摘要:
A polymer composition of excellent compatibility which comprises a block copolymer containing a polyvinyl alcohol polymer unit as one constituent and a polymer unit having an ionic group as another constituent, and protein. It is suitable, especially when the protein is gelatin, for making a photographic emulsion, microcapsules, or a photosensitive material, among others.
摘要:
Photographic material containing on a support at least one silver halide emulsion layer which contains as binders both gelatin and a polymer latex, wherein the particle size is less than 0.05 .mu.m, and which is obtained by emulsion polymerizing a monomer or monomer mixture which consists of an alkyl acrylate or an alkyl methacrylate or a monomer mixture comprising both an alkyl acrylate and an alkyl methacrylate or a mixture comprising an alkyl acrylate and/or an alkyl methacrylate together with up to 5% by weight of an ethylenically unsaturated copolymerizable acid and/or up to 30% by weight of other ethylenically unsaturated comonomers in the presence of at least 12% by weight of the monomers present of an anionic surfactant at a temperature of from 15.degree. C. to 90.degree. C. by use of a redox initiator system which is present to the extent of from 0.1% to 3% by weight of the monomers present.The latexes are of use to partially replace gelatin in photographic materials. These latex/gelatin binders are suitable for highspeed coating and drying processes and confer to the photographic materials an increased dimensional stability.
摘要:
A polymer comprising polymerized N-alkyl substituted acrylamide and a polymerized crosslinking monomer wherein the polymer has a solubility parameter from about 13 to 16 at 25.degree. C., is useful as a temporary barrier layer between reactants in photographic products. The barrier layer is particularly useful as a process timing layer in color image transfer film units.
摘要:
The antistatic property of a silver halide photographic material is effectively improved by incorporating a fluorine-containing water-soluble polymer having a styrene monomer containing a fluorine-containing group as the polymerization unit in at least one of the photographic layers of the photographic material. The incorporation of the polymer does not reduce the adhesion resistance or film strength of the photographic material. The photographic material can also maintain the improved antistatic property for a long period of time.
摘要:
Ionic copolymers of styrene sulfonic acid and maleic acid improve covering power when added to the gelatin binder employed in medical silver halide X-ray emulsions.
摘要:
A silver halide photographic material having a hydrophilic colloid layer comprising fine polymer particles loaded with a hydrophobic photographic addenda provided on a support wherein the polymer has repeating units formed from a nonionic hydrophobic monomer. The nonionic hydrophobic monomer has the formula ##STR1## R.sub.1 and R.sub.2 individually are a hydrogen atom or methyl group, R.sub.3 is a hydrogen atom, an alkyl or aryl group, and m and n are integers of from 2 to 100 individually.
摘要:
A photographic element having a photographic layer such as silver halide emulsion layer, protective layer, intermediate layer, subcoat layer, diffusion transfer image-receiving layer, antihalation layer and backing layer, can be improved in the adhesion between the layer and support, little curling on drying, and flexibility of the layer, by incorporating into the photographic layer a conversion mixture of a polyvinyl alcohol having a saponification degree of 96% or more and an ethylene-maleic anhydride copolymer.
摘要:
Polymers, containing polymerized units of at least one compound of the formula ##STR1## and at least one compound of the formula ##STR2## are useful for the preparation of silver halide emulsions.
摘要:
Compounds useful in making crosslinkable polymers having the formula (I): ##STR1## wherein R is hydrogen or methyl; R.sup.1 is cyano or ##STR2## wherein R.sup.2 is alkyl; Z is --X--R.sup.3 --X-- or ##STR3## wherein each --X-- is --O-- or --NR.sup.4 --, provided at least one --X-- is --NR.sup.4 -- wherein R.sup.4 is hydrogen or alkyl, R.sup.3 is divalent hydrocarbon and D.sub.1 and D.sub.2 together are the carbon atoms necessary to complete a 5 to 7 membered ring. These compounds can be homopolymerized or copolymerized with each other or with other polymerizable ethylenically unsaturated monomers to give crosslinkable polymers. Such polymers can be purified by conventional purification techniques such as dialysis, diafiltration, ultrafiltration without losing their capability of crosslinking. The resulting purified polymers are particularly useful in photographic materials as gelatin extenders, binders or polymeric color couplers.
摘要翻译:可用于制备具有式(I)的交联聚合物的化合物:其中R是氢或甲基; R 1是氰基或者其中R 2是烷基; Z是-X-R3-X-或,其中每个-X-是-O-或-NR4-,提供至少一个-X-是-NR4-,其中R4是氢或烷基,R3是二价烃和 D1和D2一起是完成5至7元环所必需的碳原子。 这些化合物可以彼此均聚或共聚,或与其它可聚合的烯属不饱和单体共聚以产生可交联的聚合物。 这样的聚合物可以通过常规的纯化技术如透析,渗滤,超滤而不失去其交联能力而被纯化。 所得到的纯化聚合物特别可用于照相材料,如明胶增量剂,粘合剂或聚合物色素。
摘要:
A method for dispersing an oil-soluble photographic additive which comprises dissolving the additive in an organic solvent and dispersing the resulting solution of the photographic additive in water or a hydrophilic colloid composition in the presence of a surface active polymer comprising (a) a homopolymer of units represented by the formula (I): ##STR1## wherein R is an aliphatic hydrocarbon group having 4 to 22 carbon atoms; m.sub.1 and m.sub.2 each is 0 or 1; B is --O-- or --NH--; A is a divalent aliphatic group having 1 to 50 carbon atoms; and M is a hydrogen atom or a cation group capable of forming a salt with a sulfonic acid group, or (b) a copolymer containing at least 5 mol% of units represented by the formula (I) above and the balance of divalent units copolymerizable therewith and comprising at least one of a benzene ring having a methylene group attached thereto and a naphthalene ring having a methylene group attached thereto.