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公开(公告)号：US08791451B2
公开(公告)日：2014-07-29
申请号：US12399006
申请日：2009-03-05
IPC分类号： H01L51/50 , H01L51/54 , H01L51/56 , C08L25/18 , C08L25/00 , H01L51/00 , C08L35/00 , C08L65/00
CPC分类号： C08L29/02 , C08G2261/512 , C08L25/00 , C08L25/18 , C08L35/00 , C08L65/00 , H01L51/0036 , H01L51/004 , H01L51/5088 , Y02E10/549 , Y10S362/80 , C08L2666/14 , C08L2666/04
摘要： A composition comprising: at least one conjugated polymer, at least one second polymer comprising repeat units represented by: (I) optionally, —[CH2—CH(Ph-OH)]— and (II) —[CH2—CH(Ph-OR)]— wherein Ph is a phenyl ring and R comprises a fluorinated group, an alkyl group, an alkylsulfonic acid group, an alkylene oxide group, or a combination thereof is described. Other polymers can be used as second polymer including polymers comprising modified naphthol side groups. The composition can be used in hole injection and hole transport layers for organic electronic devices. Increased lifetime and better processability can be achieved. Versatility with useful OLED emitters can be achieved. Ink formulations can be adapted for ink jet printing. The conjugated polymer can be a polythiophene. Applications include OLEDs and OPVs.
摘要翻译： 至少一种共轭聚合物，至少一种第二聚合物，其包含由以下所示的重复单元：（I）任选地， - [CH 2 -CH（Ph-OH）] - 和（II） - [CH 2 -CH（Ph- OR）] - 其中Ph是苯环，R包括氟化基团，烷基，烷基磺酸基团，烯化氧基团或其组合。 其它聚合物可以用作包含改性萘酚侧基的聚合物的第二聚合物。 该组合物可用于有机电子器件的空穴注入和空穴传输层。 可以实现寿命延长和加工性能。 可以实现具有有用的OLED发射体的多功能性。 油墨配方可适用于喷墨印刷。 共轭聚合物可以是聚噻吩。 应用包括OLED和OPV。
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32.发明授权Organic electronic devices and polymers, including photovoltaic cells and diketone-based and diketopyrrolopyrrole-based polymers 失效有机电子器件和聚合物，包括光伏电池和基于二酮和二酮吡咯并吡咯的聚合物公开(公告)号：US08691931B2
公开(公告)日：2014-04-08
申请号：US12874137
申请日：2010-09-01
申请人： Christopher T. Brown , Christophe René Gaston Grenier , Chad Landis , Elena E. Sheina , Ting Xu
发明人： Christopher T. Brown , Christophe René Gaston Grenier , Chad Landis , Elena E. Sheina , Ting Xu
IPC分类号： C08G14/10
CPC分类号： C08L65/00 , C07D487/04 , C07D495/04 , C07D519/00 , C07F7/0816 , C08G61/12 , C08G61/126 , C08G2261/124 , C08G2261/18 , C08G2261/226 , C08G2261/228 , C08G2261/3223 , C08G2261/334 , C08G2261/344 , C08G2261/364 , C08G2261/414 , C09B57/004 , C09B69/008 , C09B69/109 , C09D165/00 , H01L51/0036 , H01L51/0043 , H01L51/0069 , H01L51/0077 , H01L51/4253 , Y02E10/549 , Y10S428/917
摘要： Polymers which can be used in p-type materials for organic electronic devices and photovoltaic cells. Compounds, monomers, dimers, trimers, and polymers comprising: wherein A1 and A2 each independently comprise a fused ring system comprising at least two fused rings directly covalently linked to the pyrrole rings. Good photovoltaic efficiency and lifetime can be achieved. The R group can provide solubility, environmental stability, and fine tuning of spectroscopic and/or electronic properties. Different polymer microstructures can be prepared which encourage multiple band gaps and broad and strong absorptions. The carbonyl can interact with adjacent thiophene rings to provide backbone with rigidity, induce planarity, and reduce and/or eliminate intramolecular chain twisting defects.
摘要翻译： 可用于有机电子器件和光伏电池的p型材料的聚合物。 化合物，单体，二聚体，三聚体和聚合物，其包含：其中A1和A2各自独立地包含稠环系统，其包含直接共价连接到吡咯环上的至少两个稠合环。 可以实现良好的光伏效率和寿命。 R基团可以提供光谱和/或电子性质的溶解度，环境稳定性和微调。 可以制备不同的聚合物微结构，其可以鼓励多个带隙和宽而强的吸收。 羰基可以与相邻的噻吩环相互作用以提供具有刚性，诱导平面性的主链，并减少和/或消除分子内链扭曲缺陷。
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公开(公告)号：US20120083070A1
公开(公告)日：2012-04-05
申请号：US13316324
申请日：2011-12-09
IPC分类号： H01L51/40
CPC分类号： H01L51/0036 , C08L65/00 , C08L65/02 , C09D165/00 , C09D165/02 , H01L51/005 , H01L51/006 , H01L51/008 , H01L51/5052 , H01L51/5056 , H01L51/5088 , Y02E10/549 , Y02P70/521 , C08L2666/22
摘要： Compositions for use in hole transporting layers (HTLs) or hole injection layers (HILs) are provided, as well as methods of making the compositions and devices fabricated from the compositions. OLED devices can be made. The compositions comprise at least one conductive conjugated polymer, at least one semiconducting matrix component that is different from the conductive conjugated polymer, and an optional dopant, and are substantially free of an insulating matrix component.
摘要翻译： 提供了用于空穴传输层（HTL）或空穴注入层（HIL）的组合物，以及制备由组合物制备的组合物和装置的方法。 可以制造OLED器件。 组合物包含至少一种导电共轭聚合物，至少一种不同于导电共轭聚合物的半导体基质组分和任选的掺杂剂，并且基本上不含绝缘基质组分。
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34.发明申请ORGANIC ELECTRONIC DEVICES AND POLYMERS, INCLUDING PHOTOVOLTAIC CELLS AND DIKETONE-BASED AND DIKETOPYRROLOPYRROLE-BASED POLYMERS 失效有机电子器件和聚合物，包括光伏电池和基于二酮和基于二烯丙基的聚合物公开(公告)号：US20110114184A1
公开(公告)日：2011-05-19
申请号：US12874137
申请日：2010-09-01
申请人： Christopher T. Brown , Christophe René Gaston Grenier , Chad Landis , Elena E. Sheina , Ting Xu
发明人： Christopher T. Brown , Christophe René Gaston Grenier , Chad Landis , Elena E. Sheina , Ting Xu
IPC分类号： H01L31/0256 , C08F28/06 , C07D497/22
CPC分类号： C08L65/00 , C07D487/04 , C07D495/04 , C07D519/00 , C07F7/0816 , C08G61/12 , C08G61/126 , C08G2261/124 , C08G2261/18 , C08G2261/226 , C08G2261/228 , C08G2261/3223 , C08G2261/334 , C08G2261/344 , C08G2261/364 , C08G2261/414 , C09B57/004 , C09B69/008 , C09B69/109 , C09D165/00 , H01L51/0036 , H01L51/0043 , H01L51/0069 , H01L51/0077 , H01L51/4253 , Y02E10/549 , Y10S428/917
摘要： Polymers which can be used in p-type materials for organic electronic devices and photovoltaic cells. Compounds, monomers, dimers, trimers, and polymers comprising: wherein A1 and A2 each independently comprise a fused ring system comprising at least two fused rings directly covalently linked to the pyrrole rings. Good photovoltaic efficiency and lifetime can be achieved. The R group can provide solubility, environmental stability, and fine tuning of spectroscopic and/or electronic properties. Different polymer microstructures can be prepared which encourage multiple band gaps and broad and strong absorptions. The carbonyl can interact with adjacent thiophene rings to provide backbone with rigidity, induce planarity, and reduce and/or eliminate intramolecular chain twisting defects.
摘要翻译： 可用于有机电子器件和光伏电池的p型材料的聚合物。 化合物，单体，二聚体，三聚体和聚合物，其包含：其中A1和A2各自独立地包含稠环系统，其包含直接共价连接到吡咯环上的至少两个稠合环。 可以实现良好的光伏效率和寿命。 R基团可以提供光谱和/或电子性质的溶解度，环境稳定性和微调。 可以制备不同的聚合物微结构，其可以鼓励多个带隙和宽而强的吸收。 羰基可以与相邻的噻吩环相互作用以提供具有刚性，诱导平面性的主链，并减少和/或消除分子内链扭曲缺陷。
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公开(公告)号：US07368624B2
公开(公告)日：2008-05-06
申请号：US10812692
申请日：2004-03-30
摘要： A process for forming an aryl-aryl bond comprises the step of reacting an arene hydrocarbon compound with either (1) an organic oxidant selected from the group consisting of a quinone, a quinone imine, a quinone diimine, and a nitroarene, or (2) an oxidizing salt selected from the group consisting of a triarylaminium salt, an oxonium salt, and a nitrosium salt, or (3) a hypervalent iodine compound, each in the presence of a Brönsted or Lewis acid.
摘要翻译： 形成芳基 - 芳基键的方法包括使芳族烃化合物与（1）选自醌，醌亚胺，醌二亚胺和硝基芳烃的有机氧化剂反应的步骤，或（2） ）选自三芳基铵盐，氧鎓盐和亚硝酸盐的氧化盐，或（3）多价碘化合物，各自在布朗斯台德或路易斯酸存在下。
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公开(公告)号：US06788753B1
公开(公告)日：2004-09-07
申请号：US09570371
申请日：2000-05-12
申请人： Christopher T. Brown
发明人： Christopher T. Brown
IPC分类号： H04L700
CPC分类号： G11B27/3027 , G11B20/14 , G11B20/18 , G11B2020/1476 , H04J3/06
摘要： A timing circuit used in reading disc media or other dada includes multiple sync detection circuits. In the event that an active sync detection circuit fails to detect sync signals within predefined parameters, a different one of the sync detection circuits searches for a sync pattern. Uniquely definable sequences of sync patterns are used to determine a position of sync patterns within a sector of data.
摘要翻译： 用于读取盘媒体或其他数据的定时电路包括多个同步检测电路。 在活动同步检测电路未能检测到预定义参数内的同步信号的情况下，不同的同步检测电路搜索同步模式。 使用唯一可定义的同步模式序列来确定数据扇区内同步模式的位置。
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37.发明授权Organic electronic devices and polymers, including photovoltaic cells and diketone-based polymers 有权有机电子器件和聚合物，包括光伏电池和基于二酮的聚合物公开(公告)号：US08968885B2
公开(公告)日：2015-03-03
申请号：US12874163
申请日：2010-09-01
申请人： Christopher T. Brown , Christophe René Gaston Grenier , Chad Landis , Elena E. Sheina , Atta Gueye
发明人： Christopher T. Brown , Christophe René Gaston Grenier , Chad Landis , Elena E. Sheina , Atta Gueye
IPC分类号： H01L51/54 , H01L51/46 , C08F228/06 , C08L41/00 , C08L65/00 , C07D487/04 , C07D495/04 , C07D519/00 , C07F7/08 , C08G61/12 , C09D165/00 , H01L51/00 , C09B57/00 , C09B69/00 , C09B69/10 , H01L51/42
CPC分类号： C08L65/00 , C07D487/04 , C07D495/04 , C07D519/00 , C07F7/0816 , C08G61/12 , C08G61/126 , C08G2261/124 , C08G2261/18 , C08G2261/226 , C08G2261/228 , C08G2261/3223 , C08G2261/334 , C08G2261/344 , C08G2261/364 , C08G2261/414 , C09B57/004 , C09B69/008 , C09B69/109 , C09D165/00 , H01L51/0036 , H01L51/0043 , H01L51/0069 , H01L51/0077 , H01L51/4253 , Y02E10/549 , Y10S428/917
摘要： Polymers which can be used in p-type materials for organic electronic devices and photovoltaic cells. Compounds, monomers, dimers, trimers, and polymers comprising: Good photovoltaic efficiency and lifetime can be achieved. The R group can provide solubility, environmental stability, and fine tuning of spectroscopic and/or electronic properties. Different polymer microstructures can be prepared which encourage multiple band gaps and broad and strong absorptions. The carbonyl can interact with adjacent thiophene rings to provide backbone with rigidity, induce planarity, and reduce and/or eliminate intramolecular chain twisting defects. Polymers comprising benzodithiophene and/or benzothiadiazole structures can show particularly high performance.
摘要翻译： 可用于有机电子器件和光伏电池的p型材料的聚合物。 化合物，单体，二聚体，三聚体和聚合物包括：可以实现良好的光电效率和寿命。 R基团可以提供光谱和/或电子性质的溶解度，环境稳定性和微调。 可以制备不同的聚合物微结构，其可以鼓励多个带隙和宽而强的吸收。 羰基可以与相邻的噻吩环相互作用以提供具有刚性，诱导平面性的主链，并减少和/或消除分子内链扭曲缺陷。 包含苯并二噻吩和/或苯并噻二唑结构的聚合物可表现出特别高的性能。
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公开(公告)号：US08828274B2
公开(公告)日：2014-09-09
申请号：US12606162
申请日：2009-10-26
IPC分类号： H01B1/00 , H01L29/08 , B32B9/00 , H01L51/00 , C09D11/00 , H01L51/42 , C08L79/02 , C08G73/02 , H01L51/50
CPC分类号： H01L51/0035 , C08G73/026 , C08G2261/312 , C08G2261/512 , C08L79/02 , C09D11/52 , H01L51/0004 , H01L51/0081 , H01L51/0085 , H01L51/424 , H01L51/5056 , H01L51/5088
摘要： Polymers comprising a backbone comprising at least one arylamine repeat moiety and at least one linking moiety, wherein the linking moiety does not comprise an aryl moiety. Ink formulations and organic electronic devices such as OLEDs or OPVs can be formed from the polymers and doped polymers. The polymers can be used in a hole injection layer, hole transport layer, a hole extraction layer, or as a host material in an emissive layer. Improved stability can be achieved in organic electronic devices such as OLEDs and OPVs.
摘要翻译： 包含包含至少一个芳基胺重复部分和至少一个连接部分的主链的聚合物，其中所述连接部分不包含芳基部分。 油墨配方和有机电子器件如OLED或OPV可以由聚合物和掺杂的聚合物形成。 聚合物可用于空穴注入层，空穴传输层，空穴提取层或发光层中的主体材料。 有机电子器件如OLED和OPV可以实现稳定性的提高。
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公开(公告)号：US08709291B2
公开(公告)日：2014-04-29
申请号：US13456125
申请日：2012-04-25
CPC分类号： C09D11/00 , C08G2261/1424 , C08G2261/212 , C08G2261/3223 , C08G2261/512 , C08G2261/794 , C08L25/18 , C08L65/00 , C09D11/52 , C09D129/02 , C09D181/02 , H01B1/127 , H01L51/0002 , H01L51/0035 , H01L51/0036 , H01L51/0043 , H01L51/05 , H01L51/42 , H01L51/5048 , H01L51/5056 , H01L51/5088 , Y02E10/549
摘要： Use of certain materials in hole injection layer and/or hole transport layer can improve operational lifetimes in organic devices. Polymers having fused aromatic side groups such as polyvinylnaphthol polymers can be used in conjunction with conjugated polymers. Inks can be formulated and cast as films in organic electronic devices including OLEDs, SMOLEDs, and PLEDs. One embodiment provides a composition comprising: at least one conjugated polymer, and at least one second polymer different from the conjugated polymer comprising at least one optionally substituted fused aromatic hydrocarbon side group. The substituent can be hydroxyl. Aqueous-based inks can be formulated.
摘要翻译： 在空穴注入层和/或空穴传输层中使用某些材料可以改善有机器件的使用寿命。 具有稠合芳族侧基的聚合物如聚萘并噻唑聚合物可与共轭聚合物结合使用。 油墨可以在有机电子设备（包括OLED，SMOLED和PLED）中配制和铸造成膜。 一个实施方案提供了一种组合物，其包含：至少一种共轭聚合物和至少一种不同于包含至少一个任选取代的稠合芳烃侧基的共轭聚合物的第二聚合物。 取代基可以是羟基。 可以配制水性油墨。
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公开(公告)号：US20120277367A1
公开(公告)日：2012-11-01
申请号：US13456125
申请日：2012-04-25
IPC分类号： C08L45/00
CPC分类号： C09D11/00 , C08G2261/1424 , C08G2261/212 , C08G2261/3223 , C08G2261/512 , C08G2261/794 , C08L25/18 , C08L65/00 , C09D11/52 , C09D129/02 , C09D181/02 , H01B1/127 , H01L51/0002 , H01L51/0035 , H01L51/0036 , H01L51/0043 , H01L51/05 , H01L51/42 , H01L51/5048 , H01L51/5056 , H01L51/5088 , Y02E10/549
摘要： Use of certain materials in hole injection layer and/or hole transport layer can improve operational lifetimes in organic devices. Polymers having fused aromatic side groups such as polyvinylnaphthol polymers can be used in conjunction with conjugated polymers. Inks can be formulated and cast as films in organic electronic devices including OLEDs, SMOLEDs, and PLEDs. One embodiment provides a composition comprising: at least one conjugated polymer, and at least one second polymer different from the conjugated polymer comprising at least one optionally substituted fused aromatic hydrocarbon side group. The substituent can be hydroxyl. Aqueous-based inks can be formulated.
摘要翻译： 在空穴注入层和/或空穴传输层中使用某些材料可以改善有机器件的使用寿命。 具有稠合芳族侧基的聚合物如聚萘并噻唑聚合物可与共轭聚合物结合使用。 油墨可以在有机电子设备（包括OLED，SMOLED和PLED）中配制和铸造成膜。 一个实施方案提供了一种组合物，其包含：至少一种共轭聚合物和至少一种不同于包含至少一个任选取代的稠合芳烃侧基的共轭聚合物的第二聚合物。 取代基可以是羟基。 可以配制水性油墨。
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