公开(公告)号：US20150368748A1

公开(公告)日：2015-12-24

申请号：US14498798

申请日：2014-09-26

申请人： Johnson Controls Technology Company

发明人： Eberhard Meissner ,  Jürgen Bauer ,  Matthew A. Spence

IPC分类号： C22B3/00 ,  B01J8/00 ,  C22B3/02 ,  C22B3/04

CPC分类号： H01M10/54 ,  B01J6/001 ,  B01J6/002 ,  B01J8/008 ,  B01J19/06 ,  B01J19/2465 ,  B01J2208/00805 ,  C22B3/02 ,  C22B3/04 ,  C22B7/006 ,  C22B7/007 ,  C22B7/009 ,  C22B13/04 ,  C22B13/045 ,  H01M6/52 ,  Y02P10/234 ,  Y02W30/84

摘要： The present disclosure relates generally to systems and methods for recycling lead-acid batteries, and more specifically, relates to purifying and recycling the lead content from lead-acid batteries. A system includes a reactor that receives and mixes a lead-bearing material waste, a carboxylate source, and a recycled liquid component to form a leaching mixture yielding a lead salt precipitate. The system also includes a phase separation device coupled to the reactor, wherein the phase separation device isolates the lead salt precipitate from a liquid component of the leaching mixture. The system further includes a closed-loop liquid recycling system coupled to the phase separation device and to the reactor, wherein the closed-loop liquid recycling system receives the liquid component isolated by the phase separation device and recycles a substantial portion of the received liquid component back to the reactor as the recycled liquid component.

摘要翻译： 本公开一般涉及用于回收铅酸电池的系统和方法，更具体地，涉及从铅酸电池净化和回收铅含量。 系统包括反应器，其接收和混合含铅材料废料，羧酸盐源和再循环液体组分以形成产生铅盐沉淀物的浸出混合物。 该系统还包括耦合到反应器的相分离装置，其中相分离装置将铅盐沉淀物与浸出混合物的液体组分隔离。 该系统还包括耦合到相分离装置和反应器的闭环液体循环系统，其中闭环液体循环系统接收由相分离装置隔离的液体组分并再循环接收的液体组分的大部分 作为再循环液体组分回到反应器。

公开(公告)号：US20150368747A1

公开(公告)日：2015-12-24

申请号：US14498748

申请日：2014-09-26

申请人： Johnson Controls Technology Company

发明人： Matthew A. Spence

IPC分类号： C22B3/00 ,  C22B7/00

CPC分类号： H01M10/54 ,  B01J6/001 ,  B01J6/002 ,  B01J8/008 ,  B01J19/06 ,  B01J19/2465 ,  B01J2208/00805 ,  C22B3/02 ,  C22B3/04 ,  C22B7/006 ,  C22B7/007 ,  C22B7/009 ,  C22B13/04 ,  C22B13/045 ,  H01M6/52 ,  Y02P10/234 ,  Y02W30/84

摘要： The present disclosure relates to methods by which lead from spent lead-acid batteries may be extracted, purified, and used in the construction of new lead-acid batteries. A method includes: (A) forming a mixture including a carboxylate source and a lead-bearing material; (B) generating a first lead salt precipitate in the mixture as the carboxylate source reacts with the lead-bearing material; (C) increasing the pH of the mixture to dissolve the first lead salt precipitate; (D) isolating a liquid component of the mixture from one or more insoluble components of the mixture; (E) decreasing the pH of the liquid component of the mixture to generate a second lead salt precipitate; and (F) isolating the second lead salt precipitate from the liquid component of the mixture. Thereafter, the isolated lead salt precipitate may be converted to leady oxide for use in the manufacture of new lead-acid batteries.

摘要翻译： 本公开涉及可以提取，净化和用于构建新铅酸电池的废铅酸电池的铅的方法。 一种方法包括：（A）形成包含羧酸根源和含铅材料的混合物; （B）当羧酸酯源与含铅材料反应时，在混合物中产生第一铅盐沉淀物; （C）增加混合物的pH以溶解第一铅盐沉淀物; （D）从所述混合物的一种或多种不溶组分中分离出所述混合物的液体组分; （E）降低混合物的液体组分的pH以产生第二铅盐沉淀物; 和（F）从混合物的液体组分中分离出第二铅盐沉淀物。 此后，将分离的铅盐沉淀物转化为铅氧化物用于制造新的铅酸蓄电池。

公开(公告)号：US20150367311A1

公开(公告)日：2015-12-24

申请号：US14498771

申请日：2014-09-26

申请人： Johnson Controls Technology Company

发明人： Matthew A. Spence ,  Patrick M. Curran

IPC分类号： B01J8/00 ,  B01J6/00

CPC分类号： H01M10/54 ,  B01J6/001 ,  B01J6/002 ,  B01J8/008 ,  B01J19/06 ,  B01J19/2465 ,  B01J2208/00805 ,  C22B3/02 ,  C22B3/04 ,  C22B7/006 ,  C22B7/007 ,  C22B7/009 ,  C22B13/04 ,  C22B13/045 ,  H01M6/52 ,  Y02P10/234 ,  Y02W30/84

摘要： The present disclosure relates to systems and methods by which lead from spent lead-acid batteries may be extracted, purified, and used in the production of new lead-acid batteries. The system includes a first phase separation device configured to: receive the first mixture from the basic lead stream digestion device, isolate a liquid component from one or more insoluble components of the first mixture, and output the liquid component. The system also includes a lead salt precipitation device configured to: receive and mix the liquid component and a carboxylate source to form a second mixture including a lead salt precipitate, and output the second mixture. The system further includes a second phase separation device configured to: receive the second mixture from the lead salt precipitation device, isolate the liquid component from the lead salt precipitate of the second mixture, and output the lead salt precipitate.

摘要翻译： 本公开涉及可以提取，纯化和用于生产新铅酸电池的废铅酸电池的铅的系统和方法。 该系统包括第一相分离装置，其被配置为：从碱性铅流消解装置接收第一混合物，将液体组分与第一混合物的一种或多种不溶性组分隔离，并输出液体组分。 该系统还包括铅盐沉淀装置，其配置为：接收和混合液体组分和羧酸盐源，以形成包含铅盐沉淀物的第二混合物，并输出第二混合物。 所述系统还包括第二相分离装置，其被配置为：从所述铅盐沉淀装置接收所述第二混合物，将所述液体组分与所述第二混合物的铅盐沉淀物分离，并输出所述铅盐沉淀物。

公开(公告)号：US20130129585A1

公开(公告)日：2013-05-23

申请号：US13814477

申请日：2010-10-27

申请人： Kaihua Xu ,  Miaomiao Guo ,  Xianda He ,  Xiaokui Liang

发明人： Kaihua Xu ,  Miaomiao Guo ,  Xianda He ,  Xiaokui Liang

IPC分类号： C22B3/00

CPC分类号： C22B13/045 ,  Y02P10/212

摘要： Disclosed is a method for recycling lead from waste glass containing lead, which comprises the following steps: mechanical crushing waste glass containing lead, ball milling and screening to obtain glass powder containing lead; alkaline roasting the glass powder containing lead to obtain a roasted material; mixing polycarboxylic acid complexant and nitric acid to produce leaching agent, and then placing the roasted material into the leaching agent to obtain leachate; regulating pH value of the leachate to solidify metal ion to obtain precipitate, separating and removing impurities, rinsing and drying to obtain chemical product containing lead. The method avoids environment pollution caused by waste glass containing lead.

摘要翻译： 本发明公开了一种用于从含有铅的废玻璃中回收铅的方法，其包括以下步骤：将含铅的机械破碎废玻璃，球磨和筛分以获得含铅的玻璃粉末; 碱性焙烧包含铅的玻璃粉末以获得烤制材料; 混合多元羧酸络合剂和硝酸制备浸出剂，然后将焙烧物放入浸出剂中得到渗滤液; 调节渗滤液的pH值，固化金属离子，得到沉淀物，分离除去杂质，冲洗干燥得到含铅的化学产品。 该方法避免了铅含铅玻璃引起的环境污染。

公开(公告)号：US20120325899A1

公开(公告)日：2012-12-27

申请号：US13604886

申请日：2012-09-06

申请人： Lambertus Petrus Christinus Willemen

发明人： Lambertus Petrus Christinus Willemen

IPC分类号： B23K3/08 ,  B23K1/20 ,  B23K3/06

CPC分类号： B23K3/08 ,  B23K1/08 ,  B23K1/085 ,  B23K1/206 ,  B23K3/0646 ,  B23K3/0653 ,  C22B7/04 ,  C22B13/025 ,  C22B13/045 ,  C22B21/0069

摘要： This invention relates to for devices, systems, and methods for separating dross, carried by molten solder, into solder and residue.

摘要翻译： 本发明涉及用于将由熔融焊料携带的浮渣分离成焊料和残渣的装置，系统和方法。

公开(公告)号：US20120247509A1

公开(公告)日：2012-10-04

申请号：US13511782

申请日：2009-12-30

申请人： Guorong Lin ,  Huanrong Yu ,  Jihong Li

发明人： Guorong Lin ,  Huanrong Yu ,  Jihong Li

IPC分类号： B08B3/14 ,  B08B7/04

CPC分类号： C22B7/006 ,  B08B3/00 ,  B08B3/04 ,  B08B3/14 ,  B08B7/04 ,  C01G21/006 ,  C22B7/007 ,  C22B13/045 ,  C22B30/06 ,  C25C1/18 ,  C25C3/34 ,  C25C7/06 ,  Y02P10/234

摘要： A method of washing anode slime from lead-bismuth alloy electrolysis is disclosed, wherein a lead fluorosilicate solution with high concentration can be obtained by using the anode slime from lead-bismuth alloy electrolysis as raw material, which is characterized in that the method includes the following steps: (1) pretreating the anode slime, (2) primarily soaking the anode slime, (3) secondarily soaking the anode slime. A method of washing anode slime from lead-bismuth alloy electrolysis, and obtaining a soaking solution containing a lot of lead ions and fluorosilicic anions is provided. The soaking supernatant is added directly into the electrolyte-circulating system of lead-bismuth alloy electrolysis, which increases the utilization rate of lead ions and fluorosilicic anions, and improves the environment for smelting bismuth and silver, while reduces production cost for smelting lead, bismuth and silver. The method optimizes the process for the lead-bismuth alloy electrolysis, and solves the problem of “lean-lead” in the lead-bismuth alloy electrolysis.

摘要翻译： 公开了一种从铅 - 铋合金电解中洗涤阳极泥的方法，其中通过以铅 - 铋合金电解为原料的阳极泥可以获得高浓度的氟硅酸铅溶液，其特征在于该方法包括 以下步骤：（1）预处理阳极泥，（2）主要浸泡阳极泥，（3）二次浸泡阳极泥。 提供了从铅 - 铋合金电解中洗涤阳极泥的方法，并获得含有大量铅离子和氟硅阴离子的浸泡溶液。 将浸泡的上清液直接加入到铅 - 铋合金电解液的电解液循环系统中，提高了铅离子和氟硅酸盐的使用率，改善了铋和银的熔炼环境，同时降低了铅，铋的生产成本 和银。 该方法优化了铅铋合金电解工艺，解决了铅铋合金电解中的铅铅问题。

公开(公告)号：US08147780B2

公开(公告)日：2012-04-03

申请号：US12523096

申请日：2008-01-15

申请人： Federica Martini

发明人： Federica Martini

IPC分类号： C01G21/00

CPC分类号： C22B13/045 ,  C01G21/02 ,  C01G21/14 ,  C22B3/165 ,  C22B7/007 ,  H01M6/52 ,  H01M10/06 ,  H01M10/54 ,  Y02P10/234 ,  Y02W30/84

摘要： Wet process of low environmental impact recovers the lead content of an electrode slime and/or of lead minerals in the valuable form of high purity-lead carbonates that are convertible to highly pure lead oxide by heat treatment in oven at relatively low temperature, perfectly suited for making active electrode pastes of new batteries or other uses. The process basically comprises the following steps: a) adding sulphuric acid to a different acid leach suspension of the starting impure material for converting all dissolved lead compounds to insoluble lead sulphate; b) separating the solid phase constituted by lead sulphate and undissolved impurities from the acid leach solution; c) selectively dissolving lead sulphate contained in said separated solid phase in an aqueous solution of a lead solubilizing compound comprising preferably sodium acetate; d) separating the solution containing dissolved lead sulphate from the solid phase residue including undissolved impurities; e) adding to the separated solution of lead sulphate a carbonate of the same cation of said dissolving compound for forming insoluble lead carbonate and/or and lead oxycarbonate and a dissolved sulphate of the same cation; f) separating the precipitated carbonate and/or oxycarbonate of lead from the dissolving solution now containing also sulphate of the cation of said solubilizing compound.

摘要翻译： 低环境影响的湿法可以将高纯度碳酸铅的有价值形式的电极粘土和/或铅矿物质的铅含量回收到可在相对较低的温度下通过热处理在高温下进行热处理的高纯度氧化铅。 用于制作新电池或其他用途的活性电极膏。 该方法基本上包括以下步骤：a）将硫酸加入起始不纯物质的不同酸浸液中，将所有溶解的铅化合物转化为不溶性硫酸铅; b）从酸浸液中分离由硫酸铅和未溶解的杂质构成的固相; c）将包含在所述分离的固相中的硫酸铅选择性溶解在优选包含乙酸钠的铅增溶化合物的水溶液中; d）从包含未溶解杂质的固相残留物中分离含有溶解的硫酸铅的溶液; e）向所分离的硫酸铅溶液中加入所述溶解化合物的相同阳离子的碳酸盐，以形成不溶性碳酸铅和/或碳酸铅和相同阳离子的溶解硫酸盐; f）从现在还含有所述增溶化合物的阳离子的硫酸盐的溶解溶液中分离出沉淀的碳酸铅和/或氧化碳酸铅。

公开(公告)号：US20110083970A1

公开(公告)日：2011-04-14

申请号：US12745067

申请日：2008-11-27

申请人： Marco Olper ,  Carmelita Roncaldier ,  Carlo Olper ,  Luigi Olper ,  Alessandro Olper ,  Massimo Maccagni ,  Silvano Cossali

发明人： Marco Olper ,  Carmelita Roncaldier ,  Carlo Olper ,  Luigi Olper ,  Alessandro Olper ,  Massimo Maccagni ,  Silvano Cossali

IPC分类号： C25C1/18 ,  C22B13/00

CPC分类号： C22B13/045 ,  C22B7/008 ,  C25C1/18 ,  Y02P10/122 ,  Y02P10/234

摘要： The present invention relates to an electrolytic process for producing metallic lead starting from desulfurized lead pastel comprising the following operative phases: a) leaching the desulfurized pastel by putting it in contact with a solution comprising ammonium chloride, with the formation of a leach liquor and evolution of gaseous CO2; b) separating a first solid residue and a first clarified leach liquor from the leach liquor coming from phase a); c) leaching the solid residue separated in phase b) by putting it in contact with a solution comprising ammonium chloride and hydrogen peroxide; d) separating a second solid residue and a second clarified leach liquor from the leach liquor coming from phase c); e) joining the first clarified leach liquor coming from phase b) with the second clarified leach liquor coming from phase d) and forming a single solution; f) subjecting the solution leaving phase e) to electrolysis in a flow cell, with a current density ranging from 50 to 10,000 A/m2, said electrolysis resulting in the formation of a lead sponge. The present invention also relates to the relative desulfurization process of the pastel.

摘要翻译： 本发明涉及一种用于从脱硫铅膏制备金属铅的电解方法，其包括以下操作阶段：a）通过将脱硫粉末与包含氯化铵的溶液接触，浸出脱硫粉末，形成浸出液并进行 的气态二氧化碳; b）从第一阶段a）的浸出液中分离出第一固体残余物和第一澄清浸出液; c）通过使其与包含氯化铵和过氧化氢的溶液接触来浸出在相b）中分离的固体残余物; d）从相c）的浸出液中分离出第二固体残渣和第二澄清浸出液; e）将来自相b）的第一澄清浸出液与来自相d）的第二澄清浸出液接合并形成单一溶液; f）使离开相e）的溶液在流动池中电解，电流密度范围为50至10,000A / m 2，所述电解导致形成铅海绵。 本发明还涉及到粉笔的相对脱硫工艺。

公开(公告)号：US20100193467A1

公开(公告)日：2010-08-05

申请号：US12595445

申请日：2008-04-11

申请人： Anders Weckman ,  Juha Jokinen

发明人： Anders Weckman ,  Juha Jokinen

IPC分类号： H05K3/00 ,  B01D21/01

CPC分类号： C02F1/02 ,  C02F1/5272 ,  C02F1/66 ,  C02F9/00 ,  C02F2101/20 ,  C02F2103/16 ,  C02F2103/346 ,  C02F2303/16 ,  C22B3/065 ,  C22B3/165 ,  C22B3/22 ,  C22B3/44 ,  C22B7/006 ,  C22B13/045 ,  C22B25/04 ,  C23F1/46 ,  Y02P10/234

摘要： In the method, the spent stripper solution for tin or a tin mixture is treated to precipitate dissolved or suspended metal compounds. On the one hand chemicals for reuse, and on the other hand metals such as copper, tin, lead and/or iron are recovered from the waste water streams. Efficiency of the precipitation is improved by heating of the stripping solution at elevated temperatures, and by the addition of a precipitating reagent. Once the precipitate is removed, the remaining liquid may be reused, typically as an admixture with a fresh solution. In the production method of a regenerated stripping solution for tin comprising at least one inorganic acid, ferric ions, at least one organic acid, and at least one organic additive, the stripping solution is heated at elevated temperatures, precipitating reagent is added, precipitated matter is separated and removed, and one or some of the acids or additives mentioned are added for the recovery of the desired tin stripping capacity.

摘要翻译： 在该方法中，处理锡或锡混合物的废汽提器溶液以沉淀溶解或悬浮的金属化合物。 一方面是用于再利用的化学品，另一方面从废水流中回收诸如铜，锡，铅和/或铁的金属。 通过在升高的温度下加热汽提溶液并通过加入沉淀试剂来提高沉淀的效率。 一旦沉淀物被除去，剩余的液体可以重复使用，通常作为与新鲜溶液的混合物。 在包含至少一种无机酸，三价铁离子，至少一种有机酸和至少一种有机添加剂的锡的再生汽提溶液的制备方法中，将提取溶液在高温下加热，加入沉淀试剂，沉淀物 被分离和除去，并且加入所提及的一种或一些酸或添加剂用于回收所需的锡剥离能力。

公开(公告)号：US07498012B2

公开(公告)日：2009-03-03

申请号：US11035001

申请日：2005-01-12

申请人： Marco Olper ,  Massimo Maccagni ,  Silvano Cossali

发明人： Marco Olper ,  Massimo Maccagni ,  Silvano Cossali

IPC分类号： C01G21/14 ,  C01B31/24

CPC分类号： H01M10/54 ,  C22B3/44 ,  C22B7/008 ,  C22B13/045 ,  H01M4/73 ,  H01M10/06 ,  Y02P10/234 ,  Y02W30/84

摘要： The present invention relates to a desulfurization process of pastel and grids of lead accumulators comprising a carbonation in two steps, a granulometric separation between the two steps followed by specific desulfurization of the large part, a desodification obtaining the conversion of the PbSO4 contained in the pastel into PbCO3 which can be easily converted into metallic Pb in an oven by the addition of coal. The system used for the desodification of the large part of the pastel can also be used for the desulfurization of the fine part of the grids.

摘要翻译： 本发明涉及一种铅蓄电池的粉末和栅格的脱硫工艺，包括两步碳酸化，两步之间的粒度分离，然后大部分进行特定的脱硫，脱色获得粉末中所含的PbSO 4的转化率 加入到通过加入煤容易在烘箱中转化为金属Pb的PbCO3中。 用于大部分粉末脱水的系统也可用于网格细部分的脱硫。