Substituted 2-benzoyl-cyclohexan-1,3-diones with herbicidal effect
    32.
    发明授权
    Substituted 2-benzoyl-cyclohexan-1,3-diones with herbicidal effect 失效
    取代的具有除草效果的2-苯甲酰基 - 环己烷-1,3-二酮

    公开(公告)号:US06576596B1

    公开(公告)日:2003-06-10

    申请号:US09331639

    申请日:1999-06-23

    IPC分类号: A01N3510

    摘要: The invention relates to 2-benzoylcyclohexane-1,3-diones of the formula I where R1, R2 are each hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxyalkyl, alkenyl, alkynyl, —OR5, —OCOR6, —OSO2R6, —SH, —S(O)nR7, —SO2OR5, —SO2NR5R8, —NR8SO2R6 or —NR8COR6; R3 is hydrogen, cyano, alkyl, haloalkyl, —OR7, —SR7 or —NR7R10; R4 is hydrogen, substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, —COR9, —CO2R9, —COSR9 or —CONR8R9; X is oxygen or NR8; n is 0, 1 or 2; R5 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R6 is alkyl or haloalkyl; R7 is alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R8 is hydrogen or alkyl; R9 is alkyl, alkenyl, alkynyl, phenyl or benzyl; R10 is alkyl, haloalkyl, alkenyl or alkynyl; Q is a cyclohexane-1,3-dione ring with or without substitution attached in position 2; and agriculturally useful salts thereof; to processes and intermediates for preparing the compounds of the formula I; to compositions comprising them; and to the use of these derivatives or compositions comprising them for controlling undesirable plants.

    摘要翻译: 本发明涉及式I的2-苯甲酰基环己烷-1,3-二酮,其中R 1,R 2各自为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔基,-OR 5,-OCOR 6,-OSO 2 R 6, -SH,-S(O)nR7,-SO2OR5,-SO2NR5R8,-NR8SO2R6或-NR8COR6; R3是氢,氰基,烷基,卤代烷基,-OR7,-SR7或-NR7R10; R4是氢,取代或未取代的烷基, 环烷基,烯基,环烯基,炔基,-COR 9,-CO 2 R 9,-COSR 9或-CONR 8 R 9; X是氧或NR 8; n是0,1或2; R 5是氢,烷基,卤代烷基,烷氧基烷基,烯基或炔基; 烷基或卤代烷基; R 7是烷基,卤代烷基,烷氧基烷基,烯基或炔基; R 8是氢或烷基; R 9是烷基,烯基,炔基,苯基或苄基; R 10是烷基,卤代烷基,烯基或炔基; Q是环己烷-1 具有或不具有取代基的2-二酮环;和其农业上有用的盐;制备式I化合物的方法和中间体; 包含它们的组合物; 以及使用这些衍生物或包含它们的组合物来控制不期望的植物。

    Substituted cyclohexene-1,2-dicarboxylic acid derivatives and intermediates for their preparation
    40.
    发明授权
    Substituted cyclohexene-1,2-dicarboxylic acid derivatives and intermediates for their preparation 失效
    取代的环己烯-1,2-二羧酸衍生物及其制备中间体

    公开(公告)号:US06204222B1

    公开(公告)日:2001-03-20

    申请号:US09085769

    申请日:1998-05-29

    IPC分类号: A01N4336

    摘要: Substituted cyclohexene-1,2-dicarboxylic acid derivatives I (R1 and R2 are each H, unsubstituted or substituted C1-C6-alkyl, C3-C6-alkenyl or C3-C6-alkynyl, C3-C8-cycloalkyl, unsubstituted or substituted phenyl or heterocyclyl and, if R1 is H or C1-C6-alkyl, R2 is additionally OH, C1-C6-alkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C3-C6-cycloalkoxy, C5-C7-cycloalkenyloxy, C1-C6-haloalkoxy, C3-C6-haloalkenyloxy, C3-C7-cycloalkyl-C1-C6-alkoxy, C1-C6-alkyl-carbonyloxy, C1-C6-cyanoalkoxy, hydroxy-C1-C6-alkoxy, C1-C6-alkoxy-C1-C6-alkoxy, C1-C6-alkoxycarbonyl-C1-C6-alkoxy, C1-C6-alkoxy-C1-C6-alkoxy, C1-C6-alkylamino-C1-C6-alkoxy, C1-C6-dialkylamino-C1-C6-alkoxy, unsubstituted or substituted phenyl-C1-C6-alkoxy, phenyl-C3-C6-alkenyloxy or phenyl-C3-C7-alkynyloxy or unsubstituted or substituted amino, or R1 and R2, together with the nitrogen atom to which they are bonded, form an unsubstituted or substituted 3-membered to 8-membered heterocyclic structure, R3 is H or C1-C6-alkyl, R4 is H or halogen, R5 is H, halogen, NO2, CN or CF3, R6 is an unsubstituted or substituted 3-membered to 8-membered heterocyclic group, —A—CN, —A—CO—B, OR9, —C(R10)═O, —C(R10)═S, —C(R10)═N—R16, —CHR10)—CHR11—CO—B, —C(X1R14)(X2R15)R10 or —P(R12)(R13)═O, where the stated radicals have the meanings listed in the description, or R5 and R6 together form a 3-membered to 5-membered substituted carbon chain, and the agriculturally useful salts of Ia and Ib and intermediates for their preparation. The compounds Ia and Ib and their intermediates are suitable as herbicides and for the desiccation/defoliation of plants.

    摘要翻译: 取代的环己烯-1,2-二羧酸衍生物I(R 1和R 2各自为H,未取代或取代的C 1 -C 6 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6炔基,C 3 -C 8 - 环烷基,未取代或取代的苯基 或者杂环基,如果R 1是H或C 1 -C 6烷基,则R 2又是OH,C 1 -C 6 - 烷氧基,C 3 -C 6 - 烯氧基,C 3 -C 6 - 炔氧基,C 3 -C 6 - 环烷氧基,C 5 -C 7 - 环烯基氧基, C 1 -C 6 - 卤代烷氧基,C 3 -C 6 - 卤代链烯氧基,C 3 -C 7 - 环烷基-C 1 -C 6 - 烷氧基,C 1 -C 6烷基 - 羰氧基,C 1 -C 6 - 氰基烷氧基,羟基-C 1 -C 6烷氧基, 烷氧基-C 1 -C 6烷氧基,C 1 -C 6烷氧基-C 1 -C 6烷氧基,C 1 -C 6烷氧基-C 1 -C 6烷氧基,C 1 -C 6烷基氨基-C 1 -C 6烷氧基,C 1 -C 6二烷基氨基 - C 1 -C 6 - 烷氧基,未取代或取代的苯基-C 1 -C 6 - 烷氧基,苯基-C 3 -C 6 - 烯氧基或苯基-C 3 -C 7 - 炔氧基或未取代或取代的氨基,或R 1和R 2与 它们是键合的,形成未取代或取代的3元至8元杂环结构,R 3是H或C 1 -C 6 - 烷基,R 4是H或卤代 n为5,卤素,NO 2,CN或CF 3,R 6为未取代或取代的3元至8元杂环基,-A-CN,-A-CO-B,OR 9,-C(R 10) O,-C(R 10)= S,-C(R 10)= N-R 16,-CHR 10)-CHR 11 -CO-B,-C(X 1 R 14)(X 2 R 15)R 10或-P(R 12) 其中所述基团具有本说明书所列的含义,或者R5和R6一起形成3元至5元取代的碳链,以及Ia和Ib的农业上有用的盐及其制备的中间体。化合物Ia和 Ib及其中间体适合作为除草剂和植物的干燥/脱叶作用。