公开(公告)号：US08227370B2

公开(公告)日：2012-07-24

申请号：US12943512

申请日：2010-11-10

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/60 ,  C08F2/00 ,  B01J31/00

CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F4/651

Abstract: A catalyst system containing (a) a solid catalyst component containing a titanium halide, a magnesium halide, a first internal electron donor compound, and a second internal electron donor compound, (b) an organoaluminum compound, and (c) an external electron donor compound is disclosed. The first internal electron donor compound contains at least one ether group and at least one ketone group. The second internal electron donor compound is a 1,8-naphthyl diester compound. Methods of polymerizing or copolymerizing alpha-olefins using the catalyst system also are disclosed.

Abstract translation: 一种催化剂体系，其包含（a）含有卤化钛，卤化镁，第一内部电子给体化合物和第二内部电子给体化合物的固体催化剂组分，（b）有机铝化合物和（c）外部电子给体 公开了化合物。 第一内给电子体化合物含有至少一个醚基和至少一个酮基。 第二内电子给体化合物是1,8-萘基二酯化合物。 还公开了使用催化剂体系聚合或共聚α-烯烃的方法。

公开(公告)号：US20110294970A1

公开(公告)日：2011-12-01

申请号：US12786701

申请日：2010-05-25

Applicant: Main Chang ,  Thomas Garoff

Inventor： Main Chang ,  Thomas Garoff

IPC: C08F4/76 ,  B01J31/14 ,  C07F7/18

CPC classification number: C08F110/02 ,  C08F2500/12 ,  C08F4/651 ,  C08F4/6565

Abstract: The present invention relates to solid catalyst components comprising a reaction product of a titanium compound, a magnesium compound, an alcohol, an aluminum alkoxide, a siloxane mixture, and a maleate derivative; and catalyst systems comprising the solid catalyst components and organoaluminum compounds. The present invention also relates to methods of making the solid catalyst components and the catalyst systems, and methods of polymerizing or copolymerizing ethylene using the catalyst systems.

Abstract translation: 本发明涉及包含钛化合物，镁化合物，醇，醇铝，硅氧烷混合物和马来酸衍生物的反应产物的固体催化剂组分; 和包含固体催化剂组分和有机铝化合物的催化剂体系。 本发明还涉及制备固体催化剂组分和催化剂体系的方法，以及使用催化剂体系聚合或共聚乙烯的方法。

公开(公告)号：US20110152481A1

公开(公告)日：2011-06-23

申请号：US12655007

申请日：2009-12-21

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/50 ,  B01J31/14

CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F2500/12 ,  C08F4/651 ,  C08F4/6494

Abstract: The present invention relates to catalyst systems containing solid catalyst components comprising titanium, magnesium, halogen and a 1,8-naphthyl diaryloate internal electron donor compound; organoaluminum compounds and alkyl benzoate derivatives as external electron donors. The present invention also relates to methods of making the catalyst systems, and methods of polymerizing or copolymerizing alpha-olefins using the catalyst systems.

Abstract translation: 本发明涉及含有固体催化剂组分的催化剂体系，其中包括钛，镁，卤素和1,8-萘基二异辛烯内电子给体化合物; 有机铝化合物和苯甲酸烷基酯衍生物作为外部电子给体。 本发明还涉及制备催化剂体系的方法，以及使用催化剂体系聚合或共聚α-烯烃的方法。

公开(公告)号：US07700513B2

公开(公告)日：2010-04-20

申请号：US11753471

申请日：2007-05-24

Applicant: Zhidong Zhu ,  Main Chang

Inventor： Zhidong Zhu ,  Main Chang

IPC: C08F4/02 ,  B01J31/38

CPC classification number: C08F110/06 ,  C08F210/16 ,  C08F4/6545 ,  C08F4/651 ,  C08F4/025 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/24 ,  C08F210/06

Abstract: Disclosed are catalyst systems and methods of making the catalyst systems for the polymerization of an olefin containing a solid titanium catalyst component containing an inorganic titanium compound, a magnesium alcohol adduct made from an inorganic magnesium compound and an alcohol, and a porous support having at least one of a certain specific surface area, a certain pore volume, and a certain median particle size. The catalyst system may further contain an organoaluminum compound and optionally an organosilicon compound. Also disclosed are methods of making polyolefins.

Abstract translation: 公开了催化剂体系和制备用于聚合含有含有无机钛化合物的固体钛催化剂组分的烯烃的催化剂体系，由无机镁化合物和醇制成的镁醇加合物的催化剂体系和至少具有至少 一定的比表面积，一定的孔体积和一定的中值粒径之一。 催化剂体系还可以含有有机铝化合物和任选的有机硅化合物。 还公开了制备聚烯烃的方法。

公开(公告)号：US06977287B2

公开(公告)日：2005-12-20

申请号：US10602177

申请日：2003-06-24

Applicant: Pawan Kumar Agarwal ,  Weiqing Weng ,  Aspy K. Mehta ,  Armenag H. Dekmezian ,  Main Chang ,  Rajan K. Chudgar ,  Christopher R. Davey ,  Chon-Yie Lin ,  Galen C. Richeson ,  Palanisamy Arjunan ,  Olivier Jean Georjon

Inventor： Pawan Kumar Agarwal ,  Weiqing Weng ,  Aspy K. Mehta ,  Armenag H. Dekmezian ,  Main Chang ,  Rajan K. Chudgar ,  Christopher R. Davey ,  Chon-Yie Lin ,  Galen C. Richeson ,  Palanisamy Arjunan ,  Olivier Jean Georjon

IPC: C08F4/659 ,  C08F4/6592 ,  C08F110/06 ,  C08F210/06 ,  C08L23/14 ,  C08L23/16 ,  C08F236/20

CPC classification number: C08F4/65927 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F110/06 ,  C08F210/06 ,  C08L23/14 ,  C08L23/145 ,  C08L23/16 ,  C08L2666/04 ,  C08F236/20 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/26

Abstract: The co-polymerization reaction of one or more olefin monomers, such as propylene, with α,ω-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of α,ω-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115° C. to 135° C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations. Desirably, the melting point range of one of the crystalline populations is distinguishable from the melting point range of another crystalline population by a temperature range of from 1° C. to 8° C. More desirably, one of the crystalline populations has a melting point in the range from 152° C. to 158° C. and another crystalline population has a melting point in the range from 142° C. to 148° C.

Abstract translation: 提供一种或多种烯烃单体如丙烯与α，ω-二烯单元和所得共聚物的共聚反应。 更具体地说，共聚物可以具有90至99.999重量％的烯烃和0.001至2.000重量％的α，ω-二烯。 该共聚物的重均分子量可以在50,000至2,000,000范围内，结晶温度在115℃至135℃的范围内，熔体流动速率在0.1dg / min至100dg / 分钟 这些共聚物可以用于各种应用中，其制品包括例如膜，纤维，例如纺粘和熔喷纤维，织物如无纺织物和模塑制品。 该共聚物可进一步包括至少两个结晶群。 理想地，一种结晶群体的熔点范围与另一结晶群体的熔点范围可以区别在1℃至8℃的温度范围内。更期望的是，一个结晶群体具有熔点 在152℃至158℃的范围内，另一结晶群的熔点范围为142℃至148℃。

公开(公告)号：US20050164873A1

公开(公告)日：2005-07-28

申请号：US10766644

申请日：2004-01-28

Applicant: Zhidong Zhu ,  Main Chang

Inventor： Zhidong Zhu ,  Main Chang

IPC: C08F10/00 ,  C08F110/06 ,  B01J31/00

CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F4/6465 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

Abstract: Disclosed are catalyst systems and methods of making the catalyst systems/supports for the polymerization of an olefin containing a solid titanium catalyst component having a substantially spherical shape and containing a titanium compound and a support made from a magnesium compound and an alkyl silicate. The catalyst system may further contain an organoaluminum compound and an organosilicon compound. Also disclosed are methods of making an impact copolymer involving polymerizing an olefin to provide a polyolefin matrix and polymerizing a polyolefin rubber using a solid titanium catalyst component containing a titanium compound and a support made from a magnesium compound and an alkyl silicate.

Abstract translation: 公开了催化剂体系和制备催化剂体系/载体的方法，所述催化剂体系/载体用于聚合具有基本上球形的固体钛催化剂组分的烯烃，并含有钛化合物和由镁化合物和烷基硅酸酯制成的载体。 催化剂体系可以进一步含有有机铝化合物和有机硅化合物。 还公开了制备包含使烯烃聚合以提供聚烯烃基质并使用含有钛化合物的固体钛催化剂组分和由镁化合物和烷基硅酸酯制成的载体聚合聚烯烃橡胶的冲击共聚物的方法。

公开(公告)号：US06734267B2

公开(公告)日：2004-05-11

申请号：US10430962

申请日：2003-05-06

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F444

CPC classification number: C08F10/00 ,  C08F4/61912 ,  C08F4/61916 ,  C08F110/02 ,  Y10S526/943

Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported metallocene catalyst formed by vacuum or pressurized impregnation.

Abstract translation: 本发明通常涉及用于聚合烯烃的负载型催化剂体系。 支持本发明的催化剂的方法提供了通过真空或加压浸渍形成的负载金属茂催化剂。

公开(公告)号：US06605560B1

公开(公告)日：2003-08-12

申请号：US08816466

申请日：1997-03-13

Applicant: Main Chang

Inventor： Main Chang

IPC: B01J3100

CPC classification number: C08F10/00 ,  C08F4/61912 ,  C08F4/61916 ,  C08F110/02 ,  Y10S526/943

Abstract: This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported metallocene catalyst formed by vacuum or pressurized impregnation.

公开(公告)号：US06395847B2

公开(公告)日：2002-05-28

申请号：US09443723

申请日：1999-11-19

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F444

CPC classification number: C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  C08F36/04 ,  C08F110/06 ,  Y10S526/901 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/642

Abstract: The invention is directed to organometallic catalysts prepared by a process comprising a) combining nucleophilic group-containing particulate support material with an arylboron or arylaluminum Lewis acid compound in the presence of a Lewis base compound; b) contacting the product of a) with a trialkylaluminum compound before combining said product with a metal precursor compound capable of activation for olefin polymerization by said product a); and, c) combining the product of b) with said metal precursor compound. These catalyst compositions are suitable for addition reactions of ethylenically and acetylenically unsaturated monomers. The invention includes a polymerization process of combining or contacting olefinically unsaturated monomers with the invention catalyst composition. Use of the invention catalyst to polymerize &agr;-olefins is exemplified.

Abstract translation: 本发明涉及通过包括以下步骤的方法制备的有机金属催化剂：a）在路易斯碱化合物存在下，将含亲核基团的颗粒载体材料与芳基硼烷或芳基铝路易斯酸化合物结合; b）在将所述产物与能够由所述产物a）进行烯烃聚合活化的金属前体化合物组合之前，将a）的产物与三烷基铝化合物接触; 和c）将b）的产物与所述金属前体化合物组合。 这些催化剂组合物适用于烯属和炔属不饱和单体的加成反应。 本发明包括将烯属不饱和单体与本发明的催化剂组合物组合或接触的聚合方法。 使用本发明的催化剂来聚合α-烯烃。

公开(公告)号：US5238892A

公开(公告)日：1993-08-24

申请号：US898255

申请日：1992-06-15

Applicant: Main Chang

Inventor： Main Chang

IPC: C08F4/642 ,  C08F4/02 ,  C08F4/60 ,  C08F4/602 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/656 ,  C08F4/658 ,  C08F4/6592 ,  C08F10/00

CPC classification number: C08F10/00 ,  C08F4/63912 ,  C08F4/63916 ,  C08F4/6392 ,  Y10S526/943

Abstract: This invention relates to a supported catalyst composition useful in the polymerization of olefins and to a method for its production. The invention particularly relates to the use of undehydrated silica gel containing from about 6 to about 20 percent by weight adsorbed water as the catalyst support material. The catalyst is formed by first reacting a trialkylaluminum compound with a metallocene, and subsequently reacting the resulting material with the undehydrated silica gel. The resulting supported metallocene-alumoxane catalyst has a level of activity comparable to that of conventionally made supported catalysts which are achieved at active metal loadings which are reduced from the loadings used in the previously known metallocene-alumoxane catalysts by at least 20%, and preferably 50%.

Abstract translation: 本发明涉及可用于烯烃聚合的负载型催化剂组合物及其制备方法。 本发明特别涉及含有约6至约20重量％吸附水作为催化剂载体材料的未脱水硅胶的用途。 催化剂通过首先使三烷基铝化合物与金属茂反应形成，然后使所得材料与未脱水硅胶反应。 得到的负载型茂金属 - 铝氧烷催化剂具有与常规制备的负载型催化剂相当的活性水平，其活性金属负荷达到，其从先前已知的金属茂 - 铝氧烷催化剂中使用的负载量减少至少20％，优选 50％。