公开(公告)号：US5514730A

公开(公告)日：1996-05-07

申请号：US279718

申请日：1994-07-25

Applicant: Mieczyslaw H. Mazurek ,  Steven S. Kantner ,  David J. Kinning ,  Yvan A. Bogaert

Inventor： Mieczyslaw H. Mazurek ,  Steven S. Kantner ,  David J. Kinning ,  Yvan A. Bogaert

IPC: C08F299/08 ,  C08F290/00 ,  C09J4/00 ,  C09J4/06 ,  C09J7/02 ,  C09J183/00 ,  C09J183/02 ,  C09J183/08 ,  C09J183/10 ,  C09J183/07

CPC classification number: C09J183/08 ,  C09J183/10 ,  C09J4/06 ,  Y10S525/925 ,  Y10S526/931

Abstract: The present invention provides a radiation curable vinyl-silicone pressure-sensitive adhesive composition which combines the advantages of silicone and acrylate pressure-sensitive adhesives and which does not experience gross phase separation problems. The composition comprises at least about 20 weight percent of a certain telechelic silicone polymer, about 0.5 to about 80 weight percent of monofunctional free-radically polymerizable vinyl monomer copolymerizable with the silicone polymer, and a sufficient amount of a silicate MQ tackifying resin to impart a degree of adhesive tack to the cured composition at the use temperature, wherein the weight percentages of the silicone polymer and the monomer are based upon the total weight of the silicone polymer and monomer.

Abstract translation: 本发明提供了可聚合有机硅和丙烯酸酯压敏粘合剂的优点并且不经历总相分离问题的可辐射固化的乙烯基 - 硅氧烷压敏粘合剂组合物。 组合物包含至少约20重量％的某些遥爪硅氧烷聚合物，约0.5至约80重量％的可与硅氧烷聚合物共聚的单官能可自由基聚合的乙烯基单体，以及足够量的硅酸盐MQ增粘树脂，以赋予 在使用温度下对固化的组合物的粘合程度，其中硅氧烷聚合物和单体的重量百分比是基于有机硅聚合物和单体的总重量。

公开(公告)号：US5314748A

公开(公告)日：1994-05-24

申请号：US109004

申请日：1993-08-16

Applicant: Mieczyslaw H. Mazurek ,  Steven S. Kantner ,  Charles M. Leir ,  Yvan A. Bogaert ,  Robert K. Galkiewicz ,  Audrey A. Sherman

Inventor： Mieczyslaw H. Mazurek ,  Steven S. Kantner ,  Charles M. Leir ,  Yvan A. Bogaert ,  Robert K. Galkiewicz ,  Audrey A. Sherman

IPC: C07F7/08 ,  C07F7/12 ,  C08F299/08 ,  C08G77/26 ,  C08G77/388 ,  C09J7/02 ,  C09J155/00 ,  C09J183/08 ,  B32B7/12 ,  B32B9/04

CPC classification number: C07F7/12 ,  C07F7/0854 ,  C08F299/08 ,  C08G77/26 ,  C08G77/388 ,  C09J155/005 ,  C09J183/08 ,  C09J7/0207 ,  Y10T428/2809 ,  Y10T428/2852 ,  Y10T428/2896 ,  Y10T428/31663

Abstract: A composition which is curable to an elastomer comprising:A polymer or mixture of polymers of the formula ##STR1## wherein: X are monovalent moieties having ethylenic unsaturation which can be the same or different;Y are divalent linking groups which can be the same or different;m is an integer of 0 to 1;D are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, an alkyl group of 1 to about 10 carbon atoms, aryl, and substituted aryl;R are divalent hydrocarbon groups which can be the same or different;R.sup.1 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl;R.sup.2 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl;R.sup.3 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl;R.sup.4 are monovalent moieties which can be the same or different selenited from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; andn is an integer of about 270 to about 1000.A composition which is curable to a pressure sensitive adhesive comprising the above polymer and a sufficient amount of tackifier. The invention also relates to fluorosilane compounds useful in the preparation of silicone macromonomer, their preparation and the preparation of silicone macromonomer.

Abstract translation: 可固化成弹性体的组合物，其包含：下式的聚合物或聚合物的混合物，其中：X是具有烯属不饱和度的单价部分，其可以相同或不同; Y是可以相同或不同的二价连接基团; m为0〜1的整数; D是可以相同或不同的一价部分，其选自氢，1至约10个碳原子的烷基，芳基和取代的芳基; R是可以相同或不同的二价烃基; R1是可以相同或不同的一价部分，其选自烷基，取代的烷基，芳基和取代的芳基; R2是可以相同或不同的一种选自烷基，取代的烷基，芳基和取代的芳基的一价部分; R3是可以相同或不同的一种选自烷基，取代的烷基，乙烯基，芳基和取代的芳基的一价部分; R4是可以与由烷基，取代的烷基，乙烯基，芳基和取代的芳基组成的组相同或不同的一价部分; 并且n是约270至约1000的整数。可包含上述聚合物和足够量的增粘剂的压敏粘合剂可固化的组合物。 本发明还涉及可用于制备硅氧烷大分子单体的氟硅烷化合物，其制备和硅氧烷大分子单体的制备。

公开(公告)号：US5482991A

公开(公告)日：1996-01-09

申请号：US307936

申请日：1994-09-16

Applicant: Ramesh C. Kumar ,  Albert I. Everaerts ,  Yvan A. Bogaert

Inventor： Ramesh C. Kumar ,  Albert I. Everaerts ,  Yvan A. Bogaert

IPC: C09J131/02 ,  C09J131/00 ,  C09J131/04 ,  C09J133/02 ,  C09J133/04 ,  C09J133/20 ,  C09J133/26 ,  C09J137/00 ,  C09J139/06 ,  C09J151/08 ,  C09J155/00 ,  C09J183/00 ,  C09J183/10 ,  C08L83/00

CPC classification number: C09J151/085 ,  C09J155/005 ,  C09J183/10

Abstract: Novel pressure-sensitive adhesives are described which show significant resistance to solvents and working fluids such as jet fuel, hydraulic fluid, de-icing fluid and the like. Adhesive compositions comprise nonaqueous dispersions of copolymers of acrylic monomers prepared in the presence of a vinyl-substituted fluoroalkyl siloxane having the general formula I and a macromonomeric stabilizer. The adhesives prepared from the adhesive compositions exhibit excellent adhesion to glass, aluminum, and low surface-energy materials such as fluoroalkyl siloxane elastomers.The fluoroalkyl siloxane has the formula ##STR1##

Abstract translation: 描述了新型压敏粘合剂，其显示出对溶剂和工作流体如喷气燃料，液压油，除冰液等的显着抵抗性。 粘合剂组合物包含在具有通式I的乙烯基取代的氟烷基硅氧烷和大分子单体稳定剂的存在下制备的丙烯酸单体的共聚物的非水分散体。 由粘合剂组合物制备的粘合剂对玻璃，铝和低表面能材料如氟烷基硅氧烷弹性体表现出优异的粘合性。 氟烷基硅氧烷具有式（I）

公开(公告)号：US5270111A

公开(公告)日：1993-12-14

申请号：US966905

申请日：1992-10-27

Applicant: Francois C. D'Haese ,  Katharina J. Bischof ,  Peter Brink ,  Yvan A. Bogaert

Inventor： Francois C. D'Haese ,  Katharina J. Bischof ,  Peter Brink ,  Yvan A. Bogaert

IPC: A61L15/58 ,  A61L15/62 ,  C09J7/02 ,  C09J7/04 ,  C09J11/06 ,  C09J123/06 ,  A61L15/24

CPC classification number: C09J7/0217 ,  A61L15/585 ,  A61L15/62 ,  Y10T428/2857

Abstract: A method of using a pressure sensitive adhesive to form a moisture resistant, water-dispersible tape is provided. The adhesive and tape are resistant to autoclavation conditions and/or moisture and body fluids during usage, and are water-dispersible when immersed in aqueous solutions. The tape may be used with cloth body coverings, such as garments such as hospital gowns, drapes, dressings, diapers and other body coverings which require cloth to cloth or cloth to skin adhesion in the presence of moisture and bodily fluids yet be dispersible from such body coverings during laundering or other aqueous alkali immersion.

Abstract translation: 提供了使用压敏粘合剂形成防潮水分散性胶带的方法。 粘合剂和胶带在使用期间耐高压灭菌条件和/或湿气和体液，并且当浸入水溶液时是水分散的。 胶带可以与布身体覆盖物一起使用，例如衣服，例如医院长袍，窗帘，敷料，尿布和其他身体覆盖物，其需要布料或布料在水分和体液存在下的皮肤粘附，但是可以从其分散 洗衣期间的身体覆盖物或其他含水碱浸渍。

公开(公告)号：US5125995A

公开(公告)日：1992-06-30

申请号：US580116

申请日：1990-09-10

Applicant: Francois C. D'Haese ,  Katharina J. Bischof ,  Peter Brink ,  Yvan A. Bogaert

Inventor： Francois C. D'Haese ,  Katharina J. Bischof ,  Peter Brink ,  Yvan A. Bogaert

IPC: A61L15/58 ,  A61L15/62 ,  C09J7/02 ,  C09J133/08

CPC classification number: C09J7/0217 ,  A61L15/585 ,  A61L15/62 ,  Y10T428/2891

Abstract: A method of using a pressure sensitive adhesive to form a moisture resistant, water-dispersible tape is provided. The adhesive and tape are resistant to autoclavation conditions and/or moisture and body fluids during usage, and are water-dispersible when immersed in aqueous solutions. The tape may be used with cloth body coverings, such as garments such as hospital gowns, drapes, dressings, diapers and other body coverings which require cloth to cloth or cloth to skin adhesion in the presence of moisture and bodily fluids yet be dispersible from such body coverings during laundering or other aqueous alkali immersion.

Abstract translation: 提供了使用压敏粘合剂形成防潮水分散性胶带的方法。 粘合剂和胶带在使用期间耐高压灭菌条件和/或湿气和体液，并且当浸入水溶液时是水分散的。 胶带可以与布身体覆盖物一起使用，例如衣服，例如医院长袍，窗帘，敷料，尿布和其他身体覆盖物，其需要布料或布料在水分和体液存在下的皮肤粘附，但是可以从其分散 洗衣期间的身体覆盖物或其他含水碱浸渍。

公开(公告)号：US08288005B2

公开(公告)日：2012-10-16

申请号：US13056135

申请日：2009-04-16

Applicant: Anthony P. Manzara ,  Yvan A. Bogaert ,  Michael D. Crandall ,  Robert E. Eggers ,  Aron Y. Goodner ,  Werner M. A. Grootaert

Inventor： Anthony P. Manzara ,  Yvan A. Bogaert ,  Michael D. Crandall ,  Robert E. Eggers ,  Aron Y. Goodner ,  Werner M. A. Grootaert

IPC: B32B27/00

CPC classification number: C08K5/28 ,  Y10T428/139 ,  Y10T428/1397 ,  Y10T428/3154 ,  Y10T428/31544 ,  C08L27/12

Abstract: Compositions having a fluoropolymer with a nitrile-containing cure site and at least a) a mono azide with at least one functional group in the beta position, or b) a polyazide, as a curing agent as well as methods and articles thereof are described. Articles of this disclosure are found to exhibit excellent chemical resistance and thermal stability.

Abstract translation: 具有具有含腈固化部位的含氟聚合物和至少a）在β位具有至少一个官能团的单叠氮化物的组合物，或b）作为固化剂的聚叠氮化合物及其制备方法。 发现本公开的制品表现出优异的耐化学性和热稳定性。

公开(公告)号：US20100125120A1

公开(公告)日：2010-05-20

申请号：US12271222

申请日：2008-11-14

Applicant: Michael D. Crandall ,  Yvan A. Bogaert ,  Aron Y. Goodner ,  Werner M.A. Grootaert ,  Anthony P. Manzara

Inventor： Michael D. Crandall ,  Yvan A. Bogaert ,  Aron Y. Goodner ,  Werner M.A. Grootaert ,  Anthony P. Manzara

IPC: C08L49/00 ,  C08F8/30 ,  C08L67/06 ,  C08L55/00

CPC classification number: C09D133/00 ,  C08F220/12 ,  C08F220/18 ,  C08F220/34 ,  C08K5/28 ,  C08L2312/00 ,  C08F220/06 ,  C08F238/00 ,  C08F220/14

Abstract: Described herein are substantially linear copolymeric compositions having at least two azide groups and at least two non-activated acetylene groups. The azide groups and the non-activated acetylene groups are reacted to cure the substantially linear copolymer composition. Also, described are methods of making and using such substantially linear copolymeric compositions.

Abstract translation: 本文描述的是具有至少两个叠氮基和至少两个非活化乙炔基团的基本上线性的共聚组合物。 使叠氮化物基团和非活化乙炔基团反应以固化基本上线性的共聚物组合物。 还描述了制备和使用这种基本上线性的共聚组合物的方法。

公开(公告)号：US06245838B1

公开(公告)日：2001-06-12

申请号：US09381112

申请日：1999-09-15

Applicant: Yvan A. Bogaert ,  Eric B. T. Moonen ,  Robert R. L. Smolders ,  Francois C. D'Haese

Inventor： Yvan A. Bogaert ,  Eric B. T. Moonen ,  Robert R. L. Smolders ,  Francois C. D'Haese

IPC: C08F220

CPC classification number: C08F20/12 ,  C08F2/18 ,  Y10T428/2998

Abstract: A method for aqueous bead-type suspension polymerization of (meth)acrylic monomers to prepare non-agglomerating, storage stable (meth)acrylic polymer beads which are extrudable at low temperatures. The invention also relates to the polymer beads and to their use as adhesive, in particular as a pressure sensitive adhesive. The invention also discloses adhesive compositions comprising the polymer beads.

Abstract translation: （甲基）丙烯酸单体的水性珠型悬浮聚合的方法，以制备在低温下可挤出的非聚集，储存稳定的（甲基）丙烯酸聚合物珠粒。 本发明还涉及聚合物珠粒及其作为粘合剂的用途，特别是作为压敏粘合剂。 本发明还公开了包含聚合物珠粒的粘合剂组合物。

公开(公告)号：US5079047A

公开(公告)日：1992-01-07

申请号：US351085

申请日：1989-05-12

Applicant: Yvan A. Bogaert ,  Martine H. A. Deketele

Inventor： Yvan A. Bogaert ,  Martine H. A. Deketele

IPC: C08F2/48 ,  C08L23/08 ,  C09J4/02 ,  C09J7/02 ,  C09J133/04

CPC classification number: C09J7/0217 ,  C09J133/04 ,  C08L23/08 ,  C09J2201/606 ,  Y10S526/931 ,  Y10T428/1452 ,  Y10T428/2809 ,  Y10T428/2839 ,  Y10T428/3192 ,  Y10T428/31928

Abstract: The current invention provides a photopolymerized pressure-sensitive adhesive which adheres well to all common surfaces and has an outstanding ability to bond to plasticized vinyl substrates and to remain firmly bonded thereto even after the in contact therewith for extended periods of time comprising the photopolymerization reaction product of a mixture containing about: 60-95 parts of alkyl acrylate; 5-40 parts monoethylenically unsaturated polar copolymerizable monomer; 10-30 parts ethylene vinylacetate copolymer containing about 40% to 70% vinylacetate; and 0.1-1 part photoinitiator.

公开(公告)号：US08445601B2

公开(公告)日：2013-05-21

申请号：US12271222

申请日：2008-11-14

Applicant: Michael D. Crandall ,  Yvan A. Bogaert ,  Aron Y. Goodner ,  Werner M. A. Grootaert ,  Anthony P. Manzara

Inventor： Michael D. Crandall ,  Yvan A. Bogaert ,  Aron Y. Goodner ,  Werner M. A. Grootaert ,  Anthony P. Manzara

IPC: C08C19/22

CPC classification number: C09D133/00 ,  C08F220/12 ,  C08F220/18 ,  C08F220/34 ,  C08K5/28 ,  C08L2312/00 ,  C08F220/06 ,  C08F238/00 ,  C08F220/14

Abstract: Described herein are substantially linear copolymeric compositions having at least two azide groups and at least two non-activated acetylene groups. The azide groups and the non-activated acetylene groups are reacted to cure the substantially linear copolymer composition. Also, described are methods of making and using such substantially linear copolymeric compositions.

Abstract translation: 本文描述的是具有至少两个叠氮基和至少两个非活化乙炔基团的基本上线性的共聚组合物。 使叠氮化物基团和非活化乙炔基团反应以固化基本上线性的共聚物组合物。 还描述了制备和使用这种基本上线性的共聚组合物的方法。