公开(公告)号：US07256241B2

公开(公告)日：2007-08-14

申请号：US11329454

申请日：2006-01-10

申请人： Tohru Takekoshi ,  Peter D. Phelps ,  Yi-Feng Wang ,  Steven J. Winckler

发明人： Tohru Takekoshi ,  Peter D. Phelps ,  Yi-Feng Wang ,  Steven J. Winckler

IPC分类号： C08F275/00 ,  C08G63/85 ,  C08G63/78

CPC分类号： C08F290/00 ,  C08G63/85 ,  C08G2650/34 ,  C08J5/04 ,  C08J2367/02 ,  C08K5/04 ,  C08K5/57 ,  C08K7/02 ,  C08L63/00 ,  C08L67/02 ,  C08L71/02 ,  Y10T428/31786 ,  C08L2666/22 ,  C08L2666/14

摘要： The invention provides methods and formulations involving the use of promoters that accelerate the polymerization of macrocyclic polyester oligomers (MPOs). For example, in certain embodiments, the invention provides blends of macrocyclic polyester oligomer (MPO), catalyst, and promoter that are substantially stable at ambient temperature for a period of time. The blend material may be stored without premature polymerization of MPO or deactivation of catalyst. The invention also provides processes employing one-part, ready-to-polymerize blends that contain MPO, catalyst, and promoter, as well as processes in which the catalyst and promoter are used in separate streams and are contacted when it is desired to accelerate polymerization of MPO. Methods of the invention offer advantages in the manufacture of thermoplastic parts and composites, due at least in part to the unique properties of MPO.

摘要翻译： 本发明提供涉及使用促进大环聚酯低聚物（MPO）的聚合的促进剂的方法和配方。 例如，在某些实施方案中，本发明提供在环境温度下基本稳定一段时间的大环聚酯低聚物（MPO），催化剂和促进剂的共混物。 可以不经MPO的过早聚合或催化剂失活来储存共混材料。 本发明还提供了使用含有MPO，催化剂和促进剂的单组分即时聚合共混物的方法，以及其中催化剂和助催化剂在分开的流中使用并且当需要加速聚合时接触的方法 的MPO。 本发明的方法提供了制造热塑性部件和复合材料的优点，至少部分地由于MPO的独特性质。

公开(公告)号：US07230044B2

公开(公告)日：2007-06-12

申请号：US11260509

申请日：2005-10-27

申请人： Tohru Takekoshi ,  Steven R. Bahr ,  Steven J. Winckler

发明人： Tohru Takekoshi ,  Steven R. Bahr ,  Steven J. Winckler

IPC分类号： C08K3/00 ,  C08K3/34

CPC分类号： C08G63/82 ,  C08G63/78 ,  C08G2650/34 ,  C08K3/34 ,  C08K7/00 ,  C08K2201/016

摘要： The invention provides intimate physical mixtures of macrocyclic polyester oligomer (MPO) and filler, as well as methods for their preparation and use. Improved dispersion of filler in a polymer matrix is achieved upon polymerization, and larger amounts of filler with high aspect ratio can be used. In one aspect, the invention provides mixtures of MPO with magnesium silicate. In another aspect, the invention provides a mixture of MPO, filler, and polymerization catalyst as a one-part, ready-to-polymerize material with a long shelf life. The one-part material can be used, for example, in the manufacture of parts without modification of existing processing equipment.

摘要翻译： 本发明提供大环聚酯低聚物（MPO）和填料的亲密物理混合物，以及其制备和使用方法。 填料在聚合物基质中的分散性得到改善，可以使用较大量的高纵横比的填料。 一方面，本发明提供了MPO与硅酸镁的混合物。 另一方面，本发明提供了MPO，填料和聚合催化剂的混合物，作为具有长保质期的单组分即时聚合材料。 单件材料可以用于例如零件的制造而不改变现有的加工设备。

公开(公告)号：US20060205916A1

公开(公告)日：2006-09-14

申请号：US11367788

申请日：2006-03-03

申请人： Tohru Takekoshi ,  Steven Bahr

发明人： Tohru Takekoshi ,  Steven Bahr

IPC分类号： C08G63/02

CPC分类号： C08J3/20 ,  C08G63/81 ,  C08J2367/02

摘要： The invention provides methods for preparing composites of polyester and layered compounds. In one embodiment, the invention provides a method for preparing a composite of a poly(alkylene terephthalate) and a cation-modified layered compound via in-situ polycondensation in solvent. In another embodiment, composites are made with polyesters of average molecular weight of 10,000 g/mol or more by mixing the polyester and a layered compound in the presence of a solvent, such as ortho-dichlorobenzene.

摘要翻译： 本发明提供了制备聚酯和层状化合物的复合材料的方法。 在一个实施方案中，本发明提供了通过在溶剂中原位缩聚来制备聚（对苯二甲酸亚烷基酯）和阳离子改性的层状化合物的复合物的方法。 在另一个实施方案中，通过在溶剂例如邻二氯苯的存在下混合聚酯和层状化合物，制备平均分子量为10,000g / mol或更高的聚酯的复合材料。

公开(公告)号：US20050245676A1

公开(公告)日：2005-11-03

申请号：US11079903

申请日：2005-03-14

申请人： Steven Winckler ,  Tohru Takekoshi

发明人： Steven Winckler ,  Tohru Takekoshi

IPC分类号： C08J3/03 ,  B29C67/24 ,  B29C70/06 ,  B29K67/00 ,  C08F2/32 ,  C08G63/85 ,  C08J5/04 ,  C08J5/24 ,  B32B27/06 ,  C08K3/00

CPC分类号： B29C67/246 ,  B29C41/06 ,  C08G63/85 ,  Y10T428/31786

摘要： A water slurry process is used to prepare a prepreg and to manufacture articles from macrocyclic polyester oligomers. In one embodiment, a process for preparing a water suspension of macrocyclic polyester oligomers includes the steps of contacting a macrocyclic polyester oligomer and a polymerization catalyst with water and a surfactant, and mixing the macrocyclic polyester oligomer and polymerization catalyst with water and the surfactant thereby forming a suspension. In another embodiment, a process for impregnating macrocyclic polyester oligomers for polymerization includes the steps of providing a suspension of a macrocyclic polyester oligomer and a polymerization catalyst in water, applying the suspension to a base material, drying to remove water from the suspension, and pressing the dried suspension to a desired form. In yet another embodiment, a composition of macrocyclic polyester oligomer includes a macrocyclic polyester oligomer, a polymerization catalyst and water. In yet another embodiment, a process for polymerizing macrocyclic polyester oligomers includes the steps of mixing a blend material having a macrocyclic polyester oligomer and a polymerization catalyst with water to form a mixture, applying the mixture to a base material, drying to remove water, heating to polymerize the macrocyclic polyester oligomer, and pressing the polymerized macrocyclic polyester oligomer to a desired form.

摘要翻译： 使用水浆法制备预浸料并制备大环聚酯低聚物的制品​​。 在一个实施方案中，制备大环聚酯低聚物的水悬浮液的方法包括使大环聚酯低聚物和聚合催化剂与水和表面活性剂接触的步骤，并将大环聚酯低聚物和聚合催化剂与水和表面活性剂混合，从而形成 暂停。 在另一个实施方案中，用于聚合大环聚酯低聚物用于聚合的方法包括以下步骤：将大环聚酯低聚物和聚合催化剂的悬浮液提供在水中，将悬浮液施加到基材上，干燥以从悬浮液中除去水， 将干燥的悬浮液变成所需的形式。 在另一个实施方案中，大环聚酯低聚物的组合物包括大环聚酯低聚物，聚合催化剂和水。 在另一个实施方案中，用于聚合大环聚酯低聚物的方法包括以下步骤：将具有大环聚酯低聚物和聚合催化剂的共混材料与水混合以形成混合物，将混合物施加到基材上，干燥以除去水，加热 聚合大环聚酯低聚物，并将聚合的大环聚酯低聚物压制成所需的形式。

公开(公告)号：US06608147B2

公开(公告)日：2003-08-19

申请号：US10020381

申请日：2001-12-14

申请人： Tohru Takekoshi

发明人： Tohru Takekoshi

IPC分类号： C08F28302

CPC分类号： C08G75/23 ,  C08G64/18 ,  C08G73/1046 ,  C08G73/12 ,  C08G73/123 ,  C08L71/00 ,  C08L2666/18

摘要： Copolymers of polycarbonates or polyarylates with polyether polymers such as polyethersulfones, polyetherketones, and polyetherimides are prepared by reaction of the polyether polymer-forming reagents, e.g., bisphenol A disodium salt and bis(4-chlorophenyl) sulfone, in the presence of the polycarbonate or polyarylate. The reaction may take place in a dipolar aprotic solvent, or in a water-immiscible aromatic solvent in the presence of a phase transfer catalyst, preferably a hexaalkylguanidinium halide. Hydroxy-terminated polyether oligomers may be produced from the copolymers by saponification of carbonate or ester groups.

公开(公告)号：US06369170B1

公开(公告)日：2002-04-09

申请号：US09458920

申请日：1999-12-10

申请人： Tohru Takekoshi

发明人： Tohru Takekoshi

IPC分类号： C08F6700

CPC分类号： C08G75/23 ,  C08G64/18 ,  C08G73/1046 ,  C08G73/12 ,  C08G73/123 ,  C08L71/00 ,  C08L2666/18

摘要： Copolymers of polycarbonates or polyarylates with polyether polymers such as polyethersulfones, polyetherketones, and polyetherimides are prepared by reaction of the polyether polymer-forming reagents, e.g., bisphenol A disodium salt and bis(4-chlorophenyl)sulfone, in the presence of the polycarbonate or polyarylate. The reaction may take place in a dipolar aprotic solvent, or in a water-immiscible aromatic solvent in the presence of a phase transfer catalyst, preferably a hexaalkylguanidinium halide. Hydroxy-terminated polyether oligomers may be produced from the copolymers by saponification of carbonate or ester groups.

摘要翻译： 聚碳酸酯或多芳基化合物与聚醚聚合物如聚醚砜，聚醚酮和聚醚酰亚胺的共聚物通过聚醚聚合物形成试剂例如双酚A二钠盐和双（4-氯苯基）砜在聚碳酸酯或聚 多芳基化合物。 反应可以在相转移催化剂，优选六烷基胍卤化物的存在下，在偶极非质子溶剂中或在与水不混溶的芳族溶剂中进行。 羟基封端的聚醚低聚物可以通过碳酸酯或酯基的皂化由共聚物制备。

公开(公告)号：US5387666A

公开(公告)日：1995-02-07

申请号：US262799

申请日：1994-06-20

申请人： Tohru Takekoshi ,  Eric J. Pearce

发明人： Tohru Takekoshi ,  Eric J. Pearce

IPC分类号： C08G63/20 ,  C08G63/85

CPC分类号： C08G63/85 ,  C08G63/20

摘要： Cyclic tin catalysts are employed for the preparation of branched polyesters from macrocyclic polyester oligomers. They are less susceptible than previously known catalysts to the presence of acidic impurities in the oligomer compositions.

摘要翻译： 循环锡催化剂用于从大环聚酯低聚物制备支化聚酯。 它们比先前已知的催化剂对低聚物组合物中存在酸性杂质更不敏感。

公开(公告)号：US4769424A

公开(公告)日：1988-09-06

申请号：US56198

申请日：1987-06-01

申请人： Tohru Takekoshi ,  Patricia P. Anderson

发明人： Tohru Takekoshi ,  Patricia P. Anderson

IPC分类号： C08G73/10 ,  C08G77/42 ,  C08L77/06 ,  C08L81/02

CPC分类号： C08G73/106 ,  C08G73/1064 ,  C08G77/42

摘要： Block copolymers of polyarylene sulfide with either polyimide, or polydiorgano siloxane are provided. Various methods for making such block copolymers are shown which are useful as compatabilizers for blends of polyarylene sulfide with polyimides and polydiorgano siloaxanes.

公开(公告)号：US4716216A

公开(公告)日：1987-12-29

申请号：US932802

申请日：1986-11-19

申请人： Tohru Takekoshi ,  Patricia P. Anderson

发明人： Tohru Takekoshi ,  Patricia P. Anderson

IPC分类号： C08G73/10 ,  C08G69/42 ,  C08G75/00 ,  C08G79/02

CPC分类号： C08G73/1067 ,  C08G73/1064

摘要： Crystalline polyimides having low glass transition temperatures and high solvent resistance are obtained by reacting diamino-oligo-phenylene sulfides with aromatic tetracarboxylic acids or their anhydride derivatives. The diamino-oligo-phenylene sulfides can be of varying length and can be reacted with the dianhydride by conventional processes.

摘要翻译： 通过使二氨基 - 低聚 - 亚硫基硫醚与芳族四羧酸或它们的酸酐衍生物反应，得到具有低玻璃化转变温度和高耐溶剂性的结晶聚酰亚胺。 二氨基 - 低聚 - 亚硫基硫化物可以具有不同的长度并且可以通过常规方法与二酐反应。

公开(公告)号：USRE31805E

公开(公告)日：1985-01-15

申请号：US571323

申请日：1984-01-16

申请人： Tohru Takekoshi

发明人： Tohru Takekoshi

IPC分类号： C08G73/10

CPC分类号： C08G73/1007 ,  C08G73/1053 ,  C08G73/1071

摘要： A method is provided for making polyimides resulting from aromatic organic dianhydride and organic diamine interaction in the presence of an alkali metal salt of an oxygenated phosphorus compound.