公开(公告)号：US4837398A

公开(公告)日：1989-06-06

申请号：US140359

申请日：1988-01-04

Applicant: Clarence D. Chang ,  Cynthia T. Chu ,  Carol S. Lee

Inventor： Clarence D. Chang ,  Cynthia T. Chu ,  Carol S. Lee

IPC: B01J29/65 ,  B01J29/40 ,  B01J29/70 ,  B01J29/90 ,  C07C1/00 ,  C07C1/20 ,  C07C1/24 ,  C07C67/00 ,  C10G3/00 ,  C10G11/05 ,  C10G73/38

CPC classification number: B01J29/40 ,  B01J29/90 ,  C10G11/05 ,  C10G3/48 ,  C10G3/49 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/65 ,  B01J29/70 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/703 ,  C10G2300/807 ,  C10G2400/20 ,  C10G2400/30 ,  Y02P30/20

Abstract: Alumina-composited zeolite catalysts are activated by contact with an aqueous ammonium solution under ammonia gas pressure such that a pH of at least about 8 is maintained in the solution. The treated zeolite may thereafter be calcined without prior ammonium-exchange to provide the zeolite in the hydrogen form.

公开(公告)号：US4790928A

公开(公告)日：1988-12-13

申请号：US153395

申请日：1988-02-08

Applicant: Clarence D. Chang ,  Nai Y. Chen ,  Stuart D. Hellring ,  Ying-Yen P. Tsao ,  Dennis E. Walsh

Inventor： Clarence D. Chang ,  Nai Y. Chen ,  Stuart D. Hellring ,  Ying-Yen P. Tsao ,  Dennis E. Walsh

IPC: B01J29/40 ,  C07C1/20 ,  C10G47/02 ,  C07C5/13 ,  C10G11/02

CPC classification number: B01J29/40 ,  C07C1/20 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2529/40

Abstract: The acidity of a zeolite catalyst is reduced by calcination in an essentially water-free atmosphere at temperatures above 700.degree. C., preferably from 725.degree. to 800.degree. C., to reduce the alpha value to less than about 10 percent of its original value. The low acidity catalysts produced in this way may be used for conversions requiring low acidity, shape selective catalysis, including dewaxing. The calcined, low acidity catalysts exhibit improved dewaxing activity.

Abstract translation: 沸石催化剂的酸度通过在高于700℃，优选725℃至800℃的温度下在基本无水的气氛中煅烧而降低，以将α值降低到其原始值的约10％ 。 以这种方式生产的低酸性催化剂可用于需要低酸度，形状选择性催化（包括脱蜡）的转化。 煅烧的低酸度催化剂表现出改善的脱蜡活性。

公开(公告)号：US4754096A

公开(公告)日：1988-06-28

申请号：US72319

申请日：1987-07-13

Applicant: Clarence D. Chang ,  John D. Dixon ,  Albert B. Schwartz ,  David S. Shihabi

Inventor： Clarence D. Chang ,  John D. Dixon ,  Albert B. Schwartz ,  David S. Shihabi

IPC: C10M177/00 ,  B01J29/40 ,  C10G50/02 ,  C10M107/06 ,  C10M143/04 ,  C10N20/02 ,  C10N70/00 ,  C07C2/02 ,  C07C2/04

CPC classification number: C10G50/02

Abstract: A process for the production of lubricant oil range hydrocarbon having increased viscosity index by oligomerization of lower olefins over medium pore shape selective acid zeolite catalyst. The preferred oligomerization process is conducted using 50 ppm to 5 weight percent of water vapor as cofeed, based on olefin and acid ZSM-5 zeolite.

公开(公告)号：US4665248A

公开(公告)日：1987-05-12

申请号：US787184

申请日：1985-10-15

Applicant: Clarence D. Chang ,  Joseph N. Miale

Inventor： Clarence D. Chang ,  Joseph N. Miale

IPC: B01J29/40 ,  B01J29/70 ,  C07C1/20

CPC classification number: B01J29/40 ,  B01J29/7007 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42

Abstract: The ion-exchange capacity and acid catalytic activity of a ZSM-5 type zeolite are increased by treatment of a physical mixture of the zeolite and an inorganic oxide with water in the presence of an alkali metal cation.Specifically, the catalyst is prepared by contacting a mixture of a crystalline zeolite having a silica to alumina ratio above 12 and a Constraint Index between about 1 and about 12, and a solid source of aluminum with liquid water in the presence of an activating amount of an alkali metal cation and under a combination of conditions including a temperature up to about 370.degree. C. for less than about an hour to about 100 hours to induce increased activity to the zeolite.

Abstract translation: ZSM-5型沸石的离子交换能力和酸催化活性通过在碱金属阳离子存在下处理沸石和无机氧化物的物理混合物与水而增加。 具体地说，催化剂是通过使二氧化硅与氧化铝之比高于12的结晶沸石和约1至约12的约束指数的混合物与固体的铝水溶液接触而制备的， 碱金属阳离子，并且在包括温度高达约370℃的条件的组合下反应少于约1小时至约100小时以诱导沸石活性增加。

公开(公告)号：US4605637A

公开(公告)日：1986-08-12

申请号：US693444

申请日：1985-01-22

Applicant: Clarence D. Chang ,  Joseph N. Miale

Inventor： Clarence D. Chang ,  Joseph N. Miale

IPC: B01J29/40 ,  B01J29/70 ,  B01J29/06 ,  B01J27/14

CPC classification number: B01J29/40 ,  B01J29/7007 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  Y10S423/22 ,  Y10S423/27

Abstract: There is provided a process for activating a zeolite with an aluminum phosphate material. The process comprises hydrothermally treating an intimate mixture of the zeolite and an effective amount of aluminum phosphate activating agent in contact with an aqueous liquid phase under reaction conditions to increase the cracking activity of the mixture. Examples of zeolites which may be activated include low acidity zeolites such as boron-containing ZSM-5, boron-containing zeolite Beta and high silica ZSM-5. The aluminum phosphate may be in the form of a microporous, crystalline framework material such as AlPO.sub.4 -5.

Abstract translation: 提供了用磷酸铝材料活化沸石的方法。 该方法包括在反应条件下水热处理沸石和有效量的磷酸铝活化剂与水性液相接触的紧密混合物，以增加混合物的裂解活性。 可以被活化的沸石的实例包括低酸性沸石，例如含硼的ZSM-5，含硼沸石β和高二氧化硅ZSM-5。 磷酸铝可以是微孔，结晶骨架材料如AlPO 4 -5的形式。

公开(公告)号：US4594333A

公开(公告)日：1986-06-10

申请号：US646200

申请日：1984-08-31

Applicant: Clarence D. Chang ,  Cynthia T. W. Chu

Inventor： Clarence D. Chang ,  Cynthia T. W. Chu

IPC: C01B39/00 ,  B01J20/18 ,  B01J29/40 ,  C01B39/06 ,  C01B39/38 ,  B01J29/28

CPC classification number: B01J29/40 ,  B01J20/186 ,  B01J2229/26 ,  B01J2229/42

Abstract: The ion-exchange capacity and acid catalytic activity of a ZSM-5 type zeolite are increased by treatment of a physical mixture of the zeolite and a solid source of aluminum with water in the presence of an alkali metal compound activating agent and an alkali metal salt of a mineral acid.

Abstract translation: ZSM-5型沸石的离子交换能力和酸催化活性通过在碱金属化合物活化剂和碱金属盐存在下，通过处理沸石和固体铝源的物理混合物与水而增加 的无机酸。

公开(公告)号：US4544783A

公开(公告)日：1985-10-01

申请号：US702709

申请日：1985-02-19

Applicant: Clarence D. Chang ,  Joseph N. Miale

Inventor： Clarence D. Chang ,  Joseph N. Miale

IPC: B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  C07C1/20 ,  C07C1/00

CPC classification number: B01J29/703 ,  B01J29/06 ,  B01J2229/18 ,  B01J2229/37 ,  B01J29/40 ,  B01J29/65

Abstract: A process is provided for converting feedstock comprising oxygenates to product comprising hydrocarbons over a catalyst comprising a high silica crystalline zeolite which has been treated sequentially by contact with a dilute hydrogen fluoride solution and then by contact with aluminum chloride vapor.

Abstract translation: 提供了一种方法，用于将包含含氧化合物的原料转化成包含烃的产物，该催化剂包括高二氧化硅结晶沸石，其已经通过与稀氟化氢溶液接触然后与氯化铝蒸气接触而被顺序处理。

公开(公告)号：US4542247A

公开(公告)日：1985-09-17

申请号：US650473

申请日：1984-09-14

Applicant: Clarence D. Chang ,  Joe E. Penick ,  Richard F. Socha

Inventor： Clarence D. Chang ,  Joe E. Penick ,  Richard F. Socha

IPC: C10G50/00 ,  C10G50/02 ,  C07C5/00 ,  C07C1/00

CPC classification number: C10G50/00 ,  C10G50/02

Abstract: Disclosed is a method and apparatus for producing distillate and/or lubes which employ integrating catalytic (or thermal) dehydrogenation of paraffins with MOGDL. The process feeds the product from a low temperature propane and/or butane dehydrogenation zone into a first catalytic reactor zone, which operates at low pressure and contains zeolite oligomerization catalysts, where the low molecular weight olefins are reacted to primarily gasoline range materials. These gasoline range materials can then be pressurized to the pressure required for reacting to distillate in a second catalytic reactor zone operating at high pressure and containing a zeolite oligomerization catalyst. The distillate is subsequently sent to a hydrotreating unit and product separation zone to form lubes and other finished products.

Abstract translation: 公开了一种用于生产馏出物和/或润滑剂的方法和装置，其使用与MOGDL一起催化（或热）脱氢石蜡的方法和装置。 该方法将产物从低温丙烷和/或丁烷脱氢区进料到第一催化反应器区，其在低压下操作并含有沸石低聚催化剂，其中低分子量烯烃主要与汽油范围材料反应。 然后可以将这些汽油范围材料加压至在高压下操作并含有沸石低聚催化剂的第二催化反应器区域中与馏出物反应所需的压力。 随后将馏出物送至加氢处理装置和产品分离区以形成润滑剂和其它成品。

公开(公告)号：US4538015A

公开(公告)日：1985-08-27

申请号：US668356

申请日：1984-11-05

Applicant: Joseph N. Miale ,  Clarence D. Chang

Inventor： Joseph N. Miale ,  Clarence D. Chang

IPC: B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J37/26 ,  C07C1/20

CPC classification number: B01J29/40 ,  B01J37/26 ,  B01J2229/40 ,  B01J29/65 ,  B01J29/70

Abstract: A process is provided for conducting organic compound conversion over a catalyst comprising a crystalline zeolite which has been treated by impregnation with an ammoniacal aluminum fluoride solution, contact with an ammonium salt solution, and calcination.

Abstract translation: 提供了一种通过催化剂进行有机化合物转化的方法，该催化剂包括通过用氨水氟化铝溶液浸渍，与铵盐溶液接触和煅烧来处理的结晶沸石。

公开(公告)号：US4467133A

公开(公告)日：1984-08-21

申请号：US390087

申请日：1982-06-21

Applicant: Clarence D. Chang ,  William H. Lang

Inventor： Clarence D. Chang ,  William H. Lang

IPC: C07C1/20 ,  C10G3/00 ,  C07C1/00

CPC classification number: C07C1/20 ,  C10G3/49 ,  C07C2529/08 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/04 ,  Y02P30/20

Abstract: A process for the conversion of alcohols and/or ethers to diesel fuel hydrocarbon mixtures comprising contacting alcohols and/or ethers with large pore zeolites, such as rare-earth Y aluminosilicate under elevated pressures and temperatures below about 600.degree. F.

Abstract translation: 一种将醇和/或醚转化为柴油燃料烃混合物的方法，其包括使醇和/或醚与大孔沸石如稀土Y硅铝酸盐在升高的压力和低于约600°F的温度下接触。