摘要:
A method for imparting resistance to staining to a substrate comprising contacting the substrate with a copolymer comprising the monomers of Formula wherein D is at least one vinyl monomer selected from the group consisting of aryl olefin, alpha olefin and diene, each M is independently H, Ca, Mg, Al, Na, or K, each R1 is independently H, C1-C6 alkyl, or C1-C6 hydroxyalkyl, each R2 is independently linear or branched C1-C12 alkyl, C1-C6 hydroxyalkyl, C6F5, arylalkyl, C6H4OH, R3COOH, or R3SO3H, or R1 and R2 are linked together to form a morpholino or pyrrolidino ring, R3 is linear or branched C1-C12 alkyl, CH(COOH)CH2CH2, C6H4, or C6H3(OH), h1+h2 is h, h is a positive integer, k is zero or a positive integer, i and j are each independently zero or a positive integer, provided that the total of 1) h÷(k+h+i+j) is from about 0.005 to about 0.7, 2) k÷(k+h+i+j) is from about 0.3 to about 0.6, 3) [i+j]÷(k+h+i+j) is 0 to about 0.6, and provided that the sum of 1)+2)+3) is 1.0, said monomers occurring in any sequence.
摘要翻译:一种赋予对基材染色抗性的方法,包括使底物与包括式I的单体的共聚物接触,其中D为选自芳烯基烯烃,α-烯烃和二烯的至少一种乙烯基单体,每个M独立地为H, Ca,Mg,Al,Na或K,每个R 1独立地为H,C 1 -C 6烷基或C 1 -C 6羟基烷基,每个R 2独立地为直链或支链C 1 -C 12烷基,C 1 -C 6羟基烷基,C 6 F 5,芳基烷基,C 6 H 4 OH ,R 3 COOH或R 3 SO 3 H,或R 1和R 2连接在一起形成吗啉代或吡咯烷基环,R 3是直链或支链C 1 -C 12烷基,CH(COOH)CH 2 CH 2,C 6 H 4或C 6 H 3(OH),h1 + h2是h ,h是正整数,k是零或正整数,i和j各自独立为零或正整数,条件是1)h÷(k + h + i + j)的总和为约0.005至 约0.7,2)k÷(k + h + i + j)为约0.3至约0.6,3)[i + j]÷(k + h + i + j)为0至约0.6,条件是 所述单体为1)+2)+3)的总和为1.0 以任何顺序发生。
摘要:
A method for imparting resistance to staining to a substrate comprising contacting the substrate with a copolymer comprising the monomers of Formula wherein D is at least one vinyl monomer selected from the group consisting of aryl olefin, alpha olefin and diene, each M is independently H, Ca, Mg, Al, Na, or K, each R1 is independently H, C1-C6 alkyl, or C1-C6 hydroxyalkyl, each R2 is independently linear or branched C1-C12 alkyl, C1-C6 hydroxyalkyl, C6F5, arylalkyl, C6H4OH, R3COOH, or R3SO3H, or R1 and R2 are linked together to form a morpholino or pyrrolidino ring, R3 is linear or branched C1-C12 alkyl, CH(COOH)CH2CH2, C6H4, or C6H3(OH), h1+h2 is h, h is a positive integer, k is zero or a positive integer, i and j are each independently zero or a positive integer, provided that the total of 1) h÷(k+h+i+j) is from about 0.005 to about 0.7, 2) k÷(k+h+i+j) is from about 0.3 to about 0.6, 3) [i+j]÷(k+h+i+j) is 0 to about 0.6, and provided that the sum of 1)+2)+3) is 1.0, said monomers occurring in any sequence.
摘要翻译:一种赋予对基材染色抗性的方法,包括使底物与包括式I的单体的共聚物接触,其中D为选自芳烯基烯烃,α-烯烃和二烯的至少一种乙烯基单体,每个M独立地为H, Ca,Mg,Al,Na或K,每个R 1独立地为H,C 1 -C 6烷基或C 1 -C 6羟基烷基,每个R 2独立地为直链或支链C 1 -C 12烷基,C 1 -C 6羟基烷基,C 6 F 5,芳基烷基,C 6 H 4 OH ,R 3 COOH或R 3 SO 3 H,或R 1和R 2连接在一起形成吗啉代或吡咯烷基环,R 3是直链或支链C 1 -C 12烷基,CH(COOH)CH 2 CH 2,C 6 H 4或C 6 H 3(OH),h1 + h2是h ,h是正整数,k是零或正整数,i和j各自独立为零或正整数,条件是1)h÷(k + h + i + j)的总和为约0.005至 约0.7,2)k÷(k + h + i + j)为约0.3至约0.6,3)[i + j]÷(k + h + i + j)为0至约0.6,条件是 所述单体为1)+2)+3)的总和为1.0 以任何顺序发生。
摘要:
A method for imparting resistance to staining to a substrate comprising contacting the substrate with a copolymer comprising the monomers of Formula wherein D is at least one vinyl monomer selected from the group consisting of aryl olefin, alpha olefin and diene, each M is independently H, Ca, Mg, Al, Na, or K, each R1 is independently H, C1-C6 alkyl, or C1-C6 hydroxyalkyl, each R2 is independently linear or branched C1-C12 alkyl, C1-C6 hydroxyalkyl, C6F5, arylalkyl, C6H4OH, R3COOH, or R3SO3H, or R1 and R2 are linked together to form a morpholino or pyrrolidino ring, R3 is linear or branched C1-C12 alkyl, CH(COOH)CH2CH2, C6H4, or C6H3(OH), h1+h2 is h, h is a positive integer, k is zero or a positive integer, i and j are each independently zero or a positive integer, provided that the total of 1) h÷(k+h+i+j) is from about 0.005 to about 0.7, 2) k÷(k+h+i+j) is from about 0.3 to about 0.6, 3) [i+j]÷(k+h+i+j) is 0 to about 0.6, and provided that the sum of 1)+2)+3) is 1.0, said monomers occurring in any sequence.
摘要翻译:一种赋予对基材染色抗性的方法,包括使底物与包括式I的单体的共聚物接触,其中D为选自芳烯基烯烃,α-烯烃和二烯的至少一种乙烯基单体,每个M独立地为H, Ca,Mg,Al,Na或K,每个R 1独立地为H,C 1 -C 6烷基或C 1 -C 6羟基烷基,每个R 2独立地为直链或支链C 1 -C 12烷基,C 1 -C 6羟基烷基,C 6 F 5,芳基烷基,C 6 H 4 OH ,R 3 COOH或R 3 SO 3 H,或R 1和R 2连接在一起形成吗啉代或吡咯烷基环,R 3是直链或支链C 1 -C 12烷基,CH(COOH)CH 2 CH 2,C 6 H 4或C 6 H 3(OH),h1 + h2是h ,h是正整数,k是零或正整数,i和j各自独立为零或正整数,条件是1)h /(k + h + i + j)的总和为约0.005〜 约0.7,2)k /(k + h + i + j)为约0.3至约0.6,3)[i + j] /(k + h + i + j)为0至约0.6,条件是 1)+2)+3)的总和为1.0,所述单体为 卷曲任何顺序。
摘要:
A fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain repellent and comprising a fluorinated polymer dispersed in water or dissolved or dispersed in an organic solvent, the fluorinated polymer comprising units derived from (i) a mixture of two or more fluorinated polyether monomers that differ in at least their molecular weight, the fluorinated polyether monomers having an ethylenically unsaturated group and a perfluorinated polyether group and wherein at least 90% by weight of the mixture consists of fluorinated polyether monomers that have a perfluorinated polyether group having a molecular weight of at least 750 g/mol and (ii) one or more units derived from one or more co-monomers other than a fluorinated polyether monomer and wherein the co-monomers comprise at least one non-fluorinated monomer. Also, method for treating fibrous substrate with such composition, fluorinated polyether monomers, and fluorinated polymers derived from such monomers.
摘要:
A natural strip or strip-based weaving or weave fabric product or a natural strip or strip-based woven product is coated and protected with a crosslinking polyvinyl acetate (XPVAc or x-PVAc) adhesive. Said adhesive is applied and cured on the exterior surfaces of said product as a first coating layer or a primer in combination with a coating layer of acrylic, alkyd, asphalt, epoxy, latex, polyurethane, silicone coatings, urethane, vinyl ester, etc. coated over the cured adhesive as a second coating layer or a topcoat. Said product is woven or fabricated with stalks, stakes, staves, stems, sticks, strands, shoots, splints, straws, strings, twigs, bark, branches, laths, leaves, rods, roots, whicker, etc. of a fiber plant, a tree, or a crop, or the combination thereof.
摘要:
A method for forming a metallic nanoparticle and semiconductor coated surface, such as the surface of a fiber or other material is provided. The method can include the steps of coating at least one surface of a material, for example a textile material, with a semiconducting layer, and providing metallic nanoparticles on the semiconducting layer. The steps for coating a surface of a material with a semiconducting layer can include forming a titanium dioxide film on the surface of the textile or other material. The steps for depositing and/or providing metallic nanoparticles on the semiconducting layer can include immersing a surface having a semiconductor layer into a metallic nanoparticle precursor solution, drying the semiconductor layer, and exposing the semiconductor layer on the surface to UV radiation. The metallic nanoparticles can include gold and/or silver nanoparticles. Also disclosed are surface treated materials having a semiconductor layer thereon, wherein the semiconductor layer is treated to include metallic nanoparticles. The surface treated materials may comprise surfaces of a textile material, such as fibers. The surface treated materials are anti-microbial and resistant to peeling, as well as non-toxic to biological surfaces, such as skin. Treated fiber materials may be used in garments, masks, and other products that contact the skin, that are free of toxic/rash side effects.
摘要:
A zwitterionic resin is manufactured by a manufacturing method which includes the following steps. A first thermal process is performed on a first crosslinking agent and a choline having hydroxyl group or amino group to form a first mixture, in which the first crosslinking agent includes an isocyanate group. A second thermal process is performed on the first mixture, a second crosslinking agent, a chain extender, and an amino acid to form the zwitterionic resin, in which the chain extender includes a polyol.
摘要:
A composition for the treatment of fiber, yarn and fabrics, said composition comprising at least one highly dispersible clay nanoparticle component, at least one silicone polymer component; and water. Also provided is fiber surface treated with these compositions as well as articles including yarns, fabrics and carpets of the surface treated fiber.
摘要:
The present invention relates to an improved emulsified composition comprising a) —one or more amino functional siloxanes of the formula I b) —one or more hydrolysable alkyl silans of the formula II c) an acid d) water e) a defoamer f) a coalescent agent and optionally one or more of a preservative, co-emulsifier, catalyst, rheology modifier, fatty acid, oil and/or wax, the process of preparing it and the application method of enhancing the water repellence of an inorganic, organic or fiber based materials and/or enhancing the said materials ability to repel water soluble dirt, as well as an apparatus for use in said method.
摘要:
A polymer composition with (A) a first poly(meth)acrylate polymer or urethane polymer; and (B) a second poly(meth)acrylate polymer or urethane polymer which has a residue X incorporated therein, where X is the residue of a cyclic or acyclic sugar alcohol which is substituted with at least one —R1; —C(O)R1; —(CH2CH2O)n(CH(CH3)CH2O)mR2; —(CH2CH2O)n(CH(CH3)CH2O)mC(O)R1; or mixtures thereof; where the cyclic or acyclic sugar alcohol is selected from a saccharide, reduced sugar, aminosaccharide, aldonic acid, or aldonic acid lactone; wherein each n is independently 0 to 20; each m is independently 0 to 20; m+n is greater than 0; each R1 is independently a linear or branched alkyl group having 5 to 29 carbons optionally comprising at least 1 unsaturated bond; and each R2 is independently —H, a linear or branched alkyl group having 6 to 30 carbons optionally comprising at least 1 unsaturated bond, or mixtures thereof.