摘要:
Described are derivatives of 2-oxabicyclo[2.2.2]octanes and precursors therefor, cyclohexenemethanols as well as lower alkyl esters of said cyclohexenemethanols. The oxabicyclooctanes are useful in perfumery and foodstuff, medicinal product and tobacco flavors. The cyclohexenemethanols are useful as precursors for the oxabicyclooctanes and are, themselves, useful for their organoleptic properties in perfumery and flavors as are the esters of said cyclohexenemethanols.
摘要:
Described is a process for augmenting or enhancing the aroma or taste of a smoking tobacco comprising the step of intimately admixing with a smoking tobacco, an aroma or taste augmenting or enhancing quantity of an oxabicyclo chemical compound having the structure: ##STR1## wherein R.sub.2 is C.sub.2 -C.sub.5 alkyl or alkenyl; R.sub.4 is hydrogen, methyl or ethyl; R.sub.7 is hydrogen or methyl; and R.sub.8 is hydrogen or methyl with the proviso that when R.sub.4 is methyl or ethyl R.sub.7 and R.sub.8 are not both hydrogen and that at least one of R.sub.7 and R.sub.8 is methyl.Also described is a smoking tobacco article comprising a cylindrical shaped mass of smoking tobacco encased in a wrapper, said wrapper and said smoking tobacco being in contact with a porous filter, and being in intimate contact with either said filter, said wrapper or said shaped tobacco mass, at least one oxabicyclo chemical compound having the structure: ##STR2## wherein R.sub.2 is C.sub.2 -C.sub.5 alkyl or alkenyl; R.sub.4 is hydrogen, methyl or ethyl; R.sub.7 is hydrogen or methyl with the proviso that when R.sub.4 is methyl or ethyl, R.sub.7 and R.sub.8 are not both hydrogen and that at least one of R.sub.7 and R.sub.8 is methyl.
摘要:
Described are derivatives of 2-oxabicyclo[2.2.2]octanes and precursors therefor, cyclohexenemethanols as well as lower alkyl esters of said cyclohexenemethanols. The oxabicyclooctanes are useful in perfumery and foodstuff, medicinal product and tobacco flavors. The cyclohexenemethanols are useful as precursors for the oxabicyclooctanes and are, themselves, useful for their organoleptic properties in perfumery and flavors as are the esters of said cyclohexenemethanols.
摘要:
Described is a process for augmenting or enhancing the aroma of a solid or liquid anionic, cationic or nonionic detergent comprising the step of intimately admixing with a solid or liquid anionic, cationic or nonionic detergent base, a product prepared by a process comprising the steps of (i) intimately admixing aluminum isopropylate, toluene and a caryophyllene derivative selected from the group consisting of caryophyllene oxide and dihydro caryophyllene oxide to form a mixture; (ii) heating the resulting mixture at a temperature of from 100.degree. C. up to 150.degree. C. for a period of time from about one up to about five hours; and (iii) the rearranged caryophyllene oxide or dihydro caryophyllene oxide, a mixture of alcohols, from the reaction mass; the concentration of aluminum isopropylate catalyst in the reaction mass varying from about 0.025 molar up to about 0.75 molar; and the concentration of caryophyllene oxide or dihydro caryophyllene oxide in the reaction mass varying from about 0.25 molar up to about 1.00 molar.
摘要:
Described is a process for augmenting or enhancing the aroma of a detergent comprising the step of intimately admixing with a solid or liquid detergent base from 0.01% up to 0.5% by weight of at least one cyclic chemical compound having a structure: ##STR1## wherein R.sub.1 is selected from the group consisting of hydrogen and methyl; R.sub.2 is C.sub.3 -C.sub.4 alkyl or alkenyl; and R.sub.5 is hydrogen or C.sub.1 -C.sub.4 acyl and wherein one of the dashed lines is a carbon-carbon single bond and the other of the dashed lines is a carbon-carbon double bond.
摘要:
Described is a process for augmenting or enhancing the aroma of a detergent comprising the step of intimately admixing with a solid or liquid detergent base from 0.01% up to 0.5% by weight of said detergent of an oxabicyclooctane derivative having the structure: ##STR1## wherein R.sub.2 is C.sub.2 -C.sub.5 alkyl or alkenyl; R.sub.4 is hydrogen, methyl or ethyl; R.sub.7 is hydrogen or methyl; and R.sub.8 is hydrogen or methyl with the proviso that when R.sub.4 is methyl or ethyl, R.sub.7 and R.sub.8 are not both hydrogen and that at least one of R.sub.7 and R.sub.8 is methyl.
摘要:
Described are derivatives of 2-oxabicyclo[2.2.2]octanes and precursors therefor, cyclohexenemethanols as well as lower alkyl esters of said cyclohexenemethanols. The oxabicyclooctanes are useful in perfumery and foodstuff and medicinal product flavors. The cyclohexenemethanols are useful as precursors for the oxabicyclooctanes.
摘要:
Described are derivatives of 2-oxabicyclo[2.2.2]octanes and precursors therefor, cyclohexenemethanols as well as organometallic salts of said cyclohexenemethanols. The oxabicyclooctanes are useful in perfumery and foodstuff and medicinal product flavors. The cyclohexenemethanols and their organometallic salts are useful as precursors for the oxabicyclooctanes.
摘要:
Described is a process for augmenting or enhancing the aroma or taste of raspberry flavored foodstuffs comprising the step of adding to a foodstuff, an aroma augmenting or enhancing quantity of certain 2,6,6-trimethylcyclohexene derivatives.
摘要:
Described are cis-3-hexenyl derivatives having the generic structure: ##STR1## wherein R is one of the moieties: ##STR2## which are useful in foodstuffs, flavorings, fragrances, perfumed articles (e.g. anionic, cationic or nonionic detergents, dryer-added fabric softener articles and cosmetic powders) and smoking tobacco flavorings; processes for producing such cis-3-hexenyl derivatives and products produced according to such processes which include chemical compounds in addition to said cis-3-hexenyl derivatives.