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41.发明申请Methods for polymerizing macrocyclic polyester oligomers using catalyst promoters 失效使用催化剂促进剂聚合大环聚酯低聚物的方法公开(公告)号：US20060115666A1
公开(公告)日：2006-06-01
申请号：US11329454
申请日：2006-01-10
申请人： Tohru Takekoshi , Peter Phelps , Yi-Feng Wang , Steven Winckler
发明人： Tohru Takekoshi , Peter Phelps , Yi-Feng Wang , Steven Winckler
CPC分类号： C08F290/00 , C08G63/85 , C08G2650/34 , C08J5/04 , C08J2367/02 , C08K5/04 , C08K5/57 , C08K7/02 , C08L63/00 , C08L67/02 , C08L71/02 , Y10T428/31786 , C08L2666/22 , C08L2666/14
摘要： The invention provides methods and formulations involving the use of promoters that accelerate the polymerization of macrocyclic polyester oligomers (MPOs). For example, in certain embodiments, the invention provides blends of macrocyclic polyester oligomer (MPO), catalyst, and promoter that are substantially stable at ambient temperature for a period of time. The blend material may be stored without premature polymerization of MPO or deactivation of catalyst. The invention also provides processes employing one-part, ready-to-polymerize blends that contain MPO, catalyst, and promoter, as well as processes in which the catalyst and promoter are used in separate streams and are contacted when it is desired to accelerate polymerization of MPO. Methods of the invention offer advantages in the manufacture of thermoplastic parts and composites, due at least in part to the unique properties of MPO.
摘要翻译： 本发明提供涉及使用促进大环聚酯低聚物（MPO）的聚合的促进剂的方法和配方。 例如，在某些实施方案中，本发明提供在环境温度下基本稳定一段时间的大环聚酯低聚物（MPO），催化剂和促进剂的共混物。 可以不经MPO的过早聚合或催化剂失活来储存共混材料。 本发明还提供了使用含有MPO，催化剂和促进剂的单组分即时聚合共混物的方法，以及其中催化剂和助催化剂在分开的流中使用并且当需要加速聚合时接触的方法 的MPO。 本发明的方法提供了制造热塑性部件和复合材料的优点，至少部分地由于MPO的独特性质。
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42.发明授权Intimate physical mixtures containing macrocyclic polyester oligomer and filler 失效含有大环聚酯低聚物和填料的亲水性物理混合物公开(公告)号：US06960626B2
公开(公告)日：2005-11-01
申请号：US10859784
申请日：2004-06-03
CPC分类号： C08G63/82 , C08G63/78 , C08G2650/34 , C08K3/34 , C08K7/00 , C08K2201/016
摘要： The invention provides intimate physical mixtures of macrocyclic polyester oligomer (MPO) and filler, as well as methods for their preparation and use. Improved dispersion of filler in a polymer matrix is achieved upon polymerization, and larger amounts of filler with high aspect ratio can be used. In one aspect, the invention provides mixtures of MPO with magnesium silicate. In another aspect, the invention provides a mixture of MPO, filler, and polymerization catalyst as a one-part, ready-to-polymerize material with a long shelf life. The one-part material can be used, for example, in the manufacture of parts without modification of existing processing equipment.
摘要翻译： 本发明提供大环聚酯低聚物（MPO）和填料的亲密物理混合物，以及其制备和使用方法。 填料在聚合物基质中的分散性得到改善，可以使用较大量的高纵横比的填料。 一方面，本发明提供了MPO与硅酸镁的混合物。 另一方面，本发明提供了MPO，填料和聚合催化剂的混合物，作为具有长保质期的单组分即时聚合材料。 单件材料可以用于例如零件的制造而不改变现有的加工设备。
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43.发明授权Method for preparing polyether copolymers with polycarbonates and polyarylates 有权用聚碳酸酯和聚芳酯制备聚醚共聚物的方法公开(公告)号：US06815483B2
公开(公告)日：2004-11-09
申请号：US10016161
申请日：2001-12-10
申请人： Tohru Takekoshi
发明人： Tohru Takekoshi
IPC分类号： C08L6700
CPC分类号： C08G75/23 , C08G64/18 , C08G73/1046 , C08G73/12 , C08G73/123 , C08L71/00 , C08L2666/18
摘要： Copolymers of polycarbonates or polyarylates with polyether polymers such as polyethersulfones, polyetherketones, and polyetherimides are prepared by reaction of the polyether polymer-forming reagents, e.g., bisphenol A disodium salt and bis(4-chlorophenyl) sulfone, in the presence of the polycarbonate or polyarylate. The reaction may take place in a dipolar aprotic solvent, or in a water-immiscible aromatic solvent in the presence of a phase transfer catalyst, preferably a hexaalkylguanidinium halide. Hydroxy-terminated polyether oligomers may be produced from the copolymers by saponification of carbonate or ester groups.
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公开(公告)号：US06583233B2
公开(公告)日：2003-06-24
申请号：US10020376
申请日：2001-12-14
申请人： Tohru Takekoshi
发明人： Tohru Takekoshi
IPC分类号： C08F28302
CPC分类号： C08G75/23 , C08G64/18 , C08G73/1046 , C08G73/12 , C08G73/123 , C08L71/00 , C08L2666/18
摘要： Copolymers of polycarbonates or polyarylates with polyether polymers such as polyethersulfones, polyetherketones, and polyetherimides are prepared by reaction of the polyether polymer-forming reagents, e.g., bisphenol A disodium salt and bis(4-chlorophenyl) sulfone, in the presence of the polycarbonate or polyarylate. The reaction may take place in a dipolar aprotic solvent, or in a water-immiscible aromatic solvent in the presence of a phase transfer catalyst, preferably a hexaalkylguanidinium halide. Hydroxy-terminated polyether oligomers may be produced from the copolymers by saponification of carbonate or ester groups.
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公开(公告)号：US06197924B1
公开(公告)日：2001-03-06
申请号：US09451229
申请日：1999-11-29
申请人： Tohru Takekoshi
发明人： Tohru Takekoshi
IPC分类号： C08F600
摘要： Polyethersulfones derived from dihydroxybiphenyls or dihydroxybenzenes, especially 4,4′-dihydroxybiphenyl, are isolated by crystallization from a solvent, preferably a water-immiscible aromatic solvent. Crystallization may be achieved by cooling from the reaction temperature to a temperature in the range of about 20-100° C., optionally with the use of a crystallization aid such as preformed polyethersulfone crystals. The crystallized polyethersulfone is then separated by filtration and by-product salts are removed therefrom by extraction with water.
摘要翻译： 衍生自二羟基联苯或二羟基苯，特别是4,4'-二羟基联苯的聚醚砜通过从溶剂，优选与水不混溶的芳族溶剂中结晶分离。 结晶可以通过从反应温度冷却至约20-100℃范围内的温度，任选地使用结晶助剂如预先形成的聚醚砜晶体来实现。 然后通过过滤分离结晶的聚醚砜，通过用水萃取除去副产物盐。
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46.发明授权Method for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers 失效用于聚合大环聚（亚烷基二羧酸酯）低聚物的方法
公开(公告)号：US5591800A
公开(公告)日：1997-01-07
申请号：US565366
申请日：1995-11-30
申请人： Tohru Takekoshi , Eric J. Pearce
发明人： Tohru Takekoshi , Eric J. Pearce
摘要： Macrocyclic polyester oligomers are converted to linear polyesters by contact at a temperature of about 160.degree.-300.degree. C. with a cyclic titanium catalyst such as di-(1-butyl)-2,2-dimethylpropane-1,3-dioxytitanate, bis(2,2-dimethyl-1,3-propylene) titanate or 1-(1-butoxy)-4-methyl-2,6,7-trioxa-1-titanabicyclo[2.2.2]octane. Such catalysts have high activity and produce linear or branched polyesters of very high molecular weight.
摘要翻译： 大环聚酯低聚物通过在约160-300℃的温度下与环状钛催化剂如二 - （1-丁基）-2,2-二甲基丙烷-1,3-二氧钛酸酯，双 （2,2-二甲基-1,3-丙烯）钛酸酯或1-（1-丁氧基）-4-甲基-2,6,7-三氧杂-1-氮杂二环[2.2.2]辛烷。 这种催化剂具有高活性并产生非常高分子量的直链或支链聚酯。
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47.发明授权Method for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers 失效用于聚合大环聚（亚烷基二羧酸酯）低聚物的方法
公开(公告)号：US5527976A
公开(公告)日：1996-06-18
申请号：US371715
申请日：1995-01-12
申请人： Tohru Takekoshi , Eric J. Pearce
发明人： Tohru Takekoshi , Eric J. Pearce
摘要： Macrocyclic polyester oligomers are converted to linear polyesters by contact at a temperature of about 160.degree.-300.degree. C. with a cyclic titanium catalyst such as di-(1-butyl)-2,2-dimethylpropane-1,3-dioxytitanate, bis(2,2-dimethyl-1,3-propylene)titanate or 1-(1-butoxy)-4-methyl-2,6,7-trioxa-1-titanabicyclo[2.2.2]octane. Such catalysts have high activity and produce linear or branched polyesters of very high molecular weight.
摘要翻译： 大环聚酯低聚物通过在约160-300℃的温度下与环状钛催化剂如二 - （1-丁基）-2,2-二甲基丙烷-1,3-二氧钛酸酯，双 （2,2-二甲基-1,3-丙烯）钛酸酯或1-（1-丁氧基）-4-甲基-2,6,7-三氧杂-1-氮杂二环[2.2.2]辛烷。 这种催化剂具有高活性并产生非常高分子量的直链或支链聚酯。
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48.发明授权Method for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers 失效用于聚合大环聚（亚烷基二羧酸酯）低聚物的方法
公开(公告)号：US5389719A
公开(公告)日：1995-02-14
申请号：US262795
申请日：1994-06-20
申请人： Tohru Takekoshi , Eric J. Pearce
发明人： Tohru Takekoshi , Eric J. Pearce
摘要： Cyclic tin catalysts are employed for the preparation of branched polyesters from macrocyclic polyester oligomers. They are less susceptible than previously known catalysts to the presence of acidic impurities in the oligomer compositions,
摘要翻译： 循环锡催化剂用于从大环聚酯低聚物制备支化聚酯。 它们比先前已知的催化剂对低聚物组合物中存在酸性杂质更不敏感，
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公开(公告)号：US5194566A
公开(公告)日：1993-03-16
申请号：US744044
申请日：1991-08-12
CPC分类号： C08G73/1064 , C08G73/106 , C08G77/42
摘要： Block copolymers of polyarylene sulfide with either polyimide, or polydiorgano siloxane are provided. Various methods for making such block copolymers are shown which are useful as compatabilizers for blends of polyarylene sulfide with polyimides and polydiorgano siloxanes.
摘要翻译： 提供聚芳硫醚与聚酰亚胺或聚二有机硅氧烷的嵌段共聚物。 显示了制备这种嵌段共聚物的各种方法，其可用作聚芳硫醚与聚酰亚胺和聚二有机硅氧烷共混物的相容剂。
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50.发明授权Reactively capped polyarylene sulfide and method and intermediates for their preparation 失效反应性封端的聚芳硫醚及其制备方法和中间体
公开(公告)号：US5015703A
公开(公告)日：1991-05-14
申请号：US614967
申请日：1990-11-19
IPC分类号： C07D209/48 , C07D405/14 , C08G75/02
CPC分类号： C07D209/48 , C07D405/14 , C08G75/0222 , C08G75/029
摘要： Polyarylene sulfides react with disulfides containing reactive functional groups, typically at temperatures within the range of about 225.degree.-375.degree. C., yielding reactively capped polyarylene sulfides. The preferred reactive functional groups are amino groups and carboxy groups and functional derivatives thereof.
摘要翻译： 聚亚芳基硫化物与含有反应性官能团的二硫化物反应，通常在约225-375℃的温度范围内，产生反应性封端的聚亚芳基硫化物。 优选的反应性官能团是氨基和羧基及其官能衍生物。
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