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    Tantalum catalysts or catalyst precursors
    34.
    发明授权
    Tantalum catalysts or catalyst precursors 失效
    钽催化剂或催化剂前体

    公开(公告)号：US4197419A

    公开(公告)日：1980-04-08

    申请号：US969896

    申请日：1978-12-15

    申请人： Richard R. Schrock

    发明人： Richard R. Schrock

    IPC分类号： C07C2/34 ,  C07F9/00 ,  C07C3/21

    CPC分类号： C07C2/34 ,  C07F9/00 ,  C07C2531/22

    摘要： Tantalum catalysts or catalyst precursors of the formula ##STR1## wherein X is a halide, or alkoxide and L is an alkene (CH.sub.2 .dbd.CHR) having from 2 to 20 carbon atoms, react with 1-olefins to give catalysts of the formula ##STR2## wherein R.sup.2 is hydrogen or a C.sub.1 to C.sub.18 alkyl such as methyl, ethyl, or propyl. The catalysts or catalyst precursors selectively dimerize 1-olefins to the two possible disubstituted .alpha.-olefin dimers, the ratio of which depends on the nature of R.

    摘要翻译： 钽催化剂或下式的催化剂前体，其中X是卤化物或醇盐，L是具有2-20个碳原子的烯烃（CH 2 = CHR），与1-烯烃反应得到下式的催化剂：IMAGE >其中R2是氢或C1-C18烷基如甲基，乙基或丙基。 催化剂或催化剂前体选择性地将1-烯烃二聚成两种可能的二取代α-烯烃二聚体，其比例取决于R的性质。

    Process for dimerizing lower alpha-olefins
    38.
    发明授权
    Process for dimerizing lower alpha-olefins 失效
    二甲基脂肪醇的方法

    公开(公告)号：US3553280A

    公开(公告)日：1971-01-05

    申请号：US3553280D

    申请日：1968-05-31

    申请人： GRACE W R & CO

    发明人： KETLEY ARTHUR D

    IPC分类号： C07C2/32 ,  C07C2/34 ,  C07C3/18

    CPC分类号： C07C2/34 ,  C07C2/32 ,  C07C2531/22 ,  Y10S585/951

    摘要： A METHOD FOR DIMERIZING A LOWER ALPHA OLEFIN, SAID METHOD COMPRISING CONTACTING THE LOWER ALPHA OLEFIN WITH A CATALYTIC AMOUNT OF A COMPLEX HAVING THE FORMULA R2PD2CL4, WHERE R REPRESENTS A LOWER ALPHA OLEFIN MOLECULE, IN A REACTION MEDIUM SELECTED FROM THE GROUP CONSISTING OF; (I) CHLOROFORM CONTAINING A SMALL AMOUNT OF WATER OR A LOWER MONOHYDRIC ALCOHOL; (II) ANISOLE; (III) METHYLENE CHLORIDE; (IV) NITROBENZENE; AND (V) NITROETHANE, AT ABOUT 0-50*C., UNDER A PRESSURE OF ABOUT 1-2000 ATMOSPHERE ABSOLUTE, FOR ABOUT 0.5-100 HOURS, AND SEPARATING AND RECOVERING THE DIMERIZED OLEFIN.

    Process of producing pai-allyl metal anion compounds
    39.
    发明授权
    Process of producing pai-allyl metal anion compounds 失效
    生产PAI-ALLYL金属阴离子化合物的方法

    公开(公告)号：US3424777A

    公开(公告)日：1969-01-28

    申请号：US3424777D

    申请日：1964-08-06

    申请人： STUDIENGESELLSCHAFT KOHL M B H

    发明人： WILKE GUNTHER

    IPC分类号： B01J31/22 ,  C07C2/34 ,  C07C2/40 ,  C07F5/00 ,  C07F7/00 ,  C07F7/28 ,  C07F9/00 ,  C07F11/00 ,  C07F15/00 ,  C07F15/02 ,  C07F15/04 ,  C07F15/06 ,  C07F17/00 ,  C08F2/00 ,  C08F4/619 ,  C08F10/00 ,  C08F36/04

    CPC分类号： B01J31/2291 ,  B01J31/2295 ,  B01J2231/12 ,  B01J2231/20 ,  B01J2531/40 ,  B01J2531/48 ,  B01J2531/50 ,  B01J2531/60 ,  B01J2531/62 ,  B01J2531/66 ,  B01J2531/70 ,  B01J2531/80 ,  B01J2531/824 ,  B01J2531/828 ,  B01J2531/845 ,  B01J2531/847 ,  C07C2/34 ,  C07C2/406 ,  C07C2527/125 ,  C07C2531/02 ,  C07C2531/14 ,  C07C2531/22 ,  C07F5/00 ,  C07F7/00 ,  C07F7/28 ,  C07F9/00 ,  C07F11/00 ,  C07F15/0006 ,  C07F15/006 ,  C07F15/0086 ,  C07F15/02 ,  C07F15/04 ,  C07F15/06 ,  C07F17/00 ,  C08F4/619 ,  C08F10/00 ,  C08F36/04 ,  C08F2410/03 ,  C07C11/21 ,  C08F4/602 ,  C08F4/69025 ,  C08F4/605 ,  C08F4/69275 ,  C08F4/74 ,  C08F4/72 ,  C08F4/6411 ,  C08F4/7027 ,  C08F4/7052 ,  C08F4/7004 ,  C08F4/7088 ,  C08F4/7086

    摘要： Olefines such as mono-olefines and diolefines or mixtures thereof may be oligomerized using p -allyl metal compounds or p -allyl metal halides wherein the metal is a transition metal of Groups IV-VIII. Lewis acids such as organoaluminium compounds and aluminium halides, and Lewis bases such as (a) the alkyl, cycloalkyl, aralkyl or aryl compounds of elements of Group V other than nitrogen, (b) the tri-alkyl, -cycloalkyl, -aralkyl or -aryl esters of elements of Group V other than nitrogen, as well as their triamides and (e) dialkyl sulphoxides may be added. In the examples, butadiene, ethylene, propylene and butene-2 are separately oligomerized, mostly to dimers; also butene-2 and ethylene; ethylene and propylene; and ethylene and cyclohexene are codimerized.ALSO:Olefines such as mono-olefines and diolefines may be polymerized using p -allyl metal compounds or p -allyl metal halides wherein the metal is from Group IVa to VIIa or VIII of the specified Periodic System. Lewis acids such as organo aluminium compounds or aluminium halides and Lewis bases such as (a) the alkyl, cycloalkyl, aralkyl or aryl compounds of elements of Group V other than nitrogen, (b) the tri-alkyl, -cycloalkyl, -aralkyl or -aryl esters of elements of Group V other than nitrogen, as well as their triamides and (c) dialkyl sulphoxides, may also be present. In the examples:-(1) ethylene is polymerized using tris-p -allyl chromium, bis-p -allyl chromium iodide or bisp -allyl chromium chloride; (2) butadiene is polymerized using tetra-p -allyl chromium, tris-p -allyl-vanadium, p -allyl-nickel chloride and ethyl aluminium dichloride, tris-p -allyl chromium, tris-p -allyl cobalt, bis-p -allyl cobalt iodide and ethyl aluminium dichloride, bis-p -allyl cobalt iodide and aluminium bromide, bis-p -allyl cobalt chloride and diethyl aluminium chloride or ethyl aluminium dichloride, p -allyl cobalt diiodide, triphenyl phosphine and aluminium bromide; (3) propylene is polymerized using vanadium tetrachloride and p -allyl-magnesium chloride and (4) isoprene is polymerized using p -allyl nickel chloride and ethyl aluminium dichloride.ALSO:Catalysts for the oligomerization and polymerization of olefines comprise p -allyl compounds of metals or p -allyl metal halides wherein the metal is from Group IVA to VIIA or VIII of the specified Periodic System together with a Lewis acid and/or a Lewis base. The Lewis acids may be organoaluminium compounds or aluminium halides and the Lewis bases may be (a) the alkyl, cycloalkyl, aralkyl or aryl compounds of Group V elements other than nitrogen, (b) the tri-alkyl, -cycloalkyl, -aralkyl or-aryl esters of Group V elements other than nitrogen, as well as their triamides and (c) dialkyl sulphoxides. Many examples are given, the p -allyl compounds or halides used being tris-p -allyl chromium, bis-p -allyl chromium iodide, bis-p -allyl-chromium chloride, tris-p -allyl cobalt, bis-p -allyl cobalt iodide, bis-p -allyl cobalt chloride, p -allyl cobalt di-iodide, p -cyclooctatrienyl-nickel chloride, p -cyclo-octenyl nickel chloride, p -allyl-nickel iodide, p -allyl magnesium chloride, p -pineneyl-nickel bromide, p -allyl nickel bromide, p -crotyl nickel iodide, p -cinanmyl nickel chloride; 1, 2, 3-triphenyl-p -cyclopropenyl nickel bromide; p -allyl palladium chloride, p -allyl nickel chloride, tetra-p -allyl zirconium, tris-p -allyl vanadium and C12 H19 NiCl.

    pi-allyl metal compounds and their use as polymerization, including oligomerization, catalysts
    40.
    发明授权
    pi-allyl metal compounds and their use as polymerization, including oligomerization, catalysts 失效
    pi烯丙基金属化合物及其作为聚合反应的用途，包括低聚反应，催化剂

    公开(公告)号：US3379706A

    公开(公告)日：1968-04-23

    申请号：US38782664

    申请日：1964-08-06

    申请人： STUDIENGESELLSCHAFT M B H

    发明人： GUNTHER WILKE

    IPC分类号： B01J31/22 ,  C07C2/34 ,  C07C2/40 ,  C07F5/00 ,  C07F7/00 ,  C07F7/28 ,  C07F9/00 ,  C07F11/00 ,  C07F15/00 ,  C07F15/02 ,  C07F15/04 ,  C07F15/06 ,  C07F17/00 ,  C08F2/00 ,  C08F4/619 ,  C08F10/00 ,  C08F36/04

    CPC分类号： B01J31/2291 ,  B01J31/2295 ,  B01J2231/12 ,  B01J2231/20 ,  B01J2531/40 ,  B01J2531/48 ,  B01J2531/50 ,  B01J2531/60 ,  B01J2531/62 ,  B01J2531/66 ,  B01J2531/70 ,  B01J2531/80 ,  B01J2531/824 ,  B01J2531/828 ,  B01J2531/845 ,  B01J2531/847 ,  C07C2/34 ,  C07C2/406 ,  C07C2527/125 ,  C07C2531/02 ,  C07C2531/14 ,  C07C2531/22 ,  C07F5/00 ,  C07F7/00 ,  C07F7/28 ,  C07F9/00 ,  C07F11/00 ,  C07F15/0006 ,  C07F15/006 ,  C07F15/0086 ,  C07F15/02 ,  C07F15/04 ,  C07F15/06 ,  C07F17/00 ,  C08F4/619 ,  C08F10/00 ,  C08F36/04 ,  C08F2410/03 ,  C07C11/21 ,  C08F4/602 ,  C08F4/69025 ,  C08F4/605 ,  C08F4/69275 ,  C08F4/74 ,  C08F4/72 ,  C08F4/6411 ,  C08F4/7027 ,  C08F4/7052 ,  C08F4/7004 ,  C08F4/7088 ,  C08F4/7086

    摘要： Olefines such as mono-olefines and diolefines or mixtures thereof may be oligomerized using p -allyl metal compounds or p -allyl metal halides wherein the metal is a transition metal of Groups IV-VIII. Lewis acids such as organoaluminium compounds and aluminium halides, and Lewis bases such as (a) the alkyl, cycloalkyl, aralkyl or aryl compounds of elements of Group V other than nitrogen, (b) the tri-alkyl, -cycloalkyl, -aralkyl or -aryl esters of elements of Group V other than nitrogen, as well as their triamides and (e) dialkyl sulphoxides may be added. In the examples, butadiene, ethylene, propylene and butene-2 are separately oligomerized, mostly to dimers; also butene-2 and ethylene; ethylene and propylene; and ethylene and cyclohexene are codimerized.ALSO:Olefines such as mono-olefines and diolefines may be polymerized using p -allyl metal compounds or p -allyl metal halides wherein the metal is from Group IVa to VIIa or VIII of the specified Periodic System. Lewis acids such as organo aluminium compounds or aluminium halides and Lewis bases such as (a) the alkyl, cycloalkyl, aralkyl or aryl compounds of elements of Group V other than nitrogen, (b) the tri-alkyl, -cycloalkyl, -aralkyl or -aryl esters of elements of Group V other than nitrogen, as well as their triamides and (c) dialkyl sulphoxides, may also be present. In the examples:-(1) ethylene is polymerized using tris-p -allyl chromium, bis-p -allyl chromium iodide or bisp -allyl chromium chloride; (2) butadiene is polymerized using tetra-p -allyl chromium, tris-p -allyl-vanadium, p -allyl-nickel chloride and ethyl aluminium dichloride, tris-p -allyl chromium, tris-p -allyl cobalt, bis-p -allyl cobalt iodide and ethyl aluminium dichloride, bis-p -allyl cobalt iodide and aluminium bromide, bis-p -allyl cobalt chloride and diethyl aluminium chloride or ethyl aluminium dichloride, p -allyl cobalt diiodide, triphenyl phosphine and aluminium bromide; (3) propylene is polymerized using vanadium tetrachloride and p -allyl-magnesium chloride and (4) isoprene is polymerized using p -allyl nickel chloride and ethyl aluminium dichloride.ALSO:Catalysts for the oligomerization and polymerization of olefines comprise p -allyl compounds of metals or p -allyl metal halides wherein the metal is from Group IVA to VIIA or VIII of the specified Periodic System together with a Lewis acid and/or a Lewis base. The Lewis acids may be organoaluminium compounds or aluminium halides and the Lewis bases may be (a) the alkyl, cycloalkyl, aralkyl or aryl compounds of Group V elements other than nitrogen, (b) the tri-alkyl, -cycloalkyl, -aralkyl or-aryl esters of Group V elements other than nitrogen, as well as their triamides and (c) dialkyl sulphoxides. Many examples are given, the p -allyl compounds or halides used being tris-p -allyl chromium, bis-p -allyl chromium iodide, bis-p -allyl-chromium chloride, tris-p -allyl cobalt, bis-p -allyl cobalt iodide, bis-p -allyl cobalt chloride, p -allyl cobalt di-iodide, p -cyclooctatrienyl-nickel chloride, p -cyclo-octenyl nickel chloride, p -allyl-nickel iodide, p -allyl magnesium chloride, p -pineneyl-nickel bromide, p -allyl nickel bromide, p -crotyl nickel iodide, p -cinanmyl nickel chloride; 1, 2, 3-triphenyl-p -cyclopropenyl nickel bromide; p -allyl palladium chloride, p -allyl nickel chloride, tetra-p -allyl zirconium, tris-p -allyl vanadium and C12 H19 NiCl.