Photographic material and a process for its manufacture
    32.
    发明授权
    Photographic material and a process for its manufacture 失效
    摄影材料及其制造工艺

    公开(公告)号:US4510238A

    公开(公告)日:1985-04-09

    申请号:US471556

    申请日:1983-03-02

    CPC分类号: G03C1/053

    摘要: Photographic material containing on a support at least one silver halide emulsion layer which contains as binders both gelatin and a polymer latex, wherein the particle size is less than 0.05 .mu.m, and which is obtained by emulsion polymerizing a monomer or monomer mixture which consists of an alkyl acrylate or an alkyl methacrylate or a monomer mixture comprising both an alkyl acrylate and an alkyl methacrylate or a mixture comprising an alkyl acrylate and/or an alkyl methacrylate together with up to 5% by weight of an ethylenically unsaturated copolymerizable acid and/or up to 30% by weight of other ethylenically unsaturated comonomers in the presence of at least 12% by weight of the monomers present of an anionic surfactant at a temperature of from 15.degree. C. to 90.degree. C. by use of a redox initiator system which is present to the extent of from 0.1% to 3% by weight of the monomers present.The latexes are of use to partially replace gelatin in photographic materials. These latex/gelatin binders are suitable for highspeed coating and drying processes and confer to the photographic materials an increased dimensional stability.

    摘要翻译: 在载体上含有至少一种含有明胶和聚合物胶乳作为粘合剂的卤化银乳剂层的照相材料,其中粒径小于0.05μm,其通过乳液聚合单体或单体混合物获得,所述单体或单体混合物由 丙烯酸烷基酯或甲基丙烯酸烷基酯或包含丙烯酸烷基酯和甲基丙烯酸烷基酯或包含丙烯酸烷基酯和/或甲基丙烯酸烷基酯的混合物的单体混合物,以及至多5重量%的烯键式不饱和可共聚酸和/或 在至少12重量%存在阴离子表面活性剂的单体的存在下,在15℃至90℃的温度下,使用氧化还原引发剂体系,存在至多30重量%的其它烯属不饱和共聚单体 其存在的量为所述单体的0.1重量%至3重量%。 胶乳可用于部分替代照相材料中的明胶。 这些胶乳/明胶粘合剂适用于高速涂布和干燥过程,并赋予照相材料增加的尺寸稳定性。

    Silver halide photographic materials
    34.
    发明授权
    Silver halide photographic materials 失效
    卤化银照相材料

    公开(公告)号:US4495275A

    公开(公告)日:1985-01-22

    申请号:US277370

    申请日:1981-06-25

    CPC分类号: G03C1/385 C08F12/14 G03C1/053

    摘要: The antistatic property of a silver halide photographic material is effectively improved by incorporating a fluorine-containing water-soluble polymer having a styrene monomer containing a fluorine-containing group as the polymerization unit in at least one of the photographic layers of the photographic material. The incorporation of the polymer does not reduce the adhesion resistance or film strength of the photographic material. The photographic material can also maintain the improved antistatic property for a long period of time.

    摘要翻译: 通过将含有含氟基团的苯乙烯单体的含氟水溶性聚合物作为聚合单元并入照相材料的照相层中的至少一个中,可以有效改善卤化银照相材料的抗静电性能。 聚合物的结合不会降低照相材料的粘合性或膜强度。 照相材料也可以长时间保持改善的抗静电性能。

    Ionic copolymers in photographic light-sensitive silver halide films
    35.
    发明授权
    Ionic copolymers in photographic light-sensitive silver halide films 失效
    照相感光卤化银膜中的离子共聚物

    公开(公告)号:US4391903A

    公开(公告)日:1983-07-05

    申请号:US346738

    申请日:1982-02-08

    申请人: Peter K. Sysak

    发明人: Peter K. Sysak

    IPC分类号: G03C1/053 G03C1/72

    CPC分类号: G03C1/053

    摘要: Ionic copolymers of styrene sulfonic acid and maleic acid improve covering power when added to the gelatin binder employed in medical silver halide X-ray emulsions.

    摘要翻译: 苯乙烯磺酸和马来酸的离子共聚物当加入医用卤化银X射线乳剂中使用的明胶粘合剂时,提高了覆盖力。

    Silver halide photographic material
    36.
    发明授权
    Silver halide photographic material 失效
    卤化银照相材料

    公开(公告)号:US4358533A

    公开(公告)日:1982-11-09

    申请号:US242490

    申请日:1981-03-11

    摘要: A silver halide photographic material having a hydrophilic colloid layer comprising fine polymer particles loaded with a hydrophobic photographic addenda provided on a support wherein the polymer has repeating units formed from a nonionic hydrophobic monomer. The nonionic hydrophobic monomer has the formula ##STR1## R.sub.1 and R.sub.2 individually are a hydrogen atom or methyl group, R.sub.3 is a hydrogen atom, an alkyl or aryl group, and m and n are integers of from 2 to 100 individually.

    摘要翻译: 具有亲水胶体层的卤化银照相材料,其包含负载在载体上的疏水照相附加物的聚合物微粒,其中所述聚合物具有由非离子疏水单体形成的重复单元。 非离子疏水性单体具有下式:R1和R2分别为氢原子或甲基,R3为氢原子,烷基或芳基,m和n为2〜100的整数 单独。

    Photographic element
    37.
    发明授权
    Photographic element 失效
    摄影元素

    公开(公告)号:US4287293A

    公开(公告)日:1981-09-01

    申请号:US110751

    申请日:1980-01-08

    摘要: A photographic element having a photographic layer such as silver halide emulsion layer, protective layer, intermediate layer, subcoat layer, diffusion transfer image-receiving layer, antihalation layer and backing layer, can be improved in the adhesion between the layer and support, little curling on drying, and flexibility of the layer, by incorporating into the photographic layer a conversion mixture of a polyvinyl alcohol having a saponification degree of 96% or more and an ethylene-maleic anhydride copolymer.

    摘要翻译: 具有照相层的照相元件,例如卤化银乳剂层,保护层,中间层,底涂层,扩散转移图像接收层,防晕层和背衬层可以改善层与载体之间的粘附性,少量卷曲 通过将照相层中的皂化度为96%以上的聚乙烯醇和乙烯 - 马来酸酐共聚物的转化混合物结合到层的干燥和柔软性上。

    Crosslinkable polymers derived from amide compounds
    39.
    发明授权
    Crosslinkable polymers derived from amide compounds 失效
    衍生自酰胺化合物的可交联聚合物

    公开(公告)号:US4247673A

    公开(公告)日:1981-01-27

    申请号:US85138

    申请日:1979-10-15

    摘要: Compounds useful in making crosslinkable polymers having the formula (I): ##STR1## wherein R is hydrogen or methyl; R.sup.1 is cyano or ##STR2## wherein R.sup.2 is alkyl; Z is --X--R.sup.3 --X-- or ##STR3## wherein each --X-- is --O-- or --NR.sup.4 --, provided at least one --X-- is --NR.sup.4 -- wherein R.sup.4 is hydrogen or alkyl, R.sup.3 is divalent hydrocarbon and D.sub.1 and D.sub.2 together are the carbon atoms necessary to complete a 5 to 7 membered ring. These compounds can be homopolymerized or copolymerized with each other or with other polymerizable ethylenically unsaturated monomers to give crosslinkable polymers. Such polymers can be purified by conventional purification techniques such as dialysis, diafiltration, ultrafiltration without losing their capability of crosslinking. The resulting purified polymers are particularly useful in photographic materials as gelatin extenders, binders or polymeric color couplers.

    摘要翻译: 可用于制备具有式(I)的交联聚合物的化合物:其中R是氢或甲基; R 1是氰基或者其中R 2是烷基; Z是-X-R3-X-或,其中每个-X-是-O-或-NR4-,提供至少一个-X-是-NR4-,其中R4是氢或烷基,R3是二价烃和 D1和D2一起是完成5至7元环所必需的碳原子。 这些化合物可以彼此均聚或共聚,或与其它可聚合的烯属不饱和单体共聚以产生可交联的聚合物。 这样的聚合物可以通过常规的纯化技术如透析,渗滤,超滤而不失去其交联能力而被纯化。 所得到的纯化聚合物特别可用于照相材料,如明胶增量剂,粘合剂或聚合物色素。

    Method for dispersing a photographic additive
    40.
    发明授权
    Method for dispersing a photographic additive 失效
    分散摄影添加剂的方法

    公开(公告)号:US4198478A

    公开(公告)日:1980-04-15

    申请号:US904664

    申请日:1978-05-10

    摘要: A method for dispersing an oil-soluble photographic additive which comprises dissolving the additive in an organic solvent and dispersing the resulting solution of the photographic additive in water or a hydrophilic colloid composition in the presence of a surface active polymer comprising (a) a homopolymer of units represented by the formula (I): ##STR1## wherein R is an aliphatic hydrocarbon group having 4 to 22 carbon atoms; m.sub.1 and m.sub.2 each is 0 or 1; B is --O-- or --NH--; A is a divalent aliphatic group having 1 to 50 carbon atoms; and M is a hydrogen atom or a cation group capable of forming a salt with a sulfonic acid group, or (b) a copolymer containing at least 5 mol% of units represented by the formula (I) above and the balance of divalent units copolymerizable therewith and comprising at least one of a benzene ring having a methylene group attached thereto and a naphthalene ring having a methylene group attached thereto.

    摘要翻译: 一种用于分散油溶性照相添加剂的方法,其包括将添加剂溶解在有机溶剂中,并将所得的照相添加剂溶液在表面活性聚合物存在下分散在水或亲水胶体组合物中,所述表面活性聚合物包含(a) 由式(I)表示的单元:其中R是具有4至22个碳原子的脂族烃基; m1和m2分别为0或1; B是-O-或-NH-; A是碳原子数为1〜50的二价脂肪族基团; M是氢原子或能够与磺酸基形成盐的阳离子基团,或者(b)含有上述式(I)表示的至少5摩尔%的单元的共聚物,其余的可共聚二价单元 并且包括其上连接有亚甲基的苯环和与其连接的具有亚甲基的萘环中的至少一个。