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74 条记录 (耗时 0.031 秒)

    Method of making block copolymers by solid state polymerization
    31.
    发明授权
    Method of making block copolymers by solid state polymerization 有权
    通过固态聚合制备嵌段共聚物的方法

    公开(公告)号：US06960641B2

    公开(公告)日：2005-11-01

    申请号：US10743241

    申请日：2003-12-22

    申请人： Gregory Allen O'Neil ,  James Day ,  Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Patrick Joseph McCloskey ,  Paul Michael Smigelski, Jr.

    发明人： Gregory Allen O'Neil ,  James Day ,  Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Patrick Joseph McCloskey ,  Paul Michael Smigelski, Jr.

    IPC分类号： C08G81/00 ,  C08G63/64 ,  C08G63/80 ,  C08G64/00

    CPC分类号： C08G63/64 ,  C08G63/80

    摘要： A method of preparing block copolymers by solid state polymerization is described. A mixture of a partially crystalline polycarbonate having activated terminal aryloxy groups, for example terminal methyl salicyl groups, when heated together with an oligomeric polyester having reactive terminal hydroxy groups under solid state polymerization conditions affords block copolymers. The activated terminal aryloxy groups play a key role in preserving the block lengths of the starting materials. A control sample in which the partially crystalline polycarbonate lacks activated terminal aryloxy groups, for example polycarbonates substituted by phenol, affords a much lower molecular weight, more highly randomized copolymer product. The product block copolymers are useful as “weatherable” plastic materials.

    摘要翻译： 描述了通过固态聚合制备嵌段共聚物的方法。 当在固态聚合条件下与具有反应性末端羟基的低聚聚酯一起加热时，具有活化的末端芳氧基的部分结晶的聚碳酸酯，例如末端甲基水杨酸酯的混合物得到嵌段共聚物。 活化的末端芳氧基在保留原料的块长度方面起关键作用。 其中部分结晶聚碳酸酯缺乏活化的末端芳氧基的对照样品，例如被苯酚取代的聚碳酸酯，得到低得多的分子量，更高度随机的共聚物产物。 产品嵌段共聚物可用作“耐候性”塑料材料。

    Weatherable, thermostable polymers having improved flow composition
    32.
    发明授权
    Weatherable, thermostable polymers having improved flow composition 有权
    具有改善流动组成的耐候性耐热聚合物

    公开(公告)号：US06861482B2

    公开(公告)日：2005-03-01

    申请号：US10307873

    申请日：2002-12-02

    申请人： Daniel Joseph Brunelle ,  Tiberiu Mircea Siclovan ,  Paul Dean Sybert

    发明人： Daniel Joseph Brunelle ,  Tiberiu Mircea Siclovan ,  Paul Dean Sybert

    IPC分类号： B32B27/06 ,  B32B27/18 ,  C08G63/64 ,  C08G63/676 ,  C08G63/695 ,  C08F8/04 ,  C08G63/00

    CPC分类号： B32B27/06 ,  B32B27/18 ,  C08G63/64 ,  C08G63/676 ,  C08G63/6956 ,  Y10T428/31565

    摘要： The present invention describes the incorporation of several types of soft-block materials into resorcinol phthalate-co-polycarbonate polymers. In preferred embodiments, the soft-block materials contain aliphatic moieties or silicones as flexibilizing units. Several methods of incorporation into the copolymer structure are described including co-reaction of diols with iso/terephthaloyl chloride, replacement of the normal chainstopper with a p-alkylphenol, replacement of a portion of the bisphenol A with an aliphatic ester-bisphenol, and co-reaction of aliphatic diacid chlorides. The polymers of the present invention have good flow characteristics at temperatures generally used for coating, and have good thermostability and weatherability.

    摘要翻译： 本发明描述了将几种类型的软嵌段材料并入间苯二酚邻苯二甲酸酯共共聚物聚合物中。 在优选的实施方案中，软嵌段材料含有脂族部分或硅氧烷作为柔性单元。 描述了掺入共聚物结构的几种方法，包括二醇与异对苯二甲酰氯的共反应，正链链断裂与对烷基苯酚的取代，双酚A的一部分与脂肪族酯 - 双酚的取代，以及共 - 脂肪族二酸氯化物的反应。 本发明的聚合物在通常用于涂布的温度下具有良好的流动特性，并具有良好的热稳定性和耐候性。

    Phase transfer catalyzed method for prepared oxybisphthalic compounds
    33.
    发明授权
    Phase transfer catalyzed method for prepared oxybisphthalic compounds 有权
    相转移催化方法制备的含氧双苯二甲酸酯化合物

    公开(公告)号：US6028203A

    公开(公告)日：2000-02-22

    申请号：US210707

    申请日：1998-12-14

    申请人： Daniel Joseph Brunelle ,  Thomas Link Guggenheim

    发明人： Daniel Joseph Brunelle ,  Thomas Link Guggenheim

    IPC分类号： B01J31/02 ,  B01J31/04 ,  C07B61/00 ,  C07D209/48 ,  C07D307/89 ,  C07D405/00 ,  C07D209/02 ,  C07D307/77

    CPC分类号： C07D307/89

    摘要： Oxybisphthalic compounds such as 4,4'-oxybis(N-methylphthalimide) and 4,4'-oxybis(phthalic anhydride) are prepared from the corresponding nitro- or halo-substituted phthalic compounds by reaction with an alkanoate or carbonate salt in a non-polar solvent and in the presence of a hexaalkylguanidinium salt as phase transfer catalyst. A carboxylic acid such as 4-chlorobenzoic acid may be used as an additional catalyst. Reaction rates and yields are higher than with other phase transfer catalysts.

    摘要翻译： 由相应的硝基 - 或卤素取代的邻苯二甲酸化合物通过与非酸性的烷基酯或碳酸盐反应制备4,4'-氧双（4-甲基邻苯二甲酰亚胺）和4,4'-氧双（邻苯二甲酸酐） 在六烷基胍鎓盐作为相转移催化剂存在下进行。 可以使用羧酸如4-氯苯甲酸作为另外的催化剂。 反应速率和产率高于其他相转移催化剂。

    Copolyetherimides and phase catalyzed method for their preparation
    35.
    发明授权
    Copolyetherimides and phase catalyzed method for their preparation 失效
    共聚酰亚胺及其相催化方法制备

    公开(公告)号：US5908915A

    公开(公告)日：1999-06-01

    申请号：US944276

    申请日：1997-10-06

    申请人： Daniel Joseph Brunelle

    发明人： Daniel Joseph Brunelle

    IPC分类号： C08G64/12 ,  C08G73/02 ,  C08G73/10 ,  C08G73/16 ,  C08G8/02 ,  C08G69/26 ,  C08G73/00 ,  C08G75/00

    CPC分类号： C08G73/1021 ,  C08G73/1042 ,  C08G73/105 ,  C08G73/16

    摘要： Copolyetherimides are prepared by the reaction of an alkali metal salt of a dihydroxyaromatic compound with a bis(substituted phthalimide) and a third compound which may be a substituted aromatic ketone or sulfone or a macrocyclic polycarbonate or polyarylate oligomer. The reaction takes place the in presence of a solvent and a phase transfer catalyst having high thermal stability, such as a hexaalkylguanidinium halide. Random or block copolymers may be obtained, depending on the reaction conditions.

    摘要翻译： 共聚酰亚胺通过二羟基芳族化合物的碱金属盐与双（取代的邻苯二甲酰亚胺）和可以是取代的芳族酮或砜或大环聚碳酸酯或多芳基化合物低聚物的第三化合物的反应制备。 反应在溶剂和具有高热稳定性的相转移催化剂存在下进行，例如六烷基卤化镓。 取决于反应条件，可以获得无规或嵌段共聚物。

    Titanate esters useful as polymerization initiators for macrocylic polyester oligomers
    36.
    发明授权
    Titanate esters useful as polymerization initiators for macrocylic polyester oligomers 失效
    可用作大分子聚酯低聚物聚合引发剂的钛酸酯

    公开(公告)号：US5661214A

    公开(公告)日：1997-08-26

    申请号：US695155

    申请日：1996-08-05

    申请人： Daniel Joseph Brunelle ,  Judith Ann Serth-Guzzo

    发明人： Daniel Joseph Brunelle ,  Judith Ann Serth-Guzzo

    IPC分类号： C08G63/85 ,  C08K3/10 ,  C08G63/82

    CPC分类号： C08G63/85

    摘要： Macrocyclic polyester oligomer compositions are polymerized to high molecular weight polyesters by heating with a titanate ester composition comprising moieties having oxygen or nitrogen chelated with a titanium atom or having two titanium atom connected by alkylene ester units. Depending on the chemical nature of the initiator, the polymerization reaction may be extremely rapid as desired for structural reaction injection molding, or may have an induction period as desired for resin transfer molding.

    摘要翻译： 将大环聚酯低聚物组合物通过用包含与钛原子螯合的氧或氮螯合的钛酸酯组合物或通过亚烷基酯单元连接的两个钛原子加热而聚合成高分子量聚酯。 取决于引发剂的化学性质，聚合反应可以如结构反应注射成型所需的那样非常快，或者可以具有树脂传递模塑所需的诱导期。

    Phase transfer catalyzed method for preparation of polyetherimides
    37.
    发明授权
    Phase transfer catalyzed method for preparation of polyetherimides 有权
    相转移催化聚醚酰亚胺的制备方法

    公开(公告)号：US07714095B2

    公开(公告)日：2010-05-11

    申请号：US11363681

    申请日：2006-02-28

    申请人： Daniel Joseph Brunelle ,  Havva Yagci Acar ,  Farid Fouad Khouri ,  Thomas Link Guggenheim ,  David Winfield Woodruff ,  Norman Enoch Johnson

    发明人： Daniel Joseph Brunelle ,  Havva Yagci Acar ,  Farid Fouad Khouri ,  Thomas Link Guggenheim ,  David Winfield Woodruff ,  Norman Enoch Johnson

    IPC分类号： C08G73/00 ,  C08G73/10 ,  C08G8/02 ,  C08G14/00

    CPC分类号： C08G73/12 ,  C08G73/121 ,  C08G73/124

    摘要： Polyether polymers, such as polyetherimides, are prepared by the reaction of a dihydroxy-substituted aromatic hydrocarbon alkali metal salt, such as bisphenol A disodium salt, with a bis(N-(chlorophthalimido))aromatic compound, such as 1,3- and/or 1,4-bis(N-(4-chlorophthalimido))benzene, in a solvent such as o-dichlorobenzene and in the presence of a phase transfer catalyst such as a hexaalkylguanidinium chloride. Several embodiments may be employed to improve the method. They comprise employing substantially dry reagents, employing a high solids level in solvent, beginning with an excess of bis(N-(chlorophthalimido))-aromatic compound and incrementally adding alkali metal salt, employing alkali metal salt of small particle size, and using reagents of high purity.

    摘要翻译： 聚醚聚合物如聚醚酰亚胺通过二羟基取代的芳族烃碱金属盐如双酚A二钠盐与双（N-（氯代邻苯二甲酰亚胺基））芳族化合物如1,3-和 /或1,4-双（N-（4-氯邻苯二甲酰亚氨基））苯，在溶剂如邻二氯苯中，并在相转移催化剂如六烷基氯化the存在下进行。 可以采用几个实施例来改进该方法。 它们包括使用基本上干的试剂，在溶剂中使用高固体含量，从过量的双（N-（氯代邻苯二甲酰亚胺基）） - 芳族化合物开始，并逐渐加入碱金属盐，使用小粒径的碱金属盐，并使用试剂 的高纯度。