Anthraquinone dyestuffs containing sulphonic acid groups
    32.
    发明授权
    Anthraquinone dyestuffs containing sulphonic acid groups 失效
    含有磺酸基团的蒽醌染料

    公开(公告)号:US3980677A

    公开(公告)日:1976-09-14

    申请号:US614524

    申请日:1975-09-18

    IPC分类号: C09B1/50 C09B1/51 C09B1/52

    摘要: Dyestuffs which contain sulphonic acid groups and correspond to the formula ##SPC1##In which R.sub.1 and R.sub.2 denote lower alkyl radicals with 1 - 3 carbon atoms, which may be substituted; A means an optionally substituted aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radical; n stands for 0, 1 or 2; and R.sub.4 denotes a sulphonic acid group when n = 0 and denotes hydrogen or a sulphonic acid when n = 1 or 2.The dyestuffs are eminently suitable for the dyeing and printing of natural and synthetic polyamide fiber materials.

    摘要翻译: 含有磺酸基团并符合下式的染料:其中R 1和R 2表示可被取代的具有1-3个碳原子的低级烷基; A表示任选取代的脂族,脂环族,芳脂族,芳族或杂环基; n代表0,1或2; 当n = 0时,R 4表示磺酸基,当n = 1或2时,表示氢或磺酸。

    Anthraquinone sulphonium compounds
    34.
    发明授权
    Anthraquinone sulphonium compounds 失效
    蒽醌类化合物

    公开(公告)号:US3876664A

    公开(公告)日:1975-04-08

    申请号:US42929873

    申请日:1973-12-28

    申请人: CIBA GEIGY AG

    IPC分类号: C09B1/60 C09B1/56

    CPC分类号: C09B1/60 C09B1/50

    摘要: Anthraquinone sulphonium compounds of the formula

    Wherein W denotes the charge equivalent of an inorganic anion are useful in the preparation of anthraquinone dyestuffs of the formula

    In which R.sub.1 and R.sub.2 independently of one another each denote hydrogen or a lower alkyl group, X denotes a direct bond, --Ch.sub.2 --, --O-- or --S--, and Y denotes the nitrile group, a thiocarboxylic acid ester group, a carbacyl group, or an optionally substituted aliphatic, cycloaliphatic, carbocyclicaromatic or heterocyclic radical. The dyestuffs yield fast blue shades on polyester fibers.

    Process for dyeing polyacrylonitrile textiles with anthraquinone dyestuffs
    35.
    发明授权
    Process for dyeing polyacrylonitrile textiles with anthraquinone dyestuffs 失效
    用丙烯酸丁酯染色聚丙烯酰胺纺织品的方法

    公开(公告)号:US3792969A

    公开(公告)日:1974-02-19

    申请号:US20341971

    申请日:1971-11-30

    申请人: SANDOZ LTD

    发明人: GERTISSER B

    IPC分类号: C09B1/50 D06P1/20 D06P3/72

    CPC分类号: C09B1/50 C09B1/501

    摘要: Anthraquinone dyes of the formula

    WHEREIN M stands for a divalent radical, W for the nitro group or for an amino group, K e.g. for an ammonium-, hydrazinium- or an amminogroup, A for an anion and wherein the ring B and/or D may be further substituted. They can be used for the dyeing of acrylonitrile polymers or copolymers.

    摘要翻译: 式WHEREIN M的蒽醌染料代表二价基团,W代表硝基或氨基,例如K +。 对于阴离子的铵 - ,腙 - 或氨基 - 氨基 - ,并且其中环B和/或D可进一步被取代。 它们可用于丙烯腈聚合物或共聚物的染色。

    Process for the production of a primary aminoanthraquinone by conversion of an n-cyclohexylaminoanthraquinone
    40.
    发明授权
    Process for the production of a primary aminoanthraquinone by conversion of an n-cyclohexylaminoanthraquinone 失效
    通过转化正环己基氨基蒽醌生产伯氨基蒽醌的方法

    公开(公告)号:US3342831A

    公开(公告)日:1967-09-19

    申请号:US38826564

    申请日:1964-08-07

    申请人: BASF AG

    摘要: Primary amines of the antraquinone series are made by allowing strong sulphuric acid, oleum, chlorosulphonic acid or a melt of aluminium chloride and a melting point depressant to act on a cyclohexylamino-anthraquinone which may be substituted in the anthraquinonyl radical. When sulphuric acid or oleum is used, nitrile or amido groups may be wholly or partly saponified or sulphonic acid groups may be introduced. Preferably the acid reagent is a mixture of aluminium chloride and a compound having the general formula X1COX2 in which X1 denotes hydrogen, halogen, alkyl or amino, and X2 denotes an unsubstituted, mono-allyl- or diallyl-substituted amino group, or, if X1 is hydrogen, an O-metal group, or X1 and X2 when taken together denote an alkylenamino or an a ,o -diamino alkylene radical with 3 to 6 methylene groups which together with the CO group form an inner amide, the amido nitrogen of which may be substituted with an alkyl group. Detailed examples are given in which the products contain chloro, sulphonic acid, cyano, methoxy, carboxylic acid cyclohexylamide, carboxylic acid, hydroxy, or carboxylic amide radicals in addition to amino groups.

    摘要翻译: 蒽醌系列的伯胺通过使强硫酸,发烟硫酸,氯磺酸或氯化铝熔体和熔点降低剂作用于可在蒽醌基中取代的环己基氨基 - 蒽醌来制备。 当使用硫酸或发烟硫酸时,腈或酰氨基可以全部或部分皂化,或者可以引入磺酸基团。 优选地,酸试剂是氯化铝和具有通式X1COX2的化合物的混合物,其中X1表示氢,卤素,烷基或氨基,X2表示未取代的单烯丙基或二烯丙基取代的氨基,或如果 X1是氢,O-金属基,或X1和X2,它们一起表示亚烷基氨基或具有3至6个亚甲基的a,o-二氨基亚烷基,其与CO基一起形成内酰胺,酰氨基氮 其可以被烷基取代。 给出了除了氨基以外,产物含有氯,磺酸,氰基,甲氧基,羧酸环己酰胺,羧酸,羟基或羧酰胺基的详细实例。