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    High VI synthetic lubricants from cracked refined wax
    31.
    发明授权
    High VI synthetic lubricants from cracked refined wax 失效
    来自裂化精制蜡的高VI合成润滑剂

    公开(公告)号：US5136118A

    公开(公告)日：1992-08-04

    申请号：US571347

    申请日：1990-08-23

    申请人： J. Scott Buchanan ,  Margaret M. Wu

    发明人： J. Scott Buchanan ,  Margaret M. Wu

    IPC分类号： C10M107/02

    CPC分类号： C10M107/02 ,  C10M2205/00 ,  C10M2205/02 ,  C10N2220/02

    摘要： A process is disclosed for the production of synthetic hydrocarbon lubricants having high viscosity index by oligomerizing a mixture of alpha-olefins comprising the reaction product from the thermal cracking of refined wax. The oligomerization is carried out with Lewis acid catalyst or reduced chromium oxide on porous support.

    摘要翻译： 公开了一种通过使包含来自精制蜡的热裂解的反应产物的α-烯烃的混合物低聚而生产具有高粘度指数的合成烃类润滑剂的方法。 低聚反应用多孔载体上的路易斯酸催化剂或还原的氧化铬进行。

    Novel VI enhancing compositions and Newtonian lube blends
    32.
    发明授权
    Novel VI enhancing compositions and Newtonian lube blends 失效
    新型VI增强组合物和牛顿润滑剂混合物

    公开(公告)号：US5012020A

    公开(公告)日：1991-04-30

    申请号：US345606

    申请日：1989-05-01

    申请人： Andrew Jackson ,  Margaret M. Wu

    发明人： Andrew Jackson ,  Margaret M. Wu

    IPC分类号： C10M127/02 ,  C08F4/60 ,  C08F4/69 ,  C08F10/00 ,  C08F10/14 ,  C08F110/14 ,  C08F210/14 ,  C10G50/02 ,  C10M143/08 ,  C10N20/04 ,  C10N30/02 ,  C10N40/04 ,  C10N40/08 ,  C10N40/25 ,  C10N70/00

    CPC分类号： C08F10/14 ,  C10G50/02 ,  C10M143/08 ,  C08F110/14 ,  C08F210/14 ,  C10M2205/00 ,  C10M2205/028 ,  C10N2220/02 ,  Y02P20/582

    摘要： A novel composition is disclosed that is particularly useful as a lubricant viscosity index improver. The composition comprises branched branched C.sub.30 -C.sub.10000 hydrocarbons that have a branch ratio of less than 0.19 and viscosity at 100.degree. C. between 725 CS and 15,000 cS. The novel compositions comprise the product of the oligomerization of C.sub.6 to C.sub.20 alpha-olefin feedstock, or mixtures thereof, under oligomerization conditions at a temperature between -20.degree. C. and +90.degree. C. in contact with a reduced valence state Group VIB metal catalyst on porous support. The compositions have viscosities at 100.degree. C. between 725 cS and 15,000 cS. Using the foregoing compositions in admixture with mineral oil and synthetic lubricants provides novel lubricant blends that show an elevated viscosity index. The mixtures also show an increased stability to shear stress at high temperature with all blends notable by exhibiting Newtonian flow.

    摘要翻译： 公开了作为润滑剂粘度指数改进剂特别有用的新型组合物。 该组合物包含分支比小于0.19且在100℃下在725CS和15,000cS之间的粘度的支链C30-C10000烃。 该新型组合物包括C6-C20α-烯烃原料低聚的产物，或其混合物，在低温条件下，在-20℃至+ 90℃之间的温度下与还原的化合价VIB金属 多孔载体上的催化剂。 组合物在100℃下的粘度在725cS和15,000cS之间。 使用与矿物油和合成润滑剂混合的上述组合物提供显示升高的粘度指数的新型润滑剂共混物。 混合物还显示出在高温下对剪切应力的稳定性增加，所有共混物通过显示牛顿流动显着。

    Regeneration of reduced metal oxide oligomerization catalyst
    33.
    发明授权
    Regeneration of reduced metal oxide oligomerization catalyst 失效
    还原金属氧化物低聚催化剂的再生

    公开(公告)号：US4996384A

    公开(公告)日：1991-02-26

    申请号：US481279

    申请日：1990-02-20

    申请人： Bruce P. Pelrine ,  Margaret M. Wu

    发明人： Bruce P. Pelrine ,  Margaret M. Wu

    IPC分类号： B01J23/92 ,  B01J38/12 ,  C07C2/10

    CPC分类号： B01J23/92 ,  B01J38/12 ,  C07C2/10 ,  C07C2521/08 ,  C07C2523/26 ,  Y02P20/584

    摘要： A process for producing oligomers from alpha-olefins, such as 1-decene, in which the olefins are oligomerized over a supported, reduced metal oxide catalyst from Group VIB of the Periodic Table to give oligomers with a branch ratio of less than 0.19. The catalyst, preferably a chromium/silica catalyst the catalyst can be regenerated to allow repeated recycling of the catalyst without a loss in yield of the oligomer product. The regeneration process comprises: (i) purging or stripping the deactivated catalyst with inert gas at elevated temperature to strip unreacted olefin and oligomer product from the catalyst; (ii) contacting the deactivated and purged catalyst with a stream of oxidizing gas while heating to elevated temperature to oxidize the metal component of the catalyst and remove carbonaceous deposits from the catalyst; (iii) cooling the oxidized catalyst and contacting it with a stream of reducing gas to reduce the metal component of the oxidized catalyst to a lower valence state. The oligomerization may be carried out at relatively high temperatures of about 90.degree. to 250.degree. C. to produce liquid lubricant products of high viscosity index, typically above 130, or at lower temperatures from about -20.degree. to about +90.degree. C. to product products of higher molecular weight which may be used as lubricant additives, e.g. VI improvers. The high molecular weight products are generally characterized by a branch ratio less than 0.19, a weight average molecular weight from about 15,000 to 200,000, a number average molecular weight from about 5,000 to about 50,000 and a molecular weight distribution from about 1 to about 5. They are also shear stable under high temperature, high shear rate conditions of 150.degree. C. and a shear rate of 10.sup.6 second.sup.-1.

    摘要翻译： 从α-烯烃如1-癸烯制备低聚物的方法，其中烯烃在负载型还原的金属氧化物催化剂上从元素周期表VIB中低聚，得到分支比小于0.19的低聚物。 催化剂，优选铬/二氧化硅催化剂，催化剂可以被再生以允许催化剂的反复循环而不会使低聚物产物的产率降低。 再生方法包括：（i）在升高的温度下用惰性气体吹扫或汽提失活的催化剂，以从催化剂中除去未反应的烯烃和低聚物产物; （ii）在加热至高温以使氧化催化剂的金属组分并从催化剂中除去含碳沉积物的同时使失活和净化的催化剂与氧化气体流接触; （iii）冷却氧化的催化剂并将其与还原气体流接触，以将氧化催化剂的金属组分降至更低的化合价态。 低聚反应可以在约90℃至250℃的相对高的温度下进行，以产生高粘度指数（通常在130以上）或在约-20℃至约+90℃的较低温度至 可用作润滑剂添加剂的较高分子量的产品，例如 VI改进剂 高分子量产物通常的特征在于分支比小于0.19，重均分子量为约15,000至200,000，数均分子量为约5,000至约50,000，分子量分布为约1至约5。 它们在150℃的高温，高剪切速率条件和106秒-1的剪切速率下也剪切稳定。

    C2-C5 olefin oligomerization by reduced chromium catalysis
    34.
    发明授权
    C2-C5 olefin oligomerization by reduced chromium catalysis 失效
    通过还原铬催化的C2-C5烯烃低聚

    公开(公告)号：US4990709A

    公开(公告)日：1991-02-05

    申请号：US345061

    申请日：1989-04-28

    申请人： Margaret M. Wu

    发明人： Margaret M. Wu

    IPC分类号： C10G50/02 ,  C10M107/10

    CPC分类号： C10G50/02 ,  C10M107/10

    摘要： A process is disclosed for the oligomerization of C.sub.2 -C.sub.5 alpha olefin mixtures or C.sub.3 -C.sub.5 alpha-olefins alone to produce novel lubricant range products having high viscosity index and regio-regularity not greater than 40%. Lower hydrocarbon fractions useful as gasoline and distillate fuels are also produced. The process comprises contacting said mixtures or C.sub.3 -C.sub.5 alpha-olefins with a reduced valence state chromium oxide catalyst on a silica support in an oligomerization zone under oligomerization conditions comprising a temperature from 90.degree. C. to 250.degree. C. The process can be carried out in dilute form using an inert solvent such as octane. The lubricant products can be produced in wide range of viscosities including the direct production of low viscosity lubricants having high viscosity index.

    摘要翻译： 公开了用于C2-C5α烯烃混合物或C3-C5α-烯烃单体低聚的方法，以生产具有高粘度指数和区域规律度不大于40％的新型润滑剂范围产品。 也可以生产用作汽油和馏出燃料的低级烃馏分。 该方法包括在包含90℃至250℃的低温条件下，使所述混合物或C 3 -C 5α-烯烃与低聚区中的二氧化硅载体上的还原价态氧化铬催化剂接触。该方法可以携带 使用惰性溶剂如辛烷稀释形式。 润滑剂产品可以在宽的粘度范围内生产，包括直接生产具有高粘度指数的低粘度润滑剂。

    Liquid lubricants from alpha-olefin and styrene copolymers
    35.
    发明授权
    Liquid lubricants from alpha-olefin and styrene copolymers 失效
    来自α-烯烃和苯乙烯共聚物的液体润滑剂

    公开(公告)号：US4967029A

    公开(公告)日：1990-10-30

    申请号：US403971

    申请日：1989-09-07

    申请人： Margaret M. Wu

    发明人： Margaret M. Wu

    IPC分类号： B01J23/26 ,  C08F4/06 ,  C08F4/22 ,  C08F10/14 ,  C08F210/14 ,  C10M105/06 ,  C10M107/12 ,  C10N20/02 ,  C10N70/00

    CPC分类号： C10M107/12 ,  C08F210/14 ,  C10M2205/0285 ,  C10M2205/04 ,  C10M2205/043

    摘要： Alpha-olefins such as 1-decene are copolymerized with vinylaromatic monomers, especially styrene or the alkylstyrenes, to produce liquid lubricant oligomers having a broad range of viscosities, high viscosity index(VI), improved thermal stability and additive solubility characteristics. The lubricant oligomers are random copolymers containing recurring units of 1-alkene and vinyl aromatic monomer in mole ratios between 2:1 and 500:1, but preferably between 5:1 and 100:1 and more preferably from about 10:1 to 50:1. The recurring 1-alkene units of the copolymer have a branch ratio of less than 0.19, indicative of a poly 1-alkene segment of the copolymer chain or backbone that is essentially linear. The copolymerization catalyst is a reduced Group VIB metal catalyst on porous support, preferably reduced chromium oxide on a silica support.

    摘要翻译： α-烯烃如1-癸烯与乙烯基芳族单体，特别是苯乙烯或烷基苯乙烯共聚以制备具有宽粘度范围，高粘度指数（VI），改进的热稳定性和添加剂溶解度特性的液体润滑剂低聚物。 润滑剂低聚物是含有1-烯烃和乙烯基芳族单体的重复单元的无规共聚物，其摩尔比为2:1至500:1，但优选为5:1至100:1，更优选为约10:1至50:1。 1。 共聚物的重复1-烯烃单元的分支比小于0.19，表明基本上是线性的共聚物链或骨架的聚1-烯烃链段。 共聚催化剂是在多孔载体上还原的VIB族金属催化剂，优选在二氧化硅载体上还原的氧化铬。

    Process for manufacturing olefinic oligomers having lubricating properties
    36.
    发明授权
    Process for manufacturing olefinic oligomers having lubricating properties 失效
    制备具有润滑性能的烯烃低聚物的方法

    公开(公告)号：US4827073A

    公开(公告)日：1989-05-02

    申请号：US210434

    申请日：1988-06-23

    申请人： Margaret M. Wu

    发明人： Margaret M. Wu

    IPC分类号： C10G50/02 ,  C10M143/08 ,  C07C2/10

    CPC分类号： C10G50/02 ,  C10M143/08 ,  C10M2205/00 ,  C10M2205/028 ,  C10N2220/02

    摘要： A process for oligomerizing alpha olefin to produce lubricant range hydrocarbon stock including the step of contacting said alpha olefin with a supported solid reduced Group VIB (e.g., chromium) catalyst under oligomerization conditions at a temperature of about 90.degree. to 250.degree. C. to produce liquid lubricant hydrocarbon. The product comprises the polymeric residue of linear C.sub.6 -C.sub.20 1-alkenes, said composition having a branch ratio of less than 0.19. The weight average molecular weight is between 420 and 45,000, number average molecular weight between 420 and 18,000, molecular weight distribution between 1 and 5 and pour point below -15.degree. C. The hydrogenated lubricant range hydrocarbon product has viscosity index of about 130 to 280 and viscosity up to about 750 cS. The process is particularly useful where the starting alpha olefin consists essentially of olefinic hydrocarbon having 8 to 14 carbon atoms or mixtures thereof; wherein the process conditions include reaction temperature of about 100.degree. to 180.degree.; and wherein the support catalyst includes porous inert silica.

    摘要翻译： 一种使α-烯烃低聚以产生润滑剂范围的烃原料的方法，包括在低温条件下在约90℃至250℃的温度下使所述α-烯烃与负载的固体还原的VIB族（例如铬）催化剂接触的步骤，以产生 液体润滑剂烃。 产物包含线性C 6 -C 20 1-烯烃的聚合残基，所述组合物具有小于0.19的分支比例。 重均分子量为420至45,000，数均分子量为420至18,000，分子量分布为1至5，倾点低于-15℃。氢化润滑剂范围烃产物的粘度指数为约130至280 粘度高达约750cS。 当起始α-烯烃基本上由具有8-14个碳原子的烯烃或其混合物组成时，该方法特别有用; 其中所述工艺条件包括约100°至180°的反应温度; 并且其中所述载体催化剂包括多孔惰性二氧化硅。

    Pour point depressant for hydrocarbon compositions
    40.
    发明授权
    Pour point depressant for hydrocarbon compositions 有权
    用于烃组合物的倾点下降剂

    公开(公告)号：US08642522B2

    公开(公告)日：2014-02-04

    申请号：US12133927

    申请日：2008-06-05

    申请人： Margaret M. Wu ,  David J. Baillargeon ,  Andrew Jackson

    发明人： Margaret M. Wu ,  David J. Baillargeon ,  Andrew Jackson

    IPC分类号： C10M143/00

    CPC分类号： C10L1/1641 ,  C08F4/65912 ,  C08F4/65927 ,  C08F210/14 ,  C10L10/16 ,  C10M107/10 ,  C10M2205/028 ,  C10M2205/0285 ,  C10M2205/173 ,  C10M2209/084 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2230/02 ,  C10N2230/66 ,  C08F2500/17 ,  C10M2205/026 ,  C10M2205/0265

    摘要： Disclosed in one embodiment is a hydrocarbon blend made from 0.001 to 10 wt % of at least one poly-α-olefin, by weight of the blend, the at least one poly-α-olefin having a Kv100 within the range of from 10 to 3000 cSt and a molecular weight distribution within the range of from 1.0 to 4.5; and a base stock having a Kv100 below 20.0 cSt; wherein the at least one poly-α-olefin is present in an amount sufficient to lower the pour point of the blend by at least 5° C. relative to the pour point of the base stock. In certain embodiments the blend is formed by (a) reacting a catalyst composition and a feed containing at least two sets of α-olefins, wherein the first set of α-olefins is selected from C4 to C12 α-olefins and the second set of α-olefins is selected from C14 or larger α-olefins. The α-olefin feed may have a number average carbon number of at least 8 carbon atoms or greater.

    摘要翻译： 在一个实施方案中公开了一种烃混合物，其由0.001至10重量％的至少一种聚-α-烯烃（按共混物的重量计），至少一种聚-α-烯烃的Kv100在10〜 3000cSt，分子量分布范围为1.0-4.5; 和低于20.0cSt的Kv100的基础油; 其中所述至少一种聚-α-烯烃以足以将所述共混物的倾点相对于所述基础油料的倾点降至至少5℃的量存在。 在某些实施方案中，通过（a）催化剂组合物和含有至少两组α-烯烃的进料反应形成共混物，其中第一组α-烯烃选自C 4 -C 12α-烯烃，第二组 α-烯烃选自C14或更大的α-烯烃。 α-烯烃进料可以具有至少8个碳原子或更大的数均碳原子数。