Polymeric dyes, overcoat compositions and thermal lithographic printing plates
    451.
    发明授权
    Polymeric dyes, overcoat compositions and thermal lithographic printing plates 有权
    聚合染料,外涂层组合物和热平版印刷版

    公开(公告)号:US08491993B2

    公开(公告)日:2013-07-23

    申请号:US12669805

    申请日:2008-07-24

    Abstract: A thermal lithographic printing plate overcoat composition comprising (a) a water-soluble polymeric dye having an absorption band between about 300 and about 600 nm; and (b) micro-particles or nano-particles is provided. A negative-working thermal lithographic printing plate comprising (a) a hydrophilic substrate; (b) a near infrared imaging layer disposed on the hydrophilic substrate; and (c) an overcoat layer disposed on the imaging layer, said overcoat layer comprising a water-soluble polymeric dye having an absorption band between about 300 and about 600 nm; and micro-particles or nano-particles is also provided. Finally, a water-soluble polymeric dye having an absorption band between about 300 and about 600 nm is provided.

    Abstract translation: 一种热平版印刷版外涂层组合物,其包含(a)具有在约300和约600nm之间的吸收带的水溶性聚合物染料; 和(b)微粒或纳米颗粒。 一种负性热平版印刷版,其包含(a)亲水性基材; (b)设置在亲水基板上的近红外成像层; 和(c)设置在成像层上的外涂层,所述外涂层包含具有在约300和约600nm之间的吸收带的水溶性聚合物染料; 还提供微粒或纳米颗粒。 最后,提供了吸收带在约300和约600nm之间的水溶性聚合物染料。

    Method for preparing lithographic printing plate precursors
    452.
    发明授权
    Method for preparing lithographic printing plate precursors 有权
    平版印刷版前体的制备方法

    公开(公告)号:US08377629B2

    公开(公告)日:2013-02-19

    申请号:US12996077

    申请日:2009-07-06

    Abstract: A method of preparing a lithographic printing plate in which no pre-heat step is used comprising the steps of:—providing a lithographic printing plate precursor comprising a support and a photopolymerizable image-recording layer, the image-recording layer comprising a monomer and a binder;—image-wise exposing the precursor in an exposure unit;—off press developing the exposed precursor with an aqueous solution in a processing unit; characterized in that the ratio of the total amount of monomer to the total amount of binder is at least 1 and the time lapse between exposing an image-area of the precursor and contacting the image-area with the aqueous solution is at least 1 minute.

    Abstract translation: 一种制备其中不使用预热步骤的平版印刷版的方法,包括以下步骤: - 提供包含载体和可光聚合图像记录层的平版印刷版原版,所述图像记录层包含单体和 粘合剂;在曝光单元中将前体曝光;在处理单元中用水溶液压制曝光的前体; 其特征在于,单体总量与粘合剂总量之比至少为1,暴露前体图像区域与图像区域与水溶液接触之间的时间间隔至少为1分钟。

    Negative-working imaging elements and methods of use
    453.
    发明授权
    Negative-working imaging elements and methods of use 失效
    负面影像元素和使用方法

    公开(公告)号:US08354216B2

    公开(公告)日:2013-01-15

    申请号:US12173220

    申请日:2008-07-15

    Abstract: Negative-working imageable elements such as lithographic printing plate precursors, include a free-radically polymerizable component, an initiator composition that is capable of generating free radicals sufficient to initiate polymerization of the free-radically polymerizable component upon exposure to imaging radiation in the presence of a radiation absorbing compound, a radiation absorbing compound, an aerobic free radical inhibitor, optionally a polymeric binder that is not a free radically polymerizable component, and an anaerobic free radical inhibitor. The molar ratio of the anaerobic free radical inhibitor to the aerobic free radical inhibitor is at least 1:1. This combination of inhibitors provides increased shelf life and good latent image stability particularly when the element includes a polymeric topcoat layer that functions as an oxygen barrier.

    Abstract translation: 负面工作的可成像元件如平版印刷版前体包括可自由基聚合的组分,引发剂组合物,其能够产生足够的自由基,以便在存在可见光辐射的情况下暴露于成像辐射时引发可自由基聚合的组分的聚合 辐射吸收化合物,辐射吸收化合物,需氧自由基抑制剂,任选的不是可自由基自由基组分的聚合物粘合剂和厌氧自由基抑制剂。 厌氧自由基抑制剂与好氧自由基抑制剂的摩尔比至少为1:1。 这种抑制剂的组合提供了增加的保质期和良好的潜影稳定性,特别是当元件包括用作氧阻隔层的聚合物顶涂层时。

    LITHOGRAPHIC PRINTING PLATE PRECURSOR AND PLATE MAKING METHOD THEREOF
    456.
    发明申请
    LITHOGRAPHIC PRINTING PLATE PRECURSOR AND PLATE MAKING METHOD THEREOF 有权
    平版印刷机前驱板及其制版方法

    公开(公告)号:US20120219911A1

    公开(公告)日:2012-08-30

    申请号:US13406095

    申请日:2012-02-27

    Abstract: A lithographic printing plate precursor includes, in the following order: a support; an image-recording layer which is capable of forming an image by removing an unexposed area of the image-recording layer with at least one of printing ink and dampening water on a printing machine after exposure and contains an infrared absorbing dye, a polymerization initiator, a polymerizable compound and a binder polymer having an alkylene oxide group; and a protective layer containing a hydrophilic polymer which contains at least a repeating unit represented by the formula (1) as defined herein, a repeating unit represented by the formula (2) as defined herein, and a repeating unit represented by the formula (4) as defined herein, and in which a content of the repeating unit represented by the formula (4) is from 0.3 to 5.0% by mole based on total repeating units of the hydrophilic polymer.

    Abstract translation: 平版印刷版原版按以下顺序包括:载体; 图像记录层,其能够通过在曝光后在印刷机上用印刷油墨和润版水中的至少一种去除图像记录层的未曝光区域而形成图像,并且包含红外吸收染料,聚合引发剂, 可聚合化合物和具有烯化氧基团的粘合剂聚合物; 和含有至少含有如本文定义的式(1)表示的重复单元的亲水性聚合物的保护层,由本文定义的式(2)表示的重复单元和由式(4)表示的重复单元 ),其中由式(4)表示的重复单元的含量相对于亲水性聚合物的总重复单元为0.3〜5.0摩尔%。

    Planographic printing plate precursor and printing method using the same
    459.
    发明授权
    Planographic printing plate precursor and printing method using the same 有权
    普通印版前体和印刷方法使用相同

    公开(公告)号:US08221957B2

    公开(公告)日:2012-07-17

    申请号:US12165205

    申请日:2008-06-30

    Abstract: The invention provides a planographic printing plate precursor comprising: a hydrophilic support; and an image recording layer that is provided on the support, the image recording layer comprising: an infrared ray absorbing agent (A); a polymerization initiator (B); a polymerizable monomer (C); and a specific polymer compound (D) having an alkyleneoxy group in its molecule and having, in a side chain thereof at least one specific group. The invention further provides a printing method using the planographic printing plate precursor, wherein no specific development process is required for performing printing.

    Abstract translation: 本发明提供一种平版印刷版前体,其包括:亲水载体; 以及设置在所述支撑体上的图像记录层,所述图像记录层包括:红外线吸收剂(A); 聚合引发剂(B); 可聚合单体(C); 和在其分子中具有亚烷氧基的特定聚合物化合物(D),并且在其侧链中具有至少一个特定基团。 本发明还提供一种使用平版印刷版原版的印刷方法,其中不需要特定的显影处理来进行印刷。

    Negative working, heat sensitive lithographic printing plate precursor
    460.
    发明授权
    Negative working, heat sensitive lithographic printing plate precursor 有权
    负工作,热敏平版印刷版前体

    公开(公告)号:US08216769B2

    公开(公告)日:2012-07-10

    申请号:US12300805

    申请日:2007-05-22

    Abstract: A heat-sensitive negative-working lithographic printing plate precursor includes a support having a hydrophilic surface or which is provided with a hydrophilic layer and a coating provided thereon, the coating including an image-recording layer which includes hydrophobic thermoplastic polymer particles, a binder, and an infrared absorbing dye; wherein the hydrophobic thermoplastic polymer particles have an average particle diameter, measured by Photon Correlation Spectroscopy, of more than 10 nm and less than 40 nm; the amount of the IR-dye, without taking into account an optional counter ion, is more than 0.80 mg per m2 of the total surface of the thermoplastic polymer particles, measured by Hydrodynamic Fractionation; and the amount of hydrophobic thermoplastic polymer particles relative to the total weight of the ingredients of the imaging layer is at least 60%.

    Abstract translation: 热敏负性平版印刷版原版包括具有亲水性表面的或具有亲水层的涂层及其上设置的涂层,所述涂层包括图像记录层,该图像记录层包括疏水性热塑性聚合物颗粒,粘合剂, 和红外吸收染料; 其中所述疏水热塑性聚合物颗粒具有通过光子相关光谱测量的平均粒径大于10nm且小于40nm; 通过流体力学分级测量,不考虑任选的抗衡离子的IR染料的量大于0.80mg / m 2热塑性聚合物颗粒的总表面; 并且疏水性热塑性聚合物颗粒相对于成像层的成分的总重量的量为至少60%。

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