摘要:
Hollow cellulosic fibers are produced by nitrosating and dissolving a cellulosic material in an aprotic solvent selected from the group consisting of a dialkylacylamide and dimethylsulfoxide and regenerating the dissolved cellulose by contacting the cellulose solution with a regenerant. The regenerant is n-octanol where the solvent is a dialkylacylamide and n-hexanol where the solvent is dimethylsulfoxide. The fibers are hollow as regenerated and require no special spinnerette designs nor special spinning conditions.
摘要:
A regenerated cellulosic product is produced by nitrosating and dissolving a cellulosic material in a solution comprising a dialkylacylamide solvent and adding from 2 to 25% by weight, based on the weight of the solution, of a tertiary amine to form a soluble cellulose nitrite ester, contacting the cellulose ester with a coagulant therefore, stretching the coagulated cellulose ester prior to complete regeneration thereof and then completing the regeneration of the cellulose to produce a regenerated cellulosic product.
摘要:
This invention relates to a method for preparing carbohydrateboron alkoxide compounds. Under anhydrous conditions, stable compounds of methyl- Alpha -D-glucoside, methyl- Alpha mannoside, sucrose, cellobiose, methyl cellulose, and cellulose and boron alkoxides, such as boron ethoxide, boron prepoxide, and boron isopropoxide, were prepared in neat boron alkoxide, the parent alcohol, benzene, pyridine, and/or ethylenediamine. The method of this invention has as its objective increasing the reactivity of carbohydrates, as their molecular weights increase, with boron alkoxides by treatment in solutions of strong bases, such as pyridine and ethylenediamine. Formation of carbohydrateboron alkoxide compounds modifies the rate of oxidation of carbohydrates and is related to preparing flame-resistant products.
摘要:
Compositions for sizing textiles are provided which contain a major proportion of a low molecular, highly water soluble dextrin phosphate and a minor proportion of a high molecular nitrogen containing starch phosphate or a polymer selected from water soluble polyvinyl acetates, polyvinyl alcohols and polyacrylates, or of a mixture of such polymer and a high molecular nitrogen containing starch phosphate. The high molecular starch phosphate typically has a viscosity of about 40,000 to 60,000 cps when in 5 percent solution in water at 25* C. The low molecular dextrin phosphate is a thermally degraded phosphorylated starch having between 0.3 and 3 percent by weight of phosphorus molecularly bound therein and having a light color, a solubility higher than 30 percent in water at 25* C. and a viscosity in the range of about 5 to 500 cps when in 5 percent solution in water at 25* C.
摘要:
FINELY DIVIDED STARCH PRODUCTS CLASSIFIED AS DEXTRIN PHOSPHATE, HAVING EXTREMELY LIGHT COLOR, HIGH COLD WATER SOLUBILITY AND LOW AND RELATIVELY STABEL VISCOSITY IN AQUEOUS SOLUTION ARE PROVIDED BY HEATING UNDER LOW VACUUM TO 80-90*C., FOR 2 TO 4 HOURS, A FINELY DIVIDED MIXTURE OF POWDERED STARCH AND AN AQUEOUS SOLUTION OF ALKALI METAL PHOSPHATE AND PHOSPHORIC ACID HAVING A PH BETWEEN 2 AND 5, SUCH AS A PH OF ABOUT 3; THEN HEATING THE MIXTURE UNDER HIGH VACUUM TO AND AT A TEMPERATURE BETWEEN 125* AND 140*C. FOR 1 TO 3 HOURS TO COMPLETE THE DEHYDRATION AND REACTION OF THE MATERIAL; AND THEN COOLING IT WITH EXCLUSION OF OXYGEN, AS UNDER HIGH VACUUM. A WATER SOLUBLE ALDEHYDE REACTED IN THE MIXTURE FURTHER ENHANCES THE STABILITY OF THE PRODUCT. THE DEXTRIN PHOSPHATE CONTAINS 0.3 TO 3% OF MOLECULARLY BOUND PHOSPHORUS. IT IS ESPECIALLY USEFUL IN MIXTURES WITH HIGH MOLECULAR STARCH PRODUCTS AND/OR WATER SOLUBLE SYNTHETIC POLYMERS FOR SIZING TEXTILES, AND IN MIXTURES WITH KETENE DIMERS FOR SURFACE SIZING PAPER TO INHIBIT INK PENETRATION.
摘要:
An object of the present invention is to provide ultrafine fibrous cellulose capable of exhibiting excellent coating suitability when added to paint. The present invention relates to fibrous cellulose having a fiber width of 1,000 nm or less, in which, when the fibrous cellulose is dispersed in water to form a dispersion liquid having a viscosity of 2,500 mPa·s at 23° C., and the dispersion liquid is stirred under predetermined stirring conditions, a viscosity change rate falls within ±50%, calculated by the following formula: viscosity change rate (%)=(viscosity after stirring−viscosity before stirring)/viscosity before stirring×100.