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公开(公告)号：US4365062A
公开(公告)日：1982-12-21
申请号：US152153
申请日：1980-05-21
IPC分类号： C07D501/04 , A61K31/545 , A61K31/546 , A61P31/04 , C07D253/075 , C07D257/04 , C07D317/28 , C07D501/00 , C07D501/06 , C07D501/14 , C07D501/20 , C07D501/24 , C07D501/26 , C07D501/60
CPC分类号： C07D253/075 , C07D257/04 , C07D317/28 , C07D501/00 , C07D501/24
摘要： New cephalosporins of the formula: ##STR1## in which n=0 or 1, R.sub.1 is a radical of the formula: ##STR2## [in which R.sub.4 is a protective radical and R.sub.5 is hydrogen, alkyl, vinyl, cyanomethyl or a protective radical], or R.sub.1 is a protective radical and R.sub.2 is a protective radical or an enzymatically removable radical, or R.sub.1 is an acyl radical which may be substituted in various ways and R.sub.2 is a protective radical, in the 3-oxoethyl-bicyclooct-2-ene or -bicyclooct-3-ene or 3-oxoethylidene-bicyclooctane form if n=0, and in the 3-oxoethyl-bicyclooct-2-ene or 3-oxoethylidene-bicyclooctane form if n=1, are useful as intermediates for the preparation of 3-thiovinyl-cephalosporins useful as antibacterial agents.
摘要翻译： 式（I）的新型头孢菌素，其中n = 0或1，R1是下式的基团：其中R 4是保护基，R 5是氢，烷基，乙烯基 ，氰基甲基或保护基]，或R 1是保护基，R 2是保护基或可酶还原的基团，或者R 1是可以以各种方式被取代的酰基，R 2是保护基， 如果n = 0，则为3-氧代乙基 - 双环辛-2-烯或双环辛-3-烯或3-氧亚乙基 - 双环辛烷，如果n = 1，则为3-氧代乙基 - 双环辛-2-烯或3-氧亚乙基 - 双环辛烷， 可用作制备用作抗菌剂的3-硫代乙烯基 - 头孢菌素的中间体。
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公开(公告)号：US4351969A
公开(公告)日：1982-09-28
申请号：US244688
申请日：1981-03-17
申请人： Jacques Bourdon
发明人： Jacques Bourdon
CPC分类号： C07C37/07
摘要： Chlorophenols are prepared by thermally dehydrochlorinating a corresponding chlorocyclohexanone in the presence of a catalyst having the formula: ##STR1## wherein A is phosphorus or arsenic, R.sub.1 and R.sub.2, which are identical or different, are each hydrogen, an alkyl radical having from 1 to 12 carbon atoms, a phenyl radical or a radical --NR.sub.4 R.sub.5, in which R.sub.4 and R.sub.5, which are identical or different, are each H or an alkyl radical having from about 1 to 5 carbon atoms, R.sub.3 is an alkyl radical having from 1 to 12 carbon atoms, a phenyl radical or a radical --NR.sub.4 R.sub.5, in which R.sub.4 and R.sub.5 are as defined above, and n is equal to 0 or 1.
摘要翻译： 在具有下式的催化剂存在下，通过对相应的氯代环己酮进行热脱氯化氢来制备氯酚：其中A是磷或砷，R 1和R 2各自相同或不同，具有1至 12个碳原子，苯基或基团-NR4R5，其中R4和R5相同或不同，各自为H或具有约1至5个碳原子的烷基，R3为具有1至 12个碳原子，苯基或基团-NR4R5，其中R4和R5如上所定义，n等于0或1。
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公开(公告)号：US4350671A
公开(公告)日：1982-09-21
申请号：US199645
申请日：1980-10-22
IPC分类号： C01B25/223 , C01B25/225 , C01B25/16
CPC分类号： C01B25/225 , C01B25/223
摘要： Phosphoric acid is produced by a wet process in a homogeneous medium from calcium phosphate ore, sulphuric acid and a continuously added aqueous solution of recycled acid.Part of the phosphate is treated in a primary reaction medium, prepared separately and differing in composition from the final medium sought. By regulating the compositions of the various reaction media, the present process advantageously increases the concentration of the phosphoric acid produced and/or enhances the quality of filtration, along with other advantages.The process can advantageously be applied for the economic treatment of low-grade, poorly reactive or unground phosphates.
摘要翻译： 在磷酸钙矿石，硫酸和连续添加的再循环水溶液的均匀介质中通过湿法制备磷酸。 磷酸盐的一部分在初级反应介质中处理，单独制备，组成与所要求的最终培养基不同。 通过调节各种反应介质的组成，本发明方法有利地增加所产生的磷酸的浓度和/或提高过滤质量以及其它优点。 该方法可以有利地用于经济处理低级，低反应性或未接地磷酸盐。
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公开(公告)号：US4343743A
公开(公告)日：1982-08-10
申请号：US213472
申请日：1980-12-05
申请人： Jean Coquard , Jean Goletto
发明人： Jean Coquard , Jean Goletto
CPC分类号： C08G69/44
摘要： Random or regularly recurring block polyesteramides having glass transition temperatures at least as low as -30.degree. C. are prepared from (i) essentially difunctional monomers comprising at least one carboxylic acid function, or ester/amide-forming derivative thereof, at least 1 mol % of which comprising dicarboxylic acids or such derivatives thereof and having from 20 to 60 carbon atoms, with the amount of monofunctional carboxylic acids comprising said carboxyl monomers being less than about 1% by weight and the amount of carboxylic acids having in excess of two functional groups being less than about 5% by weight, and (ii) a member selected from the group consisting of dihydroxyl and diamino comonomers therefor, or aminoalcohol comonomers, or mixtures of diamino and aminoalcohol comonomers.
摘要翻译： 玻璃化转变温度至少低至-30℃的随机或定期重复的聚酯酰胺由（i）至少1摩尔的至少一种羧酸官能团或其成酯/酰胺形成衍生物的双官能单体制备， 其中％包含二羧酸或其衍生物并具有20至60个碳原子，其中包含所述羧基单体的单官能羧酸的量小于约1重量％，并且具有超过两个官能团的羧酸的量 基团小于约5重量％，和（ii）选自二羟基和二氨基共聚单体或氨基醇共聚单体，或二氨基和氨基醇共聚单体的混合物的成员。
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35.发明授权Extraction of uranium using electrolytic oxidization and reduction in bath compartments of a single cell 失效使用电解氧化和在单个电池的浴室中还原来提取铀
公开(公告)号：US4341602A
公开(公告)日：1982-07-27
申请号：US065504
申请日：1979-08-10
申请人： Thomas Nenner , Dominique Foraison
发明人： Thomas Nenner , Dominique Foraison
CPC分类号： C22B60/026 , C25B1/00
摘要： The invention relates to a process for the recovery and the concentration of uranium (VI) contained in an organic phase. The organic phase is treated continuously in a contact zone with an aqueous solution containing an oxidizing-reducing agent in the reduced state, said oxidizing-reducing agent being capable of reducing U.sup.+6 to U.sup.+4 in said aqueous solution. The aqueous solution employed in the process issues in part or in its entirety from the cathodic compartment of an electrolytic separation cell, which is under a direct current potential, and the aqueous phase issuing from the contact zone feeds in part or in its entirety the anodic compartment of the electrolytic cell. The process is of particular interest when applied to the recovery and concentration of uranium contained in a wet process phosphoric acid.
摘要翻译： 本发明涉及有机相中所含的铀（Ⅵ）的回收和浓缩方法。 在与含有还原状态的氧化还原剂的水溶液的接触区域中连续处理有机相，所述氧化还原剂能够在所述水溶液中还原U + 6至U + 4。 在该方法中使用的水溶液部分或全部由电解分离池的阴极室处于直流电位，并且从接触区发出的水相部分或全部进入阳极 电解池的隔室。 当应用于湿法磷酸中所含的铀的回收和浓缩时，该方法是特别有意义的。
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公开(公告)号：US4325923A
公开(公告)日：1982-04-20
申请号：US155119
申请日：1980-05-30
申请人： Roger Botton , Dominique Cosserat
发明人： Roger Botton , Dominique Cosserat
CPC分类号： B01D53/62 , B01D3/26 , B01D47/021 , B01D53/8609 , B01D53/8625 , Y10S261/75
摘要： Intimate and efficient contacting of plural, physically disparate phases, e.g., a gas and a liquid, is achieved by contacting the phases cocurrently in a column. The gas phase is introduced at a velocity between its phase transition inversion point (T) and multiple critical point (M.sub.c) velocities, which velocity is sufficient to create a dispersion of the second phase, i.e., the liquid phase, in the gas and thereby establish at most the following zones, from bottom to top, in the column: a bottom zone of constant liquid concentration designated the emulsion zone, a zone of decreasing liquid concentration, and a zone of constant liquid concentration wherein the liquid exists in the form of droplets. The feed velocity of the liquid is adjusted accordingly to provide a mass liquid concentration value in the emulsion that is between the mass liquid concentration value transition inversion point and multiple critical point values.
摘要翻译： 通过在柱中并流接触相，实现多个物理上不同相（例如气体和液体）的紧密和有效的接触。 气相以其相转变反转点（T）和多临界点（Mc）速度之间的速度引入，该速度足以产生第二相（即液相）在气体中的分散，从而 在塔中至少建立以下区域：从底部到顶部的塔：恒定液体浓度的底部区域指定为乳液区域，液体浓度降低的区域和恒定液体浓度区域，其中液体以 液滴。 相应地调节液体的进料速度以提供在质量液体浓度值转变反转点和多个临界点值之间的乳液中的质量液体浓度值。
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37.发明授权Preparation of water soluble polymeric flocculants by photopolymerization of hydrophilic monomers 失效通过亲水单体的光聚合制备水溶性聚合物絮凝剂
公开(公告)号：US4308148A
公开(公告)日：1981-12-29
申请号：US46488
申请日：1979-06-07
申请人： Jean Boutin , Jean Neel
发明人： Jean Boutin , Jean Neel
CPC分类号： C08F2/50
摘要： Water soluble polymeric flocculants are prepared by photopolymerizing olefinically unsaturated hydrophilic monomer(s), the photopolymerization recipe including a polyhydroxylated organic additive, such as gluconic acid. Such polyhydroxy compound facilitates solubilization of the resultant flocculants, without substantial decrease in the molecular weight thereof, and ensures against the by-production of water insoluble fractions.
摘要翻译： 通过光聚合烯属不饱和亲水性单体制备水溶性聚合物絮凝剂，光聚合配方包括多羟基化有机添加剂如葡萄糖酸。 这样的多羟基化合物有助于所得絮凝剂的溶解，而不会显着降低其分子量，并且确保不会产生不溶于水的级分。
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公开(公告)号：US4307233A
公开(公告)日：1981-12-22
申请号：US152085
申请日：1980-05-21
IPC分类号： A61K20060101 , A61K31/545 , A61K31/546 , A61P3/02 , A61P31/04 , C07D20060101 , C07D501/00 , C07D501/04 , C07D501/14 , C07D501/18 , C07D501/20 , C07D501/24 , C07D501/38 , C07D501/46 , C07D501/58 , C07D501/60
CPC分类号： C07D501/14
摘要： Novel 3-vinyl-cephalosporin derivates of the general formula ##STR1## in the bicyclooct-2-ene or bicyclooct-3-ene form, in which R.sub.1 is a protective radical or is a radical of the general formula ##STR2## in which R.sub.5 is hydrogen, alkyl, vinyl or cyanomethyl, or a protective radical, and R.sub.6 is hydrogen or a protective radical, and R.sub.2 is a protective radical or an enzymatically removable radical, or R.sub.1 is an acyl radical, which may carry various substituents, and R.sub.2 represents a protective radical, and R.sub.3 and R.sub.4, which are identical or different, represent alkyl (optionally substituted by hydroxyl, alkoxy, amino, alkylamino or dialkylamino) or phenyl, or form, together with the nitrogen atom, a saturated 5-membered or 6-membered heterocyclic ring optionally containing another hetero-atom, their E- and Z-forms and their mixtures, are useful as intermediates for the preparation of 3-thiovinyl cephalosporins useful as antibacterial agents.
摘要翻译： 双环-2-烯或双环-3-烯形式的新颖的3-乙烯基 - 头孢菌素衍生物，其中R 1是保护基或是通式为“IMAGE”的基团， （II），其中R 5是氢，烷基，乙烯基或氰基甲基或保护基，R 6是氢或保护基，R 2是保护基或可酶解的基，或者R 1是酰基， 并且R 2表示保护基，R 3和R 4相同或不同，代表烷基（任选被羟基，烷氧基，氨基，烷基氨基或二烷基氨基）或苯基取代，或与氮原子一起形成， 任选地含有另一个杂原子的饱和5元或6元杂环，它们的E-和Z-形式及其混合物可用作制备用作抗菌剂的3-硫代乙烯基头孢菌素的中间体。
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公开(公告)号：US4307116A
公开(公告)日：1981-12-22
申请号：US152115
申请日：1980-05-21
IPC分类号： A61K20060101 , A61K31/545 , C07D20060101 , C07D277/38 , C07D417/12 , C07D501/00 , C07D501/24 , C07D501/36 , C07D501/46
CPC分类号： C07D501/24
摘要： Novel cephalosporins of the general formula (I); ##STR1## in which R is alkyl, L-2-amino-2-carboxy-ethyl, phenyl, pyridyl, pyridyl-N-oxide, pyrimidin-2-yl, substituted pyridazin-3-yl, 5,6-dioxo-1,4,5,6-tetrahydro-1,2,4-triazin-3-yl substituted in the 4-position, 1,3,4-triazol-5-yl or 2-alkoxycarbonyl-1,3,4-triazol-5-yl substituted in the 1-position, 1,4-dialkyl-5,6-dioxo-1,4,5,6-tetrahydro-1,2,4-triazin-3-yl, 1-alkyl-5,6-dioxo-1,4,5,6-tetrahydro-1,2,4-triazin-3-yl, 2-alkyl-5,6-dioxo-1,2,5,6-tetrahydro-1,2,4-triazin-3-yl, triazol-5-yl, 1,3,4-thiadiazol-5-yl which is substituted or unsubstituted, 1,2,4-thiadiazol-5-yl which is substituted, 1,3,4-oxadiazol-5-yl which is substituted or unsubstituted, oxazol-2-yl which is substituted or unsubstituted or tetrazol-5-yl which is substituted or unsubstituted in the 1-position, R' is a hydrogen atom or a radical of the general formula (II); ##STR2## and R.sup.o is hydrogen, alkyl, vinyl or cyanomethyl, as well as their salts, are useful as anti-bacterial agents.
摘要翻译： 通式（I）的新型头孢菌素; （I）其中R是烷基，L-2-氨基-2-羧基 - 乙基，苯基，吡啶基，吡啶基-N-氧化物，嘧啶-2-基，取代的哒嗪-3-基，5,6 在4-位取代的1-二氧代-1,4,5,6-四氢-1,2,4-三嗪-3-基，1,3,4-三唑-5-基或2-烷氧基羰基-1,3 在1-位上取代的4-三唑-5-基，1,4-二烷基-5,6-二氧代-1,4,5,6-四氢-1,2,4-三嗪-3-基，1 - 烷基-5,6-二氧代-1,4,5,6-四氢-1,2,4-三嗪-3-基，2-烷基-5,6-二氧代-1,2,5,6-四氢 -1,2,4-三嗪-3-基，三唑-5-基，取代或未取代的1,3,4-噻二唑-5-基，被取代的1,2,4-噻二唑-5-基 被取代或未取代的取代或未取代的1,3,4-恶二唑-5-基，在1位被取代或未取代的四唑-5-基，R'是氢 原子或通式（II）的基团; （II）和Ro是氢，烷基，乙烯基或氰基甲基，以及它们的盐可用作抗细菌剂。
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公开(公告)号：US4301021A
公开(公告)日：1981-11-17
申请号：US136545
申请日：1980-04-02
申请人： Claude Breant
发明人： Claude Breant
CPC分类号： C11B9/0007
摘要： Perfumed compositions include, as an odorant therefor, an olfactory affecting amount of N,N-diethyl-2-ethylhexanamide.
摘要翻译： 香料组合物包括作为其加臭剂的嗅觉影响量的N，N-二乙基-2-乙基己酰胺。
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