公开(公告)号：US06830828B2

公开(公告)日：2004-12-14

申请号：US09883734

申请日：2001-06-18

申请人： Mark E. Thompson ,  Peter Djurovich ,  Sergey Lamansky ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

发明人： Mark E. Thompson ,  Peter Djurovich ,  Sergey Lamansky ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

IPC分类号： H05B3314

CPC分类号： C07D209/86 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1092 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0042 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0062 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/0088 ,  H01L51/5016 ,  H01L51/5096 ,  H01L2251/308 ,  H05B33/14 ,  Y10S428/917

摘要： Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.

摘要翻译： 描述了有机发光器件，其中发射层包含含有发射分子的主体材料，该分子适于在跨异质结构施加电压时发光，并且发射分子选自磷光有机金属络合物，包括环金属化 铂，铱和锇络合物。 有机发光器件任选地包含激子阻挡层。 此外，通过具有式L2MX的过渡金属的有机金属络合物的发射极层获得有机发光器件的改善的电致发光效率，其中L和X是不同的二齿配体。 该配方的化合物可以比先前的方法更容易合成，并且合成选项允许将荧光分子插入磷光复合物，配体以微调发光的颜色，以及配体捕获载体。

公开(公告)号：US08426041B2

公开(公告)日：2013-04-23

申请号：US13347945

申请日：2012-01-11

申请人： Peter Djurovich ,  Jui-Yi Tsai ,  Chun Lin ,  Jason Brooks ,  Bert Alleyne ,  Mark E. Thompson ,  Peter B. MacKenzie ,  Bin Ma

发明人： Peter Djurovich ,  Jui-Yi Tsai ,  Chun Lin ,  Jason Brooks ,  Bert Alleyne ,  Mark E. Thompson ,  Peter B. MacKenzie ,  Bin Ma

IPC分类号： H01L51/54 ,  C09K11/06

CPC分类号： H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/0081 ,  H01L51/5016 ,  H01L51/5036 ,  H01L2251/308 ,  Y10S428/917

摘要： An organic light emitting device having an anode, a cathode and an organic layer disposed between the anode and the cathode is provided. In one aspect, the organic layer may be an emissive layer comprising one of the following compounds:

摘要翻译： 提供一种具有设置在阳极和阴极之间的阳极，阴极和有机层的有机发光器件。 一方面，有机层可以是包含以下化合物之一的发射层：

公开(公告)号：US07824778B2

公开(公告)日：2010-11-02

申请号：US11435210

申请日：2006-05-15

申请人： Mark E. Thompson ,  Bert Alleyne ,  Peter Djurovich

发明人： Mark E. Thompson ,  Bert Alleyne ,  Peter Djurovich

IPC分类号： H01L51/54

CPC分类号： H01L51/009 ,  H01L51/006 ,  H01L51/0071 ,  H01L51/0077 ,  H01L51/0087 ,  H01L51/5016 ,  H01L51/5036 ,  Y10S428/917

摘要： Devices are provided having an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode. The emissive layer includes an emissive material having more than one metal center. In one embodiment, first and second metal centers are independently selected from the group consisting of d7, d8, and d9 metals. A bridging ligand is coordinated to the first metal center and to the second metal center. In one embodiment, the first and second metal centers each have coordination numbers of at least 3, and more preferably each have coordination numbers of 4. In one embodiment, photoactive ligands are coordinated to the first and second metal centers. In one embodiment, there are no photoactive ligands. In one embodiment, a charge neutral bi-nuclear emissive material is provided. In one embodiment the first and metal centers have a co-facial configuration, and preferably a square planar co-facial configuration. In one embodiment, the metal centers are selected from metals having an atomic number greater than or equal to 40.

摘要翻译： 提供了具有阳极，阴极和布置在阳极和阴极之间并与之电连接的发射层的器件。 发射层包括具有多于一个金属中心的发光材料。 在一个实施方案中，第一和第二金属中心独立地选自d7，d8和d9金属。 桥连配体与第一金属中心和第二金属中心配位。 在一个实施方案中，第一和第二金属中心各自具有至少3的配位数，并且更优选地各自具有4的配位数。在一个实施方案中，光活性配体与第一和第二金属中心配位。 在一个实施方案中，不存在光活性配体。 在一个实施例中，提供电荷中性双核发射材料。 在一个实施例中，第一和金属中心具有共面配置，并且优选地是正方形平面协同配置。 在一个实施方案中，金属中心选自原子序数大于或等于40的金属。

公开(公告)号：US07011897B2

公开(公告)日：2006-03-14

申请号：US10643413

申请日：2003-08-18

申请人： Mark E. Thompson ,  Peter Djurovich ,  Raymond Kwong ,  Yeh-Jiun Tung ,  David B. Knowles ,  Jason Brooks ,  Robert W. Walters ,  Bin Ma

发明人： Mark E. Thompson ,  Peter Djurovich ,  Raymond Kwong ,  Yeh-Jiun Tung ,  David B. Knowles ,  Jason Brooks ,  Robert W. Walters ,  Bin Ma

IPC分类号： C09K11/06 ,  H05B33/14

CPC分类号： C09K11/06 ,  C07F15/004 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/185 ,  H01L51/0085 ,  H01L51/5016 ,  Y10S428/917

摘要： An organic light emitting device is provided. The device has an anode, a cathode, and an emissive layer disposed between the anode and the cathode, the emissive layer further comprising an emissive material having the structure: wherein each of the variables are defined herein.

摘要翻译： 提供有机发光装置。 该装置具有阳极，阴极和布置在阳极和阴极之间的发射层，发射层还包括具有以下结构的发射材料：其中每个变量在本文中定义。

公开(公告)号：US08574726B2

公开(公告)日：2013-11-05

申请号：US13009001

申请日：2011-01-19

申请人： Mark E. Thompson ,  Peter Djurovich ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

发明人： Mark E. Thompson ,  Peter Djurovich ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

IPC分类号： H01L51/54

CPC分类号： H01L51/0085 ,  C07D209/86 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1092 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0042 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0062 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0087 ,  H01L51/0088 ,  H01L51/5016 ,  H01L51/5096 ,  H01L2251/308 ,  Y10S428/917

摘要： Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.

公开(公告)号：US08557402B2

公开(公告)日：2013-10-15

申请号：US13205290

申请日：2011-08-08

申请人： Mark E. Thompson ,  Peter Djurovich ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

发明人： Mark E. Thompson ,  Peter Djurovich ,  Sergey Lamansky ,  Drew Murphy ,  Raymond Kwong ,  Feras Abdel-Razzaq ,  Stephen R. Forrest ,  Marc A. Baldo ,  Paul E. Burrows

IPC分类号： H01L51/54 ,  C09K11/06

CPC分类号： H01L51/0085 ,  C07D209/86 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1092 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0042 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0062 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0087 ,  H01L51/0088 ,  H01L51/5016 ,  H01L51/5096 ,  H01L2251/308 ,  Y10S428/917

摘要： Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.

公开(公告)号：US20120104378A1

公开(公告)日：2012-05-03

申请号：US13347945

申请日：2012-01-11

申请人： Peter Djurovich ,  Jui-Yi Tsai ,  Chun Lin ,  Jason Brooks ,  Bert Alleyne ,  Mark E. Thompson ,  Peter B. MacKenzie ,  Bein Ma

发明人： Peter Djurovich ,  Jui-Yi Tsai ,  Chun Lin ,  Jason Brooks ,  Bert Alleyne ,  Mark E. Thompson ,  Peter B. MacKenzie ,  Bein Ma

IPC分类号： H01L51/54 ,  C07F15/00

CPC分类号： H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/0081 ,  H01L51/5016 ,  H01L51/5036 ,  H01L2251/308 ,  Y10S428/917

摘要： An organic light emitting device having an anode, a cathode and an organic layer disposed between the anode and the cathode is provided. In one aspect, the organic layer comprises a compound having at least one zwitterionic carbon donor ligand. In another aspect, the organic layer comprises a carbene compound, including the following: In another aspect, the organic layer comprises a carbene compound, including: In another aspect, the organic layer comprises a carbene compound that includes a triazole ring and has the structure: In another aspect, the organic layer comprises a carbene compound that includes a tetrazole ring and has the structure:

摘要翻译： 提供一种具有设置在阳极和阴极之间的阳极，阴极和有机层的有机发光器件。 一方面，有机层包括具有至少一个两性离子碳供体配体的化合物。 另一方面，有机层包括卡宾化合物，其包括以下：另一方面，有机层包含卡宾化合物，其包括：另一方面，有机层包含含有三唑环的卡宾化合物，其结构 另一方面，有机层包含含有四唑环的卡宾化合物，其结构如下：

公开(公告)号：US20100007273A1

公开(公告)日：2010-01-14

申请号：US12550449

申请日：2009-08-31

申请人： Peter Djurovich ,  Jui-Yi Tsai ,  Chun Lin ,  Jason Brooks ,  Bert Alleyne ,  Mark E. Thompson ,  Peter B. MacKenzie ,  Bin Ma

发明人： Peter Djurovich ,  Jui-Yi Tsai ,  Chun Lin ,  Jason Brooks ,  Bert Alleyne ,  Mark E. Thompson ,  Peter B. MacKenzie ,  Bin Ma

IPC分类号： H01J1/63 ,  C07F15/00

CPC分类号： H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/0081 ,  H01L51/5016 ,  H01L51/5036 ,  H01L2251/308 ,  Y10S428/917

摘要： An organic light emitting device having an anode, a cathode and an organic layer disposed between the anode and the cathode is provided. In one aspect, the organic layer comprises a compound having at least one zwitterionic carbon donor ligand. In another aspect, the organic layer comprises a carbene compound, including the following: In another aspect, the organic layer comprises a carbene compound, including: In another aspect, the organic layer comprises a carbene compound that includes a triazole ring and has the structure: In another aspect, the organic layer comprises a carbene compound that includes a tetrazole ring and has the structure:

摘要翻译： 提供一种具有设置在阳极和阴极之间的阳极，阴极和有机层的有机发光器件。 一方面，有机层包括具有至少一个两性离子碳供体配体的化合物。 另一方面，有机层包括卡宾化合物，其包括以下：另一方面，有机层包含卡宾化合物，其包括：另一方面，有机层包含含有三唑环的卡宾化合物，其结构 另一方面，有机层包含含有四唑环的卡宾化合物，其结构如下：

公开(公告)号：US20100000606A1

公开(公告)日：2010-01-07

申请号：US12355475

申请日：2009-05-11

申请人： Mark E. Thompson ,  Peter Djurovich

发明人： Mark E. Thompson ,  Peter Djurovich

IPC分类号： H01L51/46

CPC分类号： H01L51/009 ,  C07F15/0033 ,  C07F15/0086 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/4226 ,  Y02E10/549

摘要： The present invention generally relates to organic photosensitive optoelectronic devices. More specifically, it is directed to organic photovoltaic devices, e.g., organic solar cells. More specifically, it is directed to organic photosensitive optoelectronic devices that comprise a cyclometallated organometallic compound as a light absorbing material.

摘要翻译： 本发明一般涉及有机光敏光电器件。 更具体地，其涉及有机光伏器件，例如有机太阳能电池。 更具体地，涉及包含作为光吸收材料的环金属化有机金属化合物的有机光敏光电子器件。

公开(公告)号：US07288331B2

公开(公告)日：2007-10-30

申请号：US11408542

申请日：2006-04-20

申请人： Mark E. Thompson ,  Xiaofan Ren ,  Peter Djurovich ,  Haiping Hong ,  Stephen R. Forrest ,  Chihaya Adachi

发明人： Mark E. Thompson ,  Xiaofan Ren ,  Peter Djurovich ,  Haiping Hong ,  Stephen R. Forrest ,  Chihaya Adachi

IPC分类号： H01L51/54

CPC分类号： H01L51/5096 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/185 ,  C09K2211/187 ,  C09K2211/188 ,  H01L51/002 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/0083 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5048 ,  H01L2251/552 ,  H05B33/14 ,  Y10S428/917 ,  Y10T428/24942

摘要： Light emitting devices having charge transporting layers comprising one or more metal complexes are provided. More particularly, devices include hole transporting layers comprising at least one organometallic complex are disclosed. The present devices can further comprise an electron blocking layer for improved efficiency.

摘要翻译： 提供具有包含一种或多种金属络合物的电荷输送层的发光器件。 更具体地，装置包括包含至少一种有机金属络合物的空穴传输层。 本发明的器件还可以包括用于提高效率的电子阻挡层。