed comprising oxygen at a temperature of the catalyst bed above 260° C. for a period of at most 150 hours, and subsequently decreasing the-temperature of the catalyst bed to a value of at most 260° C. and contacting the catalyst with the feed comprising the olefin and oxygen.

Abstract translation: 烯烃环氧化方法的启动方法，该方法包括将包含银基高选择性环氧化催化剂的催化剂床或包含阳离子形式的银的催化剂前体与进料 在催化剂床的温度高于260℃的温度下包含氧，时间为至多150小时，随后将催化剂床的温度降至至多260℃的值，以及环氧化方法 该方法包括使包含银基高选择性环氧化催化剂的催化剂床或包含阳离子形式的银的催化剂前体与包含氧的进料在催化剂床的温度高于260℃的温度下接触 最多150小时的时间，随后将催化剂床的温度降至至多260℃，并将催化剂与包含烯烃和氧气的进料接触。

公开(公告)号：US06656874B2

公开(公告)日：2003-12-02

申请号：US09805317

申请日：2001-03-13

Applicant: John Robert Lockemeyer

Inventor： John Robert Lockemeyer

IPC: B01J2350

CPC classification number: B01J23/66 ,  B01J23/50 ,  B01J37/0201 ,  B01J37/06 ,  C07D301/10 ,  Y02P20/52

Abstract: This invention relates to a process for depositing one or more catalytically reactive metals on a carrier, said process comprising selecting a carrier and depositing a catalytically effective amount of one or more catalytically reactive metals on the carrier, the deposition effected by submersing the carrier in an impregnation solution wherein the hydrogen ion activity of the impregnation solution has been lowered. The invention further relates to catalysts made from the process.