摘要:
A lithium secondary battery of the present invention comprises a positive electrode formed by disposing a positive-electrode mixture layer containing a positive-electrode active material and a positive-electrode binder, on a surface of a positive-electrode current collector; a negative electrode formed by sintering a negative-electrode mixture layer containing a negative-electrode binder and a negative-electrode active material containing silicon and/or a silicon alloy, disposed on a surface of a negative-electrode current collector; a separator disposed between the positive electrode and the negative electrode; and a nonaqueous electrolyte; wherein an electrode unit obtained by setting the positive electrode and the negative electrode opposed to each other through the separator and rolling them in spirally rolled state is placed in a cylindrical battery container and wherein a curvature radius of the negative-electrode mixture layer opposed to the positive-electrode mixture layer through the separator in the spirally rolled state is 1.5 mm or larger.
摘要:
A non-aqueous electrolyte secondary battery has a positive electrode (1), a negative electrode (2), a separator (3) interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte solution in which a solute is dissolved in a non-aqueous solvent. The negative electrode contains a negative electrode active material capable of alloying with lithium and the non-aqueous solvent of the non-aqueous electrolyte solution contains one ore more fluorinated cyclic carbonates and a carboxylic ester. In addition, the non-aqueous electrolyte solution contains a nitrile compound having a chain saturated hydrocarbon group having two or more carbon atoms.
摘要:
A lithium secondary battery comprises an electrode assembly and a non-aqueous electrolyte. The electrode assembly is made by winding a negative electrode, a positive electrode, and a separator interposed between the negative and positive electrodes. The negative electrode contains a negative electrode active material that is alloyed with lithium. The non-aqueous electrolyte is impregnated in the electrode assembly. At least one of the negative and positive electrodes is divided into a plurality of electrode units which are arranged at spaces for each other along the winding direction.
摘要:
A non-aqueous electrolyte secondary battery has a positive electrode (1), a negative electrode (2), a separator (3) interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte solution in which a solute is dissolved in a non-aqueous solvent. The negative electrode contains a negative electrode active material capable of alloying with lithium and the non-aqueous solvent of the non-aqueous electrolyte solution contains one ore more fluorinated cyclic carbonates and a carboxylic ester. In addition, the non-aqueous electrolyte solution contains a nitrile compound having a chain saturated hydrocarbon group having two or more carbon atoms.
摘要:
Charge-discharge cycle performance is improved in a lithium secondary battery that adopts a thin film made of silicon or a silicon alloy as its negative electrode active material and has a wound electrode structure. The lithium secondary battery includes: a negative electrode having a current collector and a thin film made of silicon or a silicon alloy as a negative electrode active material, the thin film provided on the current collector; a positive electrode; a separator; the positive and negative electrodes being overlapped with the separator interposed therebetween, and the positive and negative electrodes and the separator being wound around to form an electrode assembly; a non-aqueous electrolyte; and a battery case accommodating the electrode assembly. The ratio of theoretical capacity per unit area of the negative electrode to charge capacity per unit area of the positive electrode is within the range of from 1.9 to 4.4.
摘要:
A non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode and a non-aqueous electrolyte. The negative electrode comprises a negative electrode active material to be alloyed with lithium and the non-aqueous electrolyte comprises a non-aqueous solvent containing fluorinated cyclic carbonate and propyl acetate.
摘要:
A nonaqueous electrolyte secondary battery which includes a positive electrode, a negative electrode and a separator stacked and wound in a cylindrical configuration, and which achieves a high energy density and superior cycle performance characteristics.The nonaqueous electrolyte secondary battery includes a positive electrode containing a positive active material, a negative electrode containing a negative active material, a separator interposed between the positive electrode and the negative electrode, and a nonaqueous electrolyte containing a solvent and a solute. Those positive electrode, negative electrode and separator are stacked and wound in a cylindrical configuration. Characteristically, the negative active material comprises a material that stores lithium via alloying with lithium, the solvent in the nonaqueous electrolyte contains a fluorinated cyclic carbonate, and the nonaqueous electrolyte has a viscosity of not higher than 2.5 mPas.
摘要:
A lithium secondary battery has a wound electrode assembly (5). The wound electrode assembly (5) has a negative electrode (2) having a negative electrode active material layer containing a negative electrode active material capable of alloying with lithium and having a filling density of 2.0 g/cc or less, a positive electrode (1) having a positive electrode active material layer containing a positive electrode active material made of a transition metal composite oxide, a separator (3) disposed between the positive and negative electrodes and having a penetration resistance of 500 g or greater, and a cylindrical hollow space (14) at a winding axis and in the vicinity thereof, wherein the positive electrode (1), the negative electrode (2), and the separator (3) are spirally wound. A columnar center pin (15) having a diameter of from 75% to 95% of the diameter of the hollow space is disposed in the hollow space.
摘要:
Charge-discharge cycle performance is improved in a lithium secondary battery utilizing a material containing silicon as a positive electrode active material. A lithium secondary battery includes a negative electrode (2) containing silicon as a negative electrode active material, a positive electrode (1) containing a lithium-transition metal composite oxide, and a non-aqueous electrolyte. Lithium carbonate is added in the positive electrode (1), and carbon dioxide is dissolved in the non-aqueous electrolyte.
摘要:
A lithium battery employs for a battery separator and a battery insulating packing and the like a battery polymeric material comprising repeating units wherein p-phenylene is combined with one type of group selected from the group composed of oxygen, a methylene group, an isopropylidene group, a carbonyl group, a carbonyldioxy group, a carboxylic acid anhydride group, an amide group, an ureylene group and a sulfonyl group, or a polymeric material comprising at least two types of repeating units wherein p-phenylene is combined with one type of group selected from the group composed of oxygen, a methylene group, an isopropylidene group, a carbonyl group, a carbonyldioxy group, a carboxylic acid anhydride group, an amide group, an ureylene group, a sulfonyl group, sulfur and a carbonyloxy group.