Photosensitive compositions having mixtures of alkoxy and non-alkoxy diazonium salt containing compounds
    31.
    发明授权
    Photosensitive compositions having mixtures of alkoxy and non-alkoxy diazonium salt containing compounds 失效
    具有含烷氧基和非烷氧基重氮盐的化合物的混合物的光敏组合物

    公开(公告)号:US06861196B2

    公开(公告)日:2005-03-01

    申请号:US10664179

    申请日:2003-09-17

    CPC classification number: G03F7/016 G03F7/021 G03F7/0215 G03F7/0217

    Abstract: The present invention includes an imageable element, which can be: (a) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; a polyvinyl acetal binder; and a sheet substrate; or (b) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; and a sheet substrate. The imaging layer includes a total aromatic diazonium salt containing compound content of at least 10 weight percent. The molar ratio of the aromatic diazonium salt containing compound having an alkoxy substituent to the aromatic diazonium salt containing compound that is free of an alkoxy substituent is from about 1.0:1 to 70:1. Upon imagewise exposure and development, an imaged element is obtained.

    Abstract translation: 本发明包括可成像元件,其可以是:(a)包含成像层的可成像元件,其包含:含有烷氧基取代基的芳族重氮盐盐化合物和不含烷氧基取代基的含芳族重氮盐的化合物; 聚乙烯醇缩醛粘合剂; 和片基材; 或(b)包含成像层的可成像元件,其包含:含有烷氧基取代基的芳族重氮盐盐化合物和不含烷氧基取代基的含芳族重氮盐盐化合物; 和片状基材。 成像层包括含有至少10重量%的化合物含量的总芳族重氮盐。 具有烷氧基取代基的含芳族重氮盐的化合物与不含烷氧基取代基的含芳族重氮盐化合物的摩尔比为约1.0:1至70:1。 在成像曝光和显影时,获得成像元件。

    Method to reduce imaging effluence in processless thermal printing plates
    32.
    发明授权
    Method to reduce imaging effluence in processless thermal printing plates 失效
    减少无处理热敏印版的成像流出的方法

    公开(公告)号:US06846608B2

    公开(公告)日:2005-01-25

    申请号:US09998685

    申请日:2001-11-29

    Abstract: A method to reduce effluence during or immediately after imaging of a printing plate is described. In one embodiment of the invention, the method comprises: (a) applying to a substrate a coating composition comprising a photothermal converter and at least one polymer comprising thiosulfate groups to obtain a coating; and (b) applying a water soluble topcoat to the coating. Preferably, the water soluble topcoat does not comprise a photothermal converter. In another embodiment of the invention, the method comprises applying to a substrate a composition comprising: (a) a photothermal converter; (b) at least one polymer comprising thiosulfate groups; and (c) an additive selected from the group consisting of diazonium, iodonium, copper(I), alkoxypyridinium or maleimide additives.

    Abstract translation: 描述了在印版成像期间或之后立即降低流出液的方法。 在本发明的一个实施方案中,所述方法包括:(a)将包含光热转化器和至少一种包含硫代硫酸盐基团的聚合物的涂料组合物涂覆于基材以获得涂层; 和(b)向涂层施加水溶性面漆。 优选地,水溶性面漆不包含光热转换器。 在本发明的另一个实施方案中,该方法包括向基底施加组合物,其包含:(a)光热转换器; (b)至少一种包含硫代硫酸盐基团的聚合物; 和(c)选自重氮,碘,铜(I),烷氧基吡啶鎓或马来酰亚胺添加剂的添加剂。

    Imaging members with ionic multifunctional epoxy compounds
    33.
    发明授权
    Imaging members with ionic multifunctional epoxy compounds 失效
    成像用离子多官能环氧化合物

    公开(公告)号:US06841335B2

    公开(公告)日:2005-01-11

    申请号:US10207583

    申请日:2002-07-29

    Abstract: An imaging member, such as a negative-working printing plate or on-press cylinder, can be prepared using a hydrophilic imaging layer comprising a hydrophilic heat-sensitive polymer containing a crosslinking agent comprising ionic groups and epoxy groups. This polymer may comprise quaternary ammonium carboxylate groups which may include at least one substituted-alkylene(C1-C3)-phenyl group. The imaging member also includes an infrared radiation sensitive material to provide added sensitivity to heat that can be supplied by laser irradiation in the IR region. The heat-sensitive polymer may be “switchable” in response to heat, and provides a lithographic image without wet processing.

    Abstract translation: 可以使用包含含有包含离子基团和环氧基团的交联剂的亲水性热敏性聚合物的亲水性成像层来制备成像构件,例如负性印刷板或压印滚筒。 该聚合物可以包含可以包括至少一个取代的亚烷基(C 1 -C 3) - 苯基的季铵羧酸酯基团。 成像构件还包括红外辐射敏感材料,以提供可以通过IR区域中的激光照射提供的热量的增加的灵敏度。 热敏聚合物可以响应于热量而“可切换”,并提供平版印刷图像而不进行湿法处理。

    Manufacture of masks and electronic parts
    35.
    发明申请
    Manufacture of masks and electronic parts 审中-公开
    面具和电子零件的制造

    公开(公告)号:US20030190533A1

    公开(公告)日:2003-10-09

    申请号:US10354838

    申请日:2003-01-30

    Abstract: Imageable precursors for masks and for electronic parts comprise a polymeric layer applied to a substrate. The layer comprises at least one polymer having infra-red absorbing groups carried as pendent groups on the polymer backbone. Certain infrared absorbing groups may also act to insolubilize the polymer in a developer, until it is imagewise exposed to infra-red radiation. Imagewise application of heat, resulting from imagewise exposure of the precursor to infra-red radiation, renders the polymer layer more soluble in the developer than prior to exposure to the infra-red radiation.

    Abstract translation: 用于掩模和电子部件的可成像前体包括施加到基底的聚合物层。 该层包含至少一种聚合物,其具有在聚合物主链上作为悬挂基团携带的红外线吸收基团。 某些红外吸收基团也可以起作用以使显影剂中的聚合物不溶解,直到其成像曝光于红外辐射。 由于将前体成像曝光到红外辐射而产生的图像上的热量使得聚合物层比暴露于红外线辐射之前更易于在显影剂中溶解。

    Method and equipment for using photo-or thermally imagable, negatively working patterning compositions
    37.
    发明申请
    Method and equipment for using photo-or thermally imagable, negatively working patterning compositions 失效
    使用光或热成像,负面工程图案化组合物的方法和设备

    公开(公告)号:US20030157429A1

    公开(公告)日:2003-08-21

    申请号:US10038740

    申请日:2002-01-03

    Abstract: A method for imaging patterning compositions comprising the steps of: (1) providing at least one patterning composition layer on a substrate; said patterning composition comprising: (a) at least one acid generator; (b) at least one cross linking resin or compound; (c) at least one binder resin comprising a polymer containing reactive pendant group selected from group consisting of hydroxyl, carboxylic acid, sulfonamide, active imide, alkoxymethylamides and mixtures thereof; and (d) at least one infrared absorber; (2) imagewise exposing the patterning composition layer to actinic radiation; (3) treating the imaged patterning composition layer with heat energy to treat the imaged portions of the composition layer; (4) flood exposing the heat-treated, imaged patterning composition layer with UV light for a predetermined time, said time being sufficient to promote the effective clear-out of non-imaged portions during the developing step without causing substantial deterioration of the imaged portions; and (5) developing the flood exposed, heat-treated imaged patterning composition with an aqueous alkaline developer to remove the non-imaged areas of the patterning composition layer and leaving the imaged areas substantially unaffected.

    Abstract translation: 一种用于成像图案化组合物的方法,包括以下步骤:(1)在基底上提供至少一个图案化组合物层; 所述图案化组合物包含:(a)至少一种酸发生剂; (b)至少一种交联树脂或化合物; (c)至少一种粘合剂树脂,其包含含有选自羟基,羧酸,磺酰胺,活性酰亚胺,烷氧基甲基酰胺及其混合物的反应性侧基的聚合物; 和(d)至少一个红外线吸收剂; (2)将图案化组合物层成像曝光于光化辐射; (3)用热能处理成像的图案化组合物层以处理组合物层的成像部分; (4)使用UV光曝光经热处理的成像图案化组合物层达预定时间,所述时间足以促进在显影步骤期间非成像部分的有效清除而不引起成像部分的显着劣化 ; 和(5)用含水碱性显影剂显影暴露于曝光的经热处理的成像图案化组合物以除去图案化组合物层的未成像区域,并使成像区域基本上不受影响。

    Spray coating matting method for printing plate precursors
    39.
    发明申请
    Spray coating matting method for printing plate precursors 失效
    用于印版前体的喷涂消光方法

    公开(公告)号:US20020086116A1

    公开(公告)日:2002-07-04

    申请号:US09751184

    申请日:2000-12-29

    CPC classification number: B05D1/04 C09D131/04 C09D133/02 C09D139/06

    Abstract: A method for applying a matting layer to a radiation-sensitive layer of a printing plate precursor comprises: (a) providing a matting composition comprising a polymer and a solvent, wherein the matting composition has a solid content of more than 10% and no more than 50% by weight based on the total composition; and (b) spraying the matting composition on the radiation-sensitive layer using an electrostatically aided rotary atomizer having a bell speed of more than 10,000 rpm, wherein the distance between the bell and the radiation-sensitive layer to be coated is less than 50 cm.

    Abstract translation: 将消光层施加到印版前体的辐射敏感层的方法包括:(a)提供包含聚合物和溶剂的消光组合物,其中所述消光组合物的固体含量大于10%且不超过 基于总组合物重量的50%; 和(b)使用具有大于10,000rpm钟速的静电辅助旋转雾化器将消光组合物喷射在辐射敏感层上,其中钟罩和待涂布的辐射敏感层之间的距离小于50cm 。

    Lithographic printing plates with a sol-gel layer
    40.
    发明授权
    Lithographic printing plates with a sol-gel layer 失效
    具有溶胶 - 凝胶层的平版印刷版

    公开(公告)号:US6136508A

    公开(公告)日:2000-10-24

    申请号:US145164

    申请日:1998-09-02

    CPC classification number: B41C1/1041 B41C1/10 B41M5/40 Y10S430/146

    Abstract: A precursor element for making a lithographic printing plate is composed of a support, an ink receptive thermal conversion inner layer and a sol-gel, ink repellent outer layer. The outer sol-gel layer containes crosslinked colloids derived from certain metal oxides or hydroxides. The plates produced from the ellements are long-running plates that require no post-imaging processing.

    Abstract translation: 用于制造平版印刷版的前体元件由支撑体,吸墨热转换内层和溶胶 - 凝胶,拒油外层组成。 外溶胶 - 凝胶层含有衍生自某些金属氧化物或氢氧化物的交联胶体。 由这些产品生产的板材是不需要后成像处理的长跑板。

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