摘要:
The present invention provides a radiation curable vinyl-silicone pressure-sensitive adhesive composition which combines the advantages of silicone and acrylate pressure-sensitive adhesives and which does not experience gross phase separation problems. The composition comprises at least about 20 weight percent of a certain telechelic silicone polymer, about 0.5 to about 80 weight percent of monofunctional free-radically polymerizable vinyl monomer copolymerizable with the silicone polymer, and a sufficient amount of a silicate MQ tackifying resin to impart a degree of adhesive tack to the cured composition at the use temperature, wherein the weight percentages of the silicone polymer and the monomer are based upon the total weight of the silicone polymer and monomer.
摘要:
A composition which is curable to an elastomer comprising:A polymer or mixture of polymers of the formula ##STR1## wherein: X are monovalent moieties having ethylenic unsaturation which can be the same or different;Y are divalent linking groups which can be the same or different;m is an integer of 0 to 1;D are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, an alkyl group of 1 to about 10 carbon atoms, aryl, and substituted aryl;R are divalent hydrocarbon groups which can be the same or different;R.sup.1 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl;R.sup.2 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl;R.sup.3 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl;R.sup.4 are monovalent moieties which can be the same or different selenited from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; andn is an integer of about 270 to about 1000.A composition which is curable to a pressure sensitive adhesive comprising the above polymer and a sufficient amount of tackifier. The invention also relates to fluorosilane compounds useful in the preparation of silicone macromonomer, their preparation and the preparation of silicone macromonomer.
摘要:
Pressure-sensitive adhesive tape having low adhesion backsizes and release coatings that can be written on with solvent and water-based inks, the indicia remaining firmly bonded and resisting smearing. The coatings comprise copolymers of (A) free radically polymerizable vinyl monomer, (B) polar monomer in sufficient amount to impart a hydrated Tg of -15.degree. C. to 35.degree. C. and a difference of at least 20.degree. C. between the hydrated and actual Tgs, and (C) siloxane-based polymer of a type and in an amount that will impart a satisfactory release value.
摘要:
A moldable, putty-like adhesive mass is disclosed comprising a blend of (1) an acrylate terpolymer adhesive containing a hydrophilic macromolecular moiety and (2) a reinforcing material which is a carbonylamido group containing polymer. The adhesive blends are moisture vapor permeable and non-water swellable. They are useful in many medical applications.